Broad-spectrum bactericidal pollution-free growth-promoting thiazole manganese-zinc compound and composition thereof
A thiazole mancozeb compound technology, applied in the field of pesticides, can solve the problems of preparation of new thiazole mancozeb compounds without literature reports, outstanding effects, etc., achieve good industrial value or pesticide value, reduce manufacturing costs and costs, and facilitate the manufacture of preparations Effect
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Embodiment 1-1A
[0163] Example 1-1A Compound thiazole manganese zinc [C 4 H 4 N 6 S 4 (Mn) 0.5 (Zn) 0.5 ] Preparation
[0164] At room temperature, add 7.99g of 2-amino-5-mercapto-1,3,4-thiadiazole (0.06mol) to a 250ml flask, add 30ml of water, stir, and add a solution of 2.45g of sodium hydroxide dissolved in an appropriate amount of water , Stir to dissolve, and then add 2.535g of manganese sulfate monohydrate (0.015mol) and 4.314g of zinc sulfate heptahydrate (0.015mol) in a mixed solution of appropriate amount of water. A large amount of precipitation will precipitate. Stir at 30-40°C for half an hour. Take out and cool, filter with suction, wash the solid with a small amount of water until the filtrate has no sulfate ions, and filter with suction. The obtained solid is diluted and dried at about 100°C in vacuum for about 5 hours to obtain 7.1g of brown-gray solid; melting point is greater than 290°C; infrared spectrum (ν KBr max cm -1 ) 3372.4, 3272.1, 3174.6, 2938.3, 2848.2, 2722.8, 1612....
Embodiment 1-2A
[0165] Example 1-2A Compound mancozeb thiazole [C 4 H 4 N 6 S 4 (Mn) 0.5 (Zn) 0.5 ] Hydrate Preparation
[0166] At room temperature, add 7.99g of 2-amino-5-mercapto-1,3,4-thiadiazole (0.06mol) to a 250ml flask, add 30ml of water, stir, and add a solution of 2.45g of sodium hydroxide dissolved in an appropriate amount of water , Stir to dissolve, then add 2.535g of manganese sulfate monohydrate (0.015mol) and 4.314g of zinc sulfate heptahydrate (0.015mol) dissolved in a proper amount of water, stir at about 30℃ for half an hour, take it out and let it cool and filter with suction Wash the solid with a small amount of water until the filtrate is free of sulfate ions, and filter with suction. The obtained solid is diluted and dried at about 50℃ for about 4 hours to obtain 7.5g of brown-gray solid; the water content is 6.62% by the Karfel method; thermal analysis: weight loss is about 6.82% (See attached figure 1 ), has a corresponding endothermic peak (DTA) under weightlessness (se...
Embodiment 1-3A
[0167] Example 1-3A Mancozeb Thiazole [C 4 H 4 N 6 S 4 (Mn) 0.8 (Zn) 0.2 ] Compound Preparation
[0168] At room temperature, add 7.99g of 2-amino-5-mercapto-1,3,4-thiadiazole (0.06mol) to a 250ml flask, add 30ml of water, stir, and add a solution of 2.45g of sodium hydroxide dissolved in an appropriate amount of water , Stir to dissolve, then add 4.056g of manganese sulfate monohydrate (0.024mol) and 1.726g of zinc sulfate heptahydrate (0.006mol) dissolved in a proper amount of water, stir at about 40℃ for half an hour, take it out and let it cool and filter with suction. Wash the solid with a small amount of water until the filtrate is free of sulfate ions, and filter with suction. The obtained solid is diluted at about 50℃ and air-dried for about 4 hours to obtain 7.2g of brown-gray solid; melting point is greater than 280℃; elemental analysis: theoretical value: C14.95%, H 1.25%, N 26.15%, S 39.91%; measured values: C 14.82%, H 1.33%, N 26.03%, S 39.78%, content analysis (ato...
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