Stat3 inhibitors
A CF3, compound technology, applied in the field of pharmacy
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Embodiment 1
[0356] Example 1. Synthesis of compounds of formula III and compounds of formula IIIx
[0357] Step 1: Formation of sulfonylamino-naphthol
[0358]
[0359] Step 1 is the reaction of 4-methoxybenzenesulfonyl chloride (1) and 4-amino-1-naphthol HCl (2) in the presence of sodium acetate to produce sulfonylamino-naphthol (3). To a 5 L round bottom flask with mechanical stirring was added 2 (139.19 g, 694 mmol) and water (2.0 L). To the stirred suspension was added sodium acetate (176.12 g, 2.13 mol) and 1 (177.52 g, 816 mmol) using a further water wheel (800 mL). The reaction was heated at 85°C by an electric mantel and the temperature was monitored using a calibrated thermocouple. The reaction was monitored by TLC and cooled after 2 h at set temperature. The purple precipitate formed during the reaction was filtered off, washed with water (1400 mL, in steps), and dried in a heated (55 °C) vacuum oven under a nitrogen purge for 18 h. The purple intermediate 3 (223.78 g, 95...
Embodiment 5
[0373] Example 5. STAT3 Inhibition ICs of Compounds of Formula IIIx and Compounds of Formula III 50
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