Photosensitive resin composition and dry film resist using the same
A technology of photosensitive resin and composition, which is applied in the field of dry film resist and alkali-soluble photosensitive resin composition, can solve the problems of destroying the storage stability of the composition, instability of the viscosity enhancer, etc., achieve excellent storage stability, improve High effect of adhesion, heat resistance and chemical resistance
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Examples
Embodiment 1 and 2
[0043] (Preparation of polymer resin)
[0044] According to the components and contents shown in Table 1 below, acrylate copolymer resins represented by Chemical Formula 1 (Preparation Examples 1 and 2), and conventionally used acrylate copolymer resins (Comparative Preparation Examples 1 and 2) were prepared. ). 70 wt% tetrahydrofuran (TFH) was used as a polymerization solvent. Polymerization was performed at 45°C using a low temperature initiator.
[0045] Classification
[0046] In Table 1, BM stands for benzyl methacrylate; MA stands for methacrylic acid; PAM-100 and PAM-200 are phosphate-containing methacrylates prepared by RHODIA; HEMA stands for 2-hydroxyethyl methacrylate ester; and MMA stands for methyl methacrylate.
Embodiment 1~5 and comparative Embodiment 1~3
[0048] (Preparation of Photosensitive Resin Composition)
[0049] The cross-linking monomer, photopolymerization initiator, dye and colorant were added to the acrylate copolymer resin, and Table 2 below shows the respective compositions and contents. After the components were dissolved, the mixture was stirred at room temperature for 2 hours, thereby obtaining a photosensitive resin composition. The resulting photosensitive resin composition was filtered with a 500-mesh filter, thereby removing impurities.
[0050] Classification (wt%)
Example
comparative example
1
2
3
4
5
1
2
3
Tree
fat
Preparation Example 1
30
-
32
-
15
-
-
-
Preparation Example 2
-
30
-
32
15
-
-
-
Comparative Preparation Example 1
-
-
-
-
-
30
- ...
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