Process of continuously leaching manganese oxide ore

A technology for leaching manganese oxide ore, which is applied in the field of continuous leaching of manganese oxide ore with good continuity, can solve the problems of long turnaround time, increase in the number of equipment used, and reduce the effective utilization rate of equipment, so as to achieve good continuity, reduce labor intensity, The effect of reducing the number of

Inactive Publication Date: 2006-11-15
GUANGXI NON FERROUS METALS GROUP HUIYUANMENGYE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The so-called intermittent leaching is to complete a series of reaction processes such as leaching and neutralization in a single reaction tank. In the production process of manganese smelting, it is to add sulfuric acid, water, manganese oxide ore, pyrite and other raw materials at one time for leaching. In the tank, after the leaching and compounding is completed, the materials in the leaching tank need to be transferred to the tank at one time before they can be fed again for production. This intermittent leaching process cannot realize continuous input and output of materials, resulting in a long turnaround time for materials between equipment , which reduces the effective utilization rate of equipment, increases the number of equipment used, and also increases production costs and labor intensity

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0009] Manganese oxide ore powder containing 19.14% manganese, pyrite powder with sulfur content of 44.54%, and sulfuric acid with a concentration of 98% are used to prepare a 100g / l dilute sulfuric acid solution. Manganese oxide ore powder, pyrite The acid-mineral ratio of powder and sulfuric acid is 1:0.21:0.46. Shuangfei powder is used as the neutralizing agent. The continuous leaching tank used is composed of three leaching tanks connected in series to form a three-stage continuous leaching. The effective volume of each leaching tank is 1m 3 / piece, one neutralization tank, the effective volume is 1.5m 3 To realize the method of the present invention.

[0010] Mix the above-mentioned manganese oxide ore powder and pyrite powder in a dry weight ratio of 1:0.21, and then continuously add them to the first-stage leaching tank of the continuous leaching tank at the same time with the prepared sulfuric acid in a ratio of 1:0.46, and continuously Stir, the material liquid ove...

Embodiment 2

[0012] Manganese oxide powder containing 20.06% manganese, pyrite powder with sulfur content of 42.37%, and sulfuric acid with a concentration of 98% are used to prepare a 90g / l dilute sulfuric acid solution. Manganese oxide powder, pyrite The acid-mineral ratio of powder and sulfuric acid is 1:0.22:0.45. Ammonia water is used as the neutralizing agent. The continuous leaching tank used is composed of four leaching tanks connected in series to form four-stage continuous leaching. The effective volume of each leaching tank is 1m 3 / piece, one neutralization tank, the effective volume is 1.5m 3 To realize the method of the present invention.

[0013] Mix the above-mentioned manganese oxide ore powder and pyrite powder in a dry weight ratio of 1:0.22 to form a mixture of two ores and a manganese sulfate solution with a free sulfuric acid concentration of 90g / l in a ratio of 1:0.45 and continuously add them to the continuous leaching tank In the first-stage leaching tank, while ...

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Abstract

A method relates to extract the manganese dioxide from ore, its technological processes is as follows: according to the ratio of 1:0.10-0.40:0.2-0.6,mixing the manganese dioxide powder, pyrites, sulfuric acid or manganese sulfate, and then continuously putting them into the continuous bank which are composed of 1-6 agitated banks, so it can form continuously extraction, the temperature of whole process is controlled during 50 to 100 deg.C. During the whole extraction, it is the multilevel continuous extraction, feed liquid overflows from the upper-stage tank into the next agitated one, after the manganese dioxide powders are extracted in the bank for 1-8h, the feed liquid running out from the last lever bank are collected into the neutralization tank, then its Ph is adjusted between 4.5-6.0 by adding into the neutralization reagent, it can get the crude manganese sulfate by filtering the neutralization feed liquid and abandoning the residue. This invention can continuously feed, output and be controlled automatically, it also can decrease the number of workers and the intensity of work.

Description

(1) Technical field: [0001] The invention relates to a method for leaching manganese oxide ore, in particular to a method for continuously leaching manganese oxide ore with good production continuity. (two) background technology: [0002] At present, in the smelting production process, the leaching process can be divided into discontinuous leaching and continuous leaching. The current leaching and compounding of the manganese smelting industry adopts the discontinuous leaching process. The so-called intermittent leaching is to complete a series of reaction processes such as leaching and neutralization in a single reaction tank. In the production process of manganese smelting, it is to add sulfuric acid, water, manganese oxide ore, pyrite and other raw materials at one time for leaching. In the tank, after the leaching and compounding is completed, the materials in the leaching tank need to be transferred to the tank at one time before they can be fed again for production. Th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/08
CPCY02P10/20
Inventor 熊一言
Owner GUANGXI NON FERROUS METALS GROUP HUIYUANMENGYE
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