A method of preparing high thermal conductivity polymer-based products using solid phase shear milling technology
A technology of solid-phase shear milling and polymer, applied in the direction of heat exchange materials, chemical instruments and methods, applications, etc., can solve the problems of limited thermal conductivity improvement, undiscussed research, limited thermal conductivity, etc., to achieve a solution Effects of agglomeration and peeling, improved compatibility, and excellent mechanical properties
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Embodiment 1
[0048] In this embodiment, the method for preparing high thermal conductivity polymer-based products using solid phase shearing and milling technology uses pure polymers as high-density polyethylene particles, and the carbon-based filler for thermal conductivity is graphene nanosheets, including the following in parts by weight step:
[0049](1) After mixing 100 parts of high-density polyethylene and 40 parts of graphene nanosheets, add them to a disc-shaped mechanochemical reactor for grinding and pulverization. After the grinding is completed, collect carbon-based fillers and evenly disperse them in the polymer matrix. Composite material powder; Among them, the process parameters of the disc-shaped mechanochemical reactor are: the grinding pressure is 30MPa, the temperature of the disc surface is controlled by feeding a constant temperature circulating liquid medium at a temperature of 40°C, and the grinding cycle is 6 times, and the disc rotation speed is 30r / min;
[0050...
Embodiment 2
[0062] In this embodiment, the method for preparing high thermal conductivity polymer-based products using solid phase shearing and milling technology uses pure polymers as high-density polyethylene particles, and carbon-based fillers for heat conduction as carbon nanotubes, including the following steps in parts by weight :
[0063] (1) After mixing 100 parts of high-density polyethylene and 40 parts of carbon nanotubes, they are added to a disc-shaped mechanochemical reactor for grinding and pulverization. After the grinding is completed, carbon-based fillers are collected and evenly dispersed in the polymer matrix. Material powder; among them, the process parameters of the disc-shaped mechanochemical reactor are as follows: the grinding pressure is 25MPa, the temperature of the disc surface is controlled by feeding a constant temperature circulating liquid medium with a temperature of 40°C, and the grinding cycle is 6 times, and the rotational speed of the disc is 30r / min;...
Embodiment 3
[0076] In this embodiment, the method for preparing a high thermal conductivity polymer-based product using solid phase shearing and milling technology adopts pure polymer as polypropylene particles, and the carbon-based filler for heat conduction is graphene nanosheets, and includes the following steps in parts by weight:
[0077] (1) After mixing 100 parts of polypropylene and 40 parts of graphene nanosheets, add them to a disc-shaped mechanochemical reactor for grinding and pulverization. After the grinding is completed, collect a composite material in which carbon-based fillers are evenly dispersed in the polymer matrix Powder; among them, the process parameters of the disc-shaped mechanochemical reactor are: the grinding pressure is 30MPa, the temperature of the disc surface is controlled by feeding a constant temperature circulating liquid medium at a temperature of 40°C, and the grinding cycle is 8 times, and the disc speed is 30r / min ;
[0078] (2) The composite materi...
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Abstract
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