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A kind of wear-resistant thermosetting powder coating for oil pipeline and preparation method thereof

A thermosetting powder and oil pipeline technology, applied in powder coatings, epoxy resin coatings, coatings, etc., to achieve the effects of good adhesion, excellent wear resistance, and high labor production efficiency

Active Publication Date: 2022-03-15
SHIPBUILDING TECH RES INSITITUTE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a wear-resistant thermosetting powder coating for oil pipelines and its preparation method. The coating can withstand the corrosion of petroleum and the wear of impurities in it, and there is good adhesion between the coating and the substrate after plastic coating , to solve the problem that the coating in the prior art cannot resist both oil corrosion and impurity wear

Method used

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  • A kind of wear-resistant thermosetting powder coating for oil pipeline and preparation method thereof

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Effect test

Embodiment 1

[0020] A wear-resistant thermosetting powder coating for oil pipelines, made of raw materials comprising the following mass fractions: 50% bisphenol A epoxy resin, 10% curing agent (phenolic hydroxyl resin with a hydroxyl value of 0.56mol / 100g), and 30% filler %, leveling agent 5.0%, curing accelerator 1.0%, degassing agent 1.0%, silane coupling agent 3.0%; the filler is mixed with barium sulfate, mica powder, glass beads and ceramic beads; leveling agent 503 solid leveling agent is used, the curing accelerator is Nanhai Yaohua 803A curing accelerator, and the degassing agent is benzoin;

[0021] A kind of preparation method of wear-resistant thermosetting powder coating for oil pipeline is: (1) take bisphenol A type epoxy resin, curing agent, filler and various auxiliary agents, stir under the rotating speed of 400r / min in high-speed mixer Pre-mixing, mixing time 10min; (2) Send the mixed raw materials into the melt extruder for melt extrusion, the screw temperature of the me...

Embodiment 2

[0023] A wear-resistant thermosetting powder coating for oil pipelines, made of raw materials comprising the following mass fractions: 40% bisphenol A epoxy resin, 15% novolac epoxy resin, curing agent (phenolic hydroxyl group with a hydroxyl value of 0.56mol / 100g) Resin) 10%, filler 25%, leveling agent 5.0%, curing accelerator 1.0%, degassing agent 1.0%, silane coupling agent 3.0%; wherein the filler consists of barium sulfate, mica powder, glass beads and ceramic beads It is mixed; the leveling agent is 503 solid leveling agent, the curing accelerator is dimethylimidazole, and the degassing agent is benzoin;

[0024] A kind of preparation method of wear-resistant thermosetting powder coating for oil pipeline is: (1) take bisphenol A type epoxy resin, novolac epoxy resin, curing agent, filler and various auxiliary agents, 500r / min in high-speed mixer Stirring and pre-mixing under the rotating speed of 8min, the mixing time is 8min; (2) the raw material after mixing is sent in...

Embodiment 3

[0026] A wear-resistant thermosetting powder coating for oil pipelines, made of raw materials comprising the following mass fractions: 20% bisphenol A epoxy resin, 22% novolac epoxy resin, curing agent (phenolic hydroxyl group with a hydroxyl value of 0.56mol / 100g) Resin) 12%, curing agent (dicyandiamide) 10%, pigment 5%, filler 13%, leveling agent 4.0%, curing accelerator 1.0%, degassing agent 1.0%, loosening agent 1%, hindered phenolic resistance Oxygen agent 0.5%, silane coupling agent 2.5%; the filler is a mixture of barium sulfate, mica powder, glass beads and ceramic beads; the leveling agent is 503 solid leveling agent, and the curing accelerator is dimethylimidazole , the loosening agent is fumed silica, and the degassing agent is benzoin;

[0027] A kind of preparation method of wear-resistant thermosetting powder coating for oil pipeline is: (1) take by weighing bisphenol A type epoxy resin, novolac epoxy resin, curing agent, filler and various auxiliary agents, 600r...

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Abstract

The invention provides a wear-resistant thermosetting powder coating for oil pipelines and a preparation method thereof. The coating is made of raw materials including the following mass fractions: thermosetting epoxy resin: 30%-60%, curing agent: 4.5%-30%, Pigment and / or filler: 20% to 30%, auxiliary agent: 2% to 12%; the curing agent is one or more of dicyandiamide, modified dicyandiamide and sebacic acid dihydrazide In combination with a phenolic hydroxyl resin, the phenolic hydroxyl resin is a phenolic curing agent with an interpenetrating structure and containing polyfunctional groups of hydroxyl, amide and amine groups with a hydroxyl value of 0.5-0.7 mol / 100g. The invention is simple to operate, easy to realize industrialized production, the product is used for coating oil pipelines, and the labor production efficiency of coating is high; the utilization rate of the coating can reach more than 98%; the coating has good adhesion between the substrate , excellent wear resistance, and more environmentally friendly.

Description

technical field [0001] The invention belongs to the technical field of thermosetting powder coatings, and in particular relates to a wear-resistant thermosetting powder coating for oil pipelines and a preparation method thereof. Background technique [0002] Due to the fact that certain impurities will be produced during oil extraction and other links, oil and gas gathering and transportation pipelines often contain a certain amount of solid particles. These sandy fluids impact the inner wall of the pipeline and cause a certain degree of erosion and wear to it, which will eventually affect normal production and may cause pipeline leakage. For oil pipelines, corrosion, scaling, waxing, and wear are the four major public hazards, which always accompany this life cycle. In order to solve the problem of oil pipelines, it is urgent to develop a pipeline coating that is corrosion-resistant, wear-resistant, and has low transmission resistance, but the coatings currently used on oi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/00C09D7/61C09D5/03
CPCC09D163/00C09D5/033C08K2003/3045C08L2205/025C08L2203/18C08K13/04C08K7/20C08K7/18C08K3/34C08K3/30C08L63/00
Inventor 由佳王娟王永光张剑慧
Owner SHIPBUILDING TECH RES INSITITUTE
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