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201results about How to "Interface stability" patented technology

Garnet structure solid electrolyte material and preparation method thereof

The invention relates to a garnet structure solid electrolyte material and a preparation method thereof. The preparation method comprises the following specific steps: mixing a compound containing five elements such as lithium, lanthanum, calcium, zirconium and tantalum in an acid solution, and drying to obtain precursor powder; and sequentially calcining, tabletting and sintering the precursor powder, thereby obtaining the garnet structure solid electrolyte material. The solid electrolyte material has a chemical composition of Li(7+x-y)CaxLa3-xTayZr2-yO12, wherein x is more than 0 and less than or equal to 1, and y is more than 0 and less than or equal to 2. The method has the advantages of simplicity and convenience in operation, low cost, low energy consumption and the like. The methodfurther contributes to obtaining materials with an accurate stoichiometric ratio and uniform particle size and reducing the content of impurities. X-ray diffraction determines that a crystal structureof the obtained solid electrolyte material is a cubic garnet structure, and an AC impedance method determines that the ionic conductivity of lithium ions in the material can reach 4.03*10<-4>S cm<-1>. The garnet structure solid electrolyte material prepared by the method disclosed by the invention is high in ionic conductivity, excellent in chemical stability and applicable to lithium secondary batteries.
Owner:TONGJI UNIV

All-solid-state lithium-air battery and preparation method and application thereof

ActiveCN105742761AAll solid state implementationImprove securityFuel and primary cellsPtru catalystElectrical battery
The invention discloses an all-solid-state lithium-air battery and a preparation method and application thereof. The all-solid-state lithium-air battery provided by the invention comprises a lithium metal anode, a porous ceramic support body, a compact electrolyte thin film, a porous cathode thin film, a sealing material, a current collector and a lead, wherein the porous support body is made of garnet type lithium-ion solid electrolyte material; in an air electrode catalyst and permeation holes of the lithium metal anode, a three-phase boundary for battery reaction is expanded, and the battery polarization resistance is reduced; the thickness of the battery electrolyte thin film is smaller than 30 micrometers, a lithium ion transmission path is shortened, and the battery ohmic resistance is reduced; and the battery is a tubular structure with a closed end, the lithium metal anode is poured into a tube, and the battery is easy to seal and is easy to work in different conditions. The all-solid-state lithium-air battery prepared according to the invention has the advantages of high charging-discharging capacity, high rate performance, high cycle stability, wide working temperature range and the like, and is applicable to the field of various mobile electronic devices and power batteries.
Owner:SUZHOU UNIV

Lithium ion battery composite separation membrane and preparation method thereof

The present invention discloses a lithium ion battery composite separation membrane and a preparation method thereof, and belongs to the technical field of lithium ion batteries, wherein at least a surface of a polyolefin separation membrane is coated with a modified natural rubber polymer coating. According to the invention, the polyolefin separation membrane and the modified natural rubber are combined to form the composite separation membrane, such that mechanical properties of the natural rubber can be improved, and the original pore closing characteristic of the polyolefin separation membrane can be maintained and utilized so as to improve safety of the battery, enhance bonding force between the separation membrane and the positive electrode and bonding force between the separation membrane and the negative electrode, eliminate the interface effect, and improve cycle stability of the battery; and the inorganic nanoparticles are added to the modified natural rubber latex, such that the crystallinity of the polymer can be reduced to a certain extent, the mechanical strength of the separation membrane and the carrier concentration can be increased, the interface compatibility between the separation membrane and the lithium electrode can be effectively improved, and the interface is stable.
Owner:HENAN NORMAL UNIV

High-voltage composite spinel-coated positive electrode material and preparation method thereof

The invention provides a high-voltage composite spinel-coated positive electrode material and a preparation method thereof. The positive electrode material comprises a lithium cobalt oxide core, a spinel-type lithium nickel manganese oxide middle layer and a solid electrolyte surface layer. The invention provides a positive electrode material with a composite coating layer on the surface, and the coating layer has good lithium ion conductivity, so that the positive electrode material is high in discharge capacity and excellent in cycle life under a high voltage without influencing a discharge platform, the volume energy density of a lithium ion battery is improved, and the corrosion of HF to the surface layer of the material can be reduced; and the high-temperature cycle life of the material is prolonged, so that the defects of unstable use structure of the positive electrode material under high charging cut-off voltage or poor cycle performance and low discharge capacity even if the structure is stable in the prior art are overcome, the high-temperature cycle performance is improved, and the material is more suitable for the actual use working condition of the material.
Owner:TIANMU LAKE INST OF ADVANCED ENERGY STORAGE TECH CO LTD

Metallurgical bonding double-metal stainless steel cladding reinforcing steel bar and preparation process thereof

InactiveCN106825515AHas comprehensive mechanical propertiesHigh strengthInduction heaterSS - Stainless steel
The invention discloses a metallurgical bonding double-metal stainless steel cladding reinforcing steel bar and a preparation process thereof. The metallurgical bonding double-metal stainless steel cladding reinforcing steel bar comprises a carbon steel core part and a stainless steel cladding. The composite forming process comprises the following steps: integrally heating an outer-layer stainless steel pipe to 600 to 1000 DEG C by using an induction heater, pouring into inner-layer carbon steel, performing metal liquid casting and manufacturing an interface metallurgical bonding cladding type double-metal composite blank; hot-rolling the cast double-metal blank to form cladding double-metal round steel and threaded steel. The metallurgical bonding interface of the stainless steel layer and the carbon steel core is formed by casting, and the advantages of high bonding strength, excellent processing property, dense structure, high quality, few procedures, low cost, high efficiency and the like are achieved. The integral stainless steel reinforcing steel bar is replaced by the double-metal reinforcing steel bar, so on the premise of guaranteeing the corrosion-resistant characteristic of the reinforcing steel bar, the stainless steel material is saved, the engineering cost is reduced, the strength of the reinforcing steel bar is effectively improved, waste of resource and energy and environmental pollution are reduced, and a wide application prospect is achieved.
Owner:丹阳恒庆复合材料科技有限公司

Lithium ion battery high-voltage electrolyte solution capable of constructing double-layer positive electrode surface film

The invention discloses a lithium ion battery high-voltage electrolyte solution capable of constructing a double-layer positive electrode surface film, and belongs to the technical field of manufacturing of lithium ion batteries. The electrolyte solution is composed of an organic solvent, a lithium salt and a film-forming additive; the organic solvent is composed of cyclocarbonate, linear carbonate and fluoroethylene carbonate; the film-forming additive is composed of a film-forming additive A, a film-forming additive B and a film-forming additive C, wherein the film-forming additive A is oneof tri(trimethylsilane)borate or tri(trimethylsilane)phosphate, the film-forming additive B is methylene methanedisulfonate, and the film-forming additive C is one of thiophene or 3,4-ethylenedioxythiophene. Through combined use of the three film-forming additives, the electrolyte solution generates double layers of positive electrode surface films with different components, an electrode/electrolyte solution interface can be stabilized, oxidation decomposition of the electrolyte solution and damage of a positive electrode material structure are inhibited, the battery cycle stability and thermal stability are improved, the internal resistance of the battery is reduced, and the battery multiplying power performance is improved.
Owner:WANXIANG 123 CO LTD +1
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