Leuco polymers as bluing agents in laundry care compositions

a technology of bluing agent and laundry care composition, which is applied in the field of laundry care compositions, can solve the problems of buildup and adversely affecting the aesthetics of finished products

Active Publication Date: 2019-08-20
PROCTER & GAMBLE CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, traditional whitening agents when used at levels providing consumer noticeable whiteness benefits may either adversely impact finished product aesthetics, or if highly depositing, have issues with build up over time and over hueing.

Method used

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  • Leuco polymers as bluing agents in laundry care compositions
  • Leuco polymers as bluing agents in laundry care compositions
  • Leuco polymers as bluing agents in laundry care compositions

Examples

Experimental program
Comparison scheme
Effect test

examples

[0185]Preparation of Alkoxylated Polyethylene Imine:

[0186]122.2 gram of the unsubstituted initial polyethylenimine (PEI1) containing (2×9)+(1×13)=31 amine hydrogens on the primary and secondary nitrogen atoms is charged to a pressure reactor. Then 150.1 g propylene oxide (2.6 mol, 83.9 mol. % of the amine hydrogens of the primary and secondary nitrogen atoms) is added to the reactor. The reaction is agitated at 120° C. under pressure until the pressure stabilizes (˜8 hours). The product (PEI 2) is obtained with 83.9 mol % of amine hydrogens replaced by a 2-hydroxypropyl group or a 1-hydroxypropane-2-yl group. In the structure below, only 2-hydroxypropyl groups have been shown for the sake of simplicity.

[0187]

[0188]Preparation of Alkoxylated Polyethylene Imine with Alkene Chain.

[0189]To 273 gram (0.1 mol) of the PEI 2 obtained above, 28.4 gram (0.1 mol, equilibrate 3.2% of the amino hydrogen to PEI 1) is added. The reaction mixture is stirred to 180° C. for 16 hours under nitrogen to...

formulation examples

[0224]The following are illustrative examples of cleaning compositions according to the present disclosure and are not intended to be limiting.

examples 1-7

iquid Laundry Detergent Compositions

[0225]

1234567Ingredients% weightAE1.8S6.775.161.361.30———AE3S————0.45——LAS0.862.062.720.680.951.563.55HSAS1.852.631.02————AE96.329.8510.207.92AE835.45AE78.4012.44C12-14 dimethyl Amine Oxide0.300.730.230.37———C12-18 Fatty Acid0.801.900.600.991.20—15.00Citric Acid2.503.961.881.980.902.500.60Optical Brightener 11.000.800.100.300.050.500.001Optical Brightener 30.0010.050.010.200.50—1.00Sodium formate1.600.091.200.041.601.200.20DTI0.320.05—0.60—0.600.01Sodium hydroxide2.303.801.701.901.702.502.30Monoethanolamine1.401.491.000.70———Diethylene glycol5.50—4.10————Chelant 10.150.150.110.070.500.110.804-formyl-phenylboronic acid————0.050.020.01Sodium tetraborate1.431.501.100.75—1.07—Ethanol1.541.771.150.89—3.007.00Polymer 10.10—————2.00Polymer 20.300.330.230.17———Polymer 3——————0.80Polymer 40.800.810.600.401.001.00—1,2-Propanediol—6.60—3.300.502.008.00Structurant0.10—————0.10Perfume1.601.101.000.800.901.501.60Perfume encapsulate0.100.050.010.020.100.050.10Pr...

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Abstract

A laundry care composition including (i) from 2 to 70 wt % of a surfactant; and (ii) from 0.0001 to 20.0 wt % of a leuco polymer including an alkoxylated polyethyleneimine covalently bound to a leuco moiety. At least a first portion of nitrogen atoms of the alkoxylated polyethyleneimine have covalently bound thereto a leuco moiety. At least a second portion of nitrogen atoms of the alkoxylated polyethyleneimine have covalently bound thereto a moiety selected from the group consisting of oxyalkylene moieties, polyoxyalkylene moieties, and mixtures thereof; and at least a third portion of nitrogen atoms of the alkoxylated polyethyleneimine have covalently bound thereto a moiety selected from the group consisting of an alkylene chain, an alkylene chain having covalently bound thereto a phenyl or naphthyl group, and mixtures thereof. Methods of making the leuco polymer and methods of treating textiles with such laundry care compositions.

Description

TECHNICAL FIELD[0001]This application describes laundry care compositions that contain leuco polymers and their use in the laundering of textile articles. These types of leuco polymers are provided in a stable, substantially colorless state and then may be transformed to an intense colored state upon exposure to certain physical or chemical changes such as, for example, exposure to oxygen, ion addition, exposure to light, and the like. The laundry care compositions containing the leuco polymers are designed to enhance the apparent or visually perceived whiteness of, or to impart a desired hue to, textile articles washed or otherwise treated with the laundry care composition.BACKGROUND[0002]As textile substrates age, their color tends to fade or yellow due to exposure to light, air, soil, and natural degradation of the fibers that comprise the substrates. As such, to visually enhance these textile substrates and counteract the fading and yellowing the use of polymeric colorants for c...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): C11D1/00C11D3/22C11D3/20C11D3/26C11D3/30C11D3/40C11D3/42C09B11/00C09B11/04C09B11/10C09B69/10C11D3/18C11D11/00C11D3/37
CPCC11D3/42C09B69/103C09B69/109C11D1/00C11D3/187C11D11/0017C11D3/221C11D3/26C11D3/3723C11D3/40C11D3/20
Inventor MIRACLE, GREGORY SCOTQIN, HAIHUDEY, SANJEEV KUMAR
Owner PROCTER & GAMBLE CO
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