Direct elemental synthesis of sodium borohydride
A technology of sodium hydroxide and hydride, which is applied in the direction of borane/diborane hydride, metal boride, boron/boride, etc., and can solve problems such as the reduction of unrevealed sodium ions
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[0008] Unless indicated to the contrary, all percentages herein are expressed in weight percent and temperatures are expressed in °C. A "transition metal" is any element of Groups 3 to 12 of the IUPAC Periodic Table of the Elements, ie elements with atomic weights 21-30, 39-48, 57-80 and 89-103.
[0009] Reducing agents suitable for use in the present invention include carbon, hydrocarbons, alkali metals, alkaline earth metals, transition metals, Al, Ga, Si, P, and metal hydrides. Examples of particular reducing agents include methane, ethane, propane, butane, syngas, coal, coke, Be, Mg, Ca, Al, Si, Ti, Sc, Y, La, V, Cr, Mn, Co, Ni , Cu, Zn, magnesium dihydride and calcium hydride. In one embodiment of the present invention, the reducing agent is a hydrocarbon or a mixture of hydrocarbons. In one embodiment of the present invention, the reducing agent is at least one C 1 -C 4 hydrocarbon. In another embodiment of the present invention, preferred reducing agents are Mg, Ca...
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