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High-strength and high-flame-retardant organic silicon foam material and preparation method thereof

An organosilicon foam, high flame retardant technology, applied in the field of high strength and high flame retardant organosilicon foam material and its preparation, can solve the problems of poor mechanical properties, poor flame retardant performance and the like

Active Publication Date: 2020-07-07
新纳奇材料科技江苏有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nevertheless, silicone rubber itself also has some shortcomings. Taking the open-cell silicone rubber foam material as an example, although it has good compressive stress relaxation properties, its mechanical properties are poor, and its flame retardancy is not good.

Method used

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  • High-strength and high-flame-retardant organic silicon foam material and preparation method thereof
  • High-strength and high-flame-retardant organic silicon foam material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] A high-strength and highly flame-retardant silicone foam material, comprising component A and component B at a weight ratio of 1:1, wherein component A includes the following components in parts by weight:

[0035] 18 parts of hydroxyl silicone oil, 20 parts of vinyl silicone oil, 29 parts of flame retardant filler, 6 parts of fumed silica, 16 parts of hollow glass microspheres, 10 parts of nano calcium carbonate, 1 part of platinum catalyst;

[0036] Component B is in parts by weight and includes the following components:

[0037] 30 parts of hydroxyl silicone oil, 36 parts of vinyl silicone oil, 10 parts of flame retardant filler, 6 parts of fumed silica, 8 parts of hollow glass microspheres, 5 parts of nano-calcium carbonate, 1 part of carbon black, 1 part of acetylenic alcohol, hydrogen-containing silicone oil 4 parts;

[0038] The flame retardant filler is a mixture of molybdenum disulfide / zinc ferrite hybrid cyclic polyphosphazene composite material, aluminum hyd...

Embodiment 2

[0047] A high-strength and highly flame-retardant silicone foam material, comprising component A and component B at a weight ratio of 1:1, wherein component A includes the following components in parts by weight:

[0048] 18 parts of hydroxyl silicone oil, 20 parts of vinyl silicone oil, 29 parts of flame retardant filler, 6 parts of fumed silica, 16 parts of hollow glass microspheres, 10 parts of nano calcium carbonate, 1 part of platinum catalyst;

[0049] Component B is in parts by weight and includes the following components:

[0050] 30 parts of hydroxyl silicone oil, 36 parts of vinyl silicone oil, 10 parts of flame retardant filler, 6 parts of fumed silica, 8 parts of hollow glass microspheres, 5 parts of nano-calcium carbonate, 1 part of carbon black, 1 part of acetylenic alcohol, hydrogen-containing silicone oil 4 parts;

[0051] The flame retardant filler is a mixture of molybdenum disulfide / zinc ferrite hybrid cyclic polyphosphazene composite material, aluminum hyd...

Embodiment 3

[0060] A high-strength and highly flame-retardant silicone foam material, comprising component A and component B at a weight ratio of 1:1, wherein component A includes the following components in parts by weight:

[0061] 19 parts of hydroxyl silicone oil, 25 parts of vinyl silicone oil, 30 parts of flame retardant filler, 7 parts of fumed silica, 15 parts of hollow glass microspheres, 9 parts of nano-calcium carbonate, 2 parts of platinum catalyst;

[0062] Component B is in parts by weight and includes the following components:

[0063] 32 parts of hydroxyl silicone oil, 35 parts of vinyl silicone oil, 12 parts of flame retardant filler, 7 parts of fumed silica, 10 parts of hollow glass microspheres, 6 parts of nano-calcium carbonate, 1 part of carbon black, 1 part of acetylenic alcohol, hydrogen-containing silicone oil 5 copies;

[0064] The flame retardant filler is a mixture of molybdenum disulfide / zinc ferrite hybrid cyclic polyphosphazene composite material, aluminum h...

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Abstract

The invention discloses a high-strength and high-flame-retardant organic silicon foam material. The material comprises a component A and a component B. The component A is prepared from, by weight, 10-20 parts of hydroxyl silicone oil, 20-70 parts of vinyl silicone oil, 10-40 parts of a flame-retardant filler, 5-10 parts of fumed silica, 7-20 parts of hollow glass beads, 5-10 parts of nano calciumcarbonate and 1-3 parts of a catalyst. The component B comprises the following components in parts by weight: 30-40 parts of hydroxyl silicone oil, 20-70 parts of vinyl silicone oil, 10-40 parts of aflame-retardant filler, 5-10 parts of fumed silica, 7-20 parts of hollow glass beads, 5-10 parts of nano calcium carbonate, 1-3 parts of carbon black, 1-3 parts of an inhibitor and 2-15 parts of hydrogen-containing silicone oil. The invention discloses a preparation method of the organic silicon foam material. The organic silicon foam material is good in mechanical property, good in flame retardant property, simple in preparation method and low in equipment requirement.

Description

Technical field: [0001] The invention relates to the field of polymer materials, in particular to a high-strength and high-flame-retardant organic silicon foam material and a preparation method thereof. Background technique: [0002] The foam materials currently on the market are mainly polyurethane foam plastics. However, the flame retardancy of polyurethane foam plastics is not ideal, and the limiting oxygen index (LOI) is only 19%, which belongs to a kind of flammable material. If it is used in the field of construction transportation, its safety cannot be effectively guaranteed. Therefore, the research and development of a new foam material with high flame retardant properties is very necessary. [0003] Silicone rubber is a kind of linear polysiloxane compound with silicon-oxygen bond as the main chain and side groups of silicon atoms connected to organic groups such as methyl, phenyl and vinyl groups. Silicone rubber foam material, also known as sponge silicone rubbe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L83/04C08L85/02C08L83/05C08K13/06C08K7/26C08K7/28C08K3/26C08K3/22C08K9/04C08K3/30C08K3/04C08K7/24C08J9/00
CPCC08J9/0061C08J9/0066C08J9/0071C08J9/0095C08J9/0085C08J2383/07C08J2483/04C08J2485/02C08J2483/05B29B7/90B29B7/7404B29B7/7485B29B7/823B29B7/88
Inventor 胡丽娜余跃
Owner 新纳奇材料科技江苏有限公司
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