Application of diquinoline phosphite in PVC barium-zinc composite heat stabilizer

A technology of bisquinoline phosphite and composite heat stabilizer, which is applied in the application field of bisquinoline phosphite in PVC barium zinc composite heat stabilizer, and can solve the problem of easy decomposition, limited aging resistance and limited application To improve the precipitation performance, reduce the color difference of the film, and improve the printing performance

Pending Publication Date: 2021-12-24
ZHEJIANG HIMPTON NEW MATERIAL
View PDF6 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this compound is easily decomposed in the stabilizer system, resulting in a large amount of free phenol, and its application in export PVC soft products with high environmental protection requirements is

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Application of diquinoline phosphite in PVC barium-zinc composite heat stabilizer
  • Application of diquinoline phosphite in PVC barium-zinc composite heat stabilizer
  • Application of diquinoline phosphite in PVC barium-zinc composite heat stabilizer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0022] The technical solutions of the present invention will be further specifically described below through specific implementation examples.

[0023] The raw materials used in the examples are conventional raw materials in the market.

[0024] Preparation of bisquinoline phosphite:

[0025] Using 68.7g of phosphorus trichloride and 228.4g of 8-hydroxyquinoline as raw materials, add phosphorus trichloride dropwise to 8-hydroxyquinoline at a temperature of 70°C and a time of 120 minutes to obtain triquinoline phosphite Phosphorous acid ester: 20.5 g of phosphorous acid was dropped into the above product, and reacted for 60 minutes at 120° C. to obtain 168 g of diquinoline phosphite.

[0026] The formula composition of the liquid barium zinc stabilizer of embodiment 1-4 is as follows table:

[0027]

[0028]

[0029] The preparation method of the liquid barium zinc stabilizer of example 1-4 carries out according to the following steps:

[0030] (1) Add barium isooctano...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to application of diquinoline phosphate in a PVC barium-zinc composite heat stabilizer, the structural formula of the diquinoline phosphate is shown in the specification, the diquinoline phosphate compound adopts a novel heterocyclic group to replace an aliphatic aromatic group, and the compound is added in the preparation of a liquid barium-zinc stabilizer, so that the precipitation resistance of the liquid barium-zinc stabilizer can be effectively improved, efficient heat aging resistance (static stability) is also achieved, and excellent processability in secondary printing of advertising films and the like can be realized.

Description

technical field [0001] The invention relates to the application of bisquinoline phosphite in a PVC barium-zinc composite heat stabilizer. Background technique [0002] Due to the poor compatibility of metal soap and PVC resin in traditional barium-zinc PVC composite heat stabilizers, metal soap is continuously precipitated during the process of PVC calendering, and the precipitate is attached to the surface of the PVC film, which affects the printing, inkjet and printing of the product. transparency. Therefore, it is necessary to add an anti-separation agent to the liquid stabilizer to improve the inkjet performance of the PVC film and inhibit the precipitation. At present, most of the anti-separation agents with better effects in liquid stabilizers contain phenolic substances, and their dosage is 4-10% (accounting for the percentage of liquid stabilizers). It is suitable for soft PVC films with low environmental protection requirements. However, most toy films exported to...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08K5/526C08K5/098C08K5/06C08L27/06C08L91/06
CPCC08K5/526C08K5/098C08K5/06C08L27/06C08L2201/08C08K2201/014C08L91/06
Inventor 刘毓林廖永林高尔金王利锋陈森方
Owner ZHEJIANG HIMPTON NEW MATERIAL
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap