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Composition for odor suppression

A technology of odor inhibitor and composition, applied in the field of composition for odor control, can solve the problems of reduced film transparency, film color deterioration, influence on mechanical properties and the like

Pending Publication Date: 2020-07-24
DOW GLOBAL TECH LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

High loading of ZnO particles also increases haze, which leads to reduced transparency and / or deterioration of film color in olefin-based polymer films
High loading of ZnO particles also adversely affects mechanical properties such as impact strength and film tear strength
Therefore, processing parameters and end-use mechanical requirements impose practical constraints on loading ZnO particles into olefin-based polymer compositions

Method used

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  • Composition for odor suppression
  • Composition for odor suppression
  • Composition for odor suppression

Examples

Experimental program
Comparison scheme
Effect test

example

[0114] Materials used in the examples are provided in Table 1 below.

[0115] Table 1

[0116]

[0117] 1. Membrane

[0118]Masterbatch processing. Two batches of masterbatches were prepared to allow easy feeding of the odor control composition into subsequent film production lines. Masterbatches were prepared on a Coperion ZSK 26 twin-screw extruder using a general purpose screw. Material residence time was controlled by the screw design, the feed rate was 20 lbs / hr, and the screw speed was 300 revolutions per minute (RPM). Not injected with oil. There is no side arm feeder. Not vacuumed. The compounded material is conveyed through a water bath and subsequently cut by a strand cutter pelletizer. After collection, the pelletized material was subjected to N 2 Purged and subsequently sealed in aluminum bags.

[0119] The composition of the first masterbatch (MB1) was 50wt% LLDPE 1, 25wt% ZnO and 25wt% Surlyn 9150. The composition of the second masterbatch (MB2) is 9...

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PUM

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Abstract

A composition for odor control includes (A) from 85 wt% to 99.5 wt% of an olefin-based compound and (B) from 15 wt% to 0.5 wt% of an odor suppressant. The odor suppressant includes a blend of (i) an ionomer, (ii) particles of zinc oxide, and (iii) particles of copper oxide. The composition has a methyl mercaptan odor suppression value of greater than 45% as measured in accordance with ASTM D5504-12.

Description

Background technique [0001] Many uses of articles made from olefin-based polymers suffer from unpleasant odors. Common sources of unpleasant odors include emissions of hydrogen sulfide (H 2 S) compositions and thiol-containing compositions. It is desirable in many applications to be able to remove or otherwise suppress the odor of olefin-based polymer articles. Therefore, many industries need to remove sulfur-based odorants (such as H 2 S and thiol) materials. A common example is the ability of plastic garbage bag liners (ie, olefin-based polymer articles) to remove odors. [0002] Particles of metal oxides such as zinc oxide (ZnO) and especially zinc salts are known to consume many odor-producing molecules such as H 2 S and thiols. All other factors being equal, it is well known that ZnO concentration is directly related to odor suppression - ie, as the ZnO concentration increases in a given olefin-based polymer article, so does the effectiveness of odor suppression. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08K3/22
CPCC08K2003/2248C08K2003/2296C08K2201/005C08K2201/014C08L23/0815C08K3/22C08L23/0876C08J5/18C08K2201/006C08L2203/16
Inventor A·L·克拉索夫斯基孙科夫K·卢S·T·马泰乌奇A·威廉森J·E·鲁伊斯J·E·博恩坎普
Owner DOW GLOBAL TECH LLC