Straw hydrothermal carbon-based coal-like briquette fuel for combustion and preparation method thereof

A technology of molding fuel and hydrothermal carbon, which is applied in the direction of fuel, waste fuel, biofuel, etc., can solve the problems of waste of water resources, discharge, easy looseness and stability, etc., to reduce waste water treatment costs, improve overall efficiency, energy The effect of increasing productivity

Pending Publication Date: 2021-05-25
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most biomass stalks have not been fully and rationally utilized. For example, a small part of corn stalks is used as heating and cooking materials or roughage for animals, and most of them are used as field fertilizers or burned on site.
[0004] At present, some straws are carbonized to prepare biochar for use as adsorbents, solid fuels or soil improvers, but limited by the carbonization process, the prepared biochar has poor combustion characteristics, molding characteristics, hydrophobicity and stability. It shows that it is easy to loosen in the case of high humidity or water, and its stability is poor, which affects transportation and storage, and it is also easy to cause microbial activities and cause internal corruption or spontaneous combustion or emission of polluted gases, which is not conducive to its use as a solid fuel. Combustion and transportation, thereby limiting the application range of straw biochar as a solid fuel
[0005] In addition, more liquid by-products will be produced after hydrothermal carbonization, and the high-value components are not fully utilized; and the treatment of liquid by-products is difficult, which increases the production cost of straw carbonization; hydrothermal carbonization continues to use fresh water , but also cause waste of water resources

Method used

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  • Straw hydrothermal carbon-based coal-like briquette fuel for combustion and preparation method thereof
  • Straw hydrothermal carbon-based coal-like briquette fuel for combustion and preparation method thereof
  • Straw hydrothermal carbon-based coal-like briquette fuel for combustion and preparation method thereof

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preparation example Construction

[0028] A method for preparing "coal-like" briquette fuel based on straw hydrothermal charcoal for combustion, comprising the following steps:

[0029] The straw is pulverized and subjected to hydrothermal carbonization. The temperature of the hydrothermal carbonization is 220-240° C., the hydrothermal carbonization time is 20-30 minutes, and the water is circulated 2-3 times during the hydrothermal carbonization process to obtain biochar.

[0030] In some embodiments, the straw is wheat straw, corn straw, rice straw and cotton straw.

[0031] In some embodiments, the particle size of the crushed straw is 0.5-5mm.

[0032] Further, during the hydrothermal carbonization process, the ratio of solid to liquid is 1:12-17, preferably 1:15.

[0033] In some embodiments, the temperature of hydrothermal carbonization is 230-235° C., and the time of hydrothermal carbonization is 22-27 minutes.

[0034] Further, the temperature of hydrothermal carbonization is 231° C., and the time of ...

Embodiment

[0041] A method for preparing a "coal-like" briquette fuel based on straw hydrothermal charcoal for combustion, comprising the following steps:

[0042] Use straw as raw material, cut it to 30-35cm, and crush it to 1-5mm with a high-speed pulverizer; mix the crushed straw and water evenly at a ratio of 1:15, and carry out hydrothermal carbonization reaction in a high-pressure reactor ;Set the hydrothermal carbonization temperature to 231°C, and the hydrothermal carbonization time to 25 minutes, using automatic pressure; after the hydrothermal carbonization experiment, recover the liquid by-products, and carry out the hydrothermal carbonization reaction again according to the above method, with a total of 2 or 3 cycles can;

[0043] After the reactor is cooled to room temperature, the hydrothermal charcoal and liquid by-products are separated by vacuum filtration, and the hydrothermal charcoal is dried in an oven at 60°C until the moisture content is 10-15%; the universal mater...

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Abstract

The invention discloses straw hydrothermal carbon-based coal-like briquette fuel for combustion and a preparation method thereof. The preparation method comprises the following steps: crushing straws, carrying out hydrothermal carbonization at 220-240 DEG C for 20-30 min, and circulating water for 2-3 times in the hydrothermal carbonization process. The optimal process conditions are as follows: the hydrothermal carbonization temperature is 231 DEG C, the hydrothermal carbonization time is 25 min, water circulation is performed for 2 or 3 times in the hydrothermal carbonization process, the water content of hydrothermal carbon forming is 10-15%, and the forming pressure is 130 MPa. The straw hydrothermal carbon formed particles have the characteristics that the ash content is 2.11%, the volatile content is 78.63%, the high calorific value is 21.03 MJ / kg (the value is close to the combustion calorific value of coal), the comprehensive combustion characteristic index is 9.55% 2 / (K3. min<2>), the water permeability resistance is 10.24%, the compressive strength is 6.04 MPa, and the forming energy consumption is 8.92 J / g.

Description

technical field [0001] The invention relates to the technical field of utilization of biomass straw as fuel, in particular to a "coal-like" briquette fuel based on straw hydrothermal charcoal for combustion and a preparation method thereof. Background technique [0002] The information disclosed in this background section is only intended to increase the understanding of the general background of the present invention, and is not necessarily taken as an acknowledgment or any form of suggestion that the information constitutes the prior art already known to those skilled in the art. [0003] The main component of biomass straw is lignocellulose, which has the characteristics of large quantity, wide distribution, strong renewability and low pollution. However, most biomass stalks have not been fully and rationally utilized. For example, a small part of corn stalks is used as heating and cooking materials or roughage for animals, and most of them are used as field fertilizers o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L5/44C10B53/02
CPCC10L5/447C10L5/445C10B53/02Y02E50/30Y02E50/10
Inventor 张新雁王文龙刘贤孙成功
Owner SHANDONG UNIV
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