Copper alloy material for electric element and method of making same

A technology for electrical components and manufacturing methods, applied in electrical components, cable/conductor manufacturing, metal rolling, etc., can solve the problems that phosphor bronze can not fully meet the performance, poor migration resistance, can not adapt to the increase of energization current, etc. Good bending properties, excellent elongation and electrical conductivity, and low anisotropy

Active Publication Date: 2007-03-07
株式会社日立金属新材料
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, phosphor bronze does not sufficiently satisfy the performance required for the above-mentioned connector materials
For example, since the conductivity of phosphor bronze is as low as about 20% IACS, it cannot adapt to the increase of current (because the increase of Joule heat is significant), and there is also the disadvantage of poor migration resistance.

Method used

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  • Copper alloy material for electric element and method of making same

Examples

Experimental program
Comparison scheme
Effect test

no. 1 Embodiment approach

[0018] Composition of copper alloy materials for electrical components

[0019] The copper alloy material for electrical components in this embodiment is characterized in that it contains 1.0 to 5.0% by mass of Ni, 0.2 to 1.0% by mass of Si, 0.05 to 2.0% by mass of Sn, and 0.1 to 5.0% by mass of Sn in its average composition. % of Zn, 0.01 to 0.3% by mass of P, a total of 0.05 to 1.0% by mass of at least one selected from Fe and Co, the balance being Cu and unavoidable impurities, the total mass of Ni, Fe and Co and Si The ratio [(Ni+Fe+Co) / (Si+P)] to the total mass of P is 4-10.

[0020] The reasons for adding and limiting the alloy components constituting the copper alloy material for electrical components such as terminals, connectors, and lead frames in this embodiment will be described below.

[0021] Adding Ni, Fe, Co together with Si and P will form Si compound and P compound and disperse and precipitate in the material. In the conventional Cu-Ni-Si alloy, the strengt...

no. 2 Embodiment approach

[0030] Composition of copper alloy materials for electrical components

[0031]The copper alloy material for electrical components in this embodiment is characterized in that it contains 1.0 to 5.0% by mass of Ni, 0.2 to 1.0% by mass of Si, 0.05 to 2.0% by mass of Sn, and 0.1 to 5.0% by mass of Sn in its average composition. % of Zn, 0.01 to 0.3 mass % of P, a total of 0.05 to 1.0 mass % of at least one selected from Fe and Co, a total of 0.01 to 1.0 mass % of at least one selected from Mg, Ti, Cr and Zr species, the balance is Cu and unavoidable impurities, and the ratio [(Ni+Fe+Co) / (Si+P)] of the total mass of Ni, Fe and Co to the total mass of Si and P is 4-10.

[0032] The reasons for adding and limiting the alloy components constituting the copper alloy material for electrical components in this embodiment will be described below.

[0033] The reasons for adding Ni, Si, Sn, Zn, P, Fe, and Co, and the reasons for specifying the content (addition amount) and composition ra...

Embodiment 1

[0053] Using oxygen-free copper as the base material, melted in a high-frequency melting furnace with Ni: 3.0 mass%, Si: 0.5 mass%, P: 0.15 mass%, Fe: 0.15 mass%, Co: 0.15 mass%, Sn: 1.0 mass %, Zn: a copper alloy composed of 1.5% by mass was cast into an ingot with a diameter of 30 mm and a length of 250 mm.

[0054] This was heated to 850° C. and extruded (hot worked) to form a plate shape with a width of 20 mm and a thickness of 8 mm to obtain a copper alloy raw material, which was then cold-rolled to a thickness of 0.36 mm (first cold rolling). Next, the cold-rolled material was held at 800° C. for 10 minutes, then poured into water, and subjected to a first heat treatment of cooling to room temperature (about 20° C.) at a rate of about 300° C. / min. Next, the cooled material was cold-rolled to a thickness of 0.3 mm (second cold rolling), and then the second heat treatment (sample No. 1) of holding at 470° C. for 2 hours was performed.

[0055] For the sample No. 1 produce...

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Abstract

The present invention provides a copper alloy material for electrical components that is excellent in strength, yield strength, elongation, and electrical conductivity, and has good bending performance. The copper alloy contains (mass %) 1.0-5.0% Ni, 0.2-1.0% Si, 0.05-2.0% Sn, 0.1-5.0% Zn, 0.01-0.3% P, and a total of 0.05-1.0% selected from Fe and Co. At least one, the balance is Cu and unavoidable impurities, the ratio of the total mass of Ni, Fe and Co to the total mass of Si and P is 4 to 10, and the tensile strength is greater than or equal to 700N / mm2, The elongation is greater than or equal to 10%, and the electrical conductivity is greater than or equal to 40% IACS. The manufacturing method includes: the first cold rolling process, after forming the copper alloy raw material, cold rolling the copper alloy raw material to a thickness of 1.1 to 1.3 times the target final plate thickness; the first heat treatment process, heating the first cold rolled material to After 700-850°C, cool down to below 300°C at a rate of above 25°C per minute; the second cold rolling process, cold-roll the material after the first heat treatment to the target final plate thickness; the second heat treatment process, the second cold The rolled material is heated to 400-500° C. and kept for 30 minutes to 3 hours.

Description

technical field [0001] The present invention relates to a copper alloy material for electrical components such as terminals, connectors, and lead frames, and a manufacturing method thereof, and particularly relates to a copper alloy material for electrical components that is excellent in tensile strength, 0.2% yield strength, elongation, conductivity, and good bending workability Copper alloy material and manufacturing method thereof. Background technique [0002] In recent years, electronic devices such as mobile phones and notebook personal computers have been reduced in size, thickness and weight, and components such as terminals and connectors used have smaller electrical components with narrower electrode pitches. Moreover, the lead frame is also developing towards smaller size and thinner wall. [0003] Due to such miniaturization, the materials used also become thinner, but from the point of view that the reliability of the connection must be maintained, although the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B1/02H01B13/00C22C9/06B21B3/00H01R43/00
CPCC22C9/02C22F1/08C22C9/04C22C9/06
Inventor 山本佳纪高野浩聪古德浩一佟庆平野村克己
Owner 株式会社日立金属新材料
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