Borate salt solution for cold-rolling plate bonderizing prediction

A borate and cold-rolled plate technology, applied in the field of borate solution, can solve the problems of lack of extensiveness, time-consuming, high cost, etc., to avoid major coating quality problems, reduce sample preparation costs, and simplify peripheral conditions Effect

Active Publication Date: 2006-11-01
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

[0005] 1. Time-consuming: It takes 1 to 2 hours to complete the phosphating sample preparation at the production site, and another 2 to 3 hours for the film weight and microscopic morphology analysis of the small sample, a total of 3 to 5 hours, and this does not include the transportation of the sample time; while it takes 2-3 hours for phosphating solution preparation time to complete phosphating sample preparation in the laboratory, if the laboratory is far away from the production site, the time required may be as long as several weeks
[0006] 2. High cost: The entire production line must be run for sample preparation on the phosphating site. The cost includes manpower, equipment operation, chemicals, energy media, etc. Generally speaking, at least RMB 50,000 is required
[0007] 3. The applicability is not wide: For cold-rolled plate suppliers, it is necessary to obtain the phosphating chemicals of each specific user, including degreasing agents, surface conditioners and phosphating solutions, etc. At the same time, it is necessary to understand the phosphating chemicals It is difficult to evaluate the process parameters of the product before it can be phosphatized; and even if all the information is obtained, the results are only applicable to this user and are not universal
[0009] 1. The evaluation results are only applicable to specific users who use the phosphating solution and are not universal;
[0010] 2. The prediction result is incomplete, only the quality of the phosphating film can be predicted, but the sensitivity of the cold-rolled sheet to phosphating cannot be predicted
[0012] 1. It can only evaluate the difference in surface properties before and after phosphating of cold-rolled sheets, but cannot distinguish the difference between the phosphating quality of different cold-rolled sheets;
[0013] 2. The cold-rolled sheet must be placed in the real phosphating solution to obtain the phosphating film, otherwise the prediction cannot be realized

Method used

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  • Borate salt solution for cold-rolling plate bonderizing prediction
  • Borate salt solution for cold-rolling plate bonderizing prediction
  • Borate salt solution for cold-rolling plate bonderizing prediction

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Embodiment Construction

[0024] The following is an evaluation of the phosphating quality of the three cold-rolled sheets, combined with Figure 1 ~ Figure 3 , to illustrate a preferred embodiment of the present invention.

[0025] Step 1, the Na 2 B 4 o 7 10H 2 O (sodium tetraborate) is placed in distilled water, dissolved and prepared into a sodium tetraborate solution, and then hydrochloric acid with a concentration of 1:1 is used as a pH regulator to adjust the pH value of the solution. After adjustment, the solute concentration of the sodium tetraborate solution is 0.05 / mol, and the pH value of the solution at 25°C is between 5.5 and 6.9.

[0026] Step 2, respectively placing the three kinds of cold-rolled sheet a, cold-rolled sheet b and cold-rolled sheet c to be tested in the above-mentioned sodium tetraborate solution.

[0027] Step 3. Use a potentiostat to record the dynamic change process of the potential value of the cold-rolled sheet after entering the above-mentioned sodium tetrabor...

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Abstract

A borate solution used to predict phosphorization ability of cold-rolled sheet has solute concentration of 0.01-0.1 / mole and its solution pH value is 4-6.9 under normal temperature of 20-30 deg.c.

Description

technical field [0001] The invention relates to a borate solution used for predicting the phosphability of cold-rolled sheets. Background technique [0002] Cold-rolled sheet is a heterogeneous material. The chemical composition of the material, the diversity of rolling and annealing processes lead to huge differences in the composition and characteristics of the surface of the cold-rolled sheet, making the cold-rolled sheet before coating, including degreasing, rinsing, Surface conditioning, phosphating, rinsing and other processes will have different behaviors, resulting in differences in the phosphating properties of cold-rolled sheets, which will further lead to the appearance quality and corrosion resistance of cold-rolled sheets after coating. different. In order to prevent poor phosphating quality of the cold-rolled sheet, it is necessary to evaluate the phosphating ability of the cold-rolled sheet before formal use. [0003] At present, the main application industr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N27/28G01N27/42
Inventor 戴毅刚申龙张剑萍陈红星
Owner BAOSHAN IRON & STEEL CO LTD
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