The invention discloses an amorphous iron-based
silicon-
phosphorus composite negative
electrode material and a preparation method and application thereof, the raw materials of the iron-based
silicon-
phosphorus composite negative
electrode material comprise an iron element, a
silicon element, a
phosphorus element and a carbon material, the
molar ratio of the silicon element to the phosphorus element is 2: 1-1: 2, the
molar ratio of the silicon element to the iron element is 8: 1-1: 2, and the
mass ratio of an iron / silicon / phosphorus mixture to the carbon material is 5: 5-8: 2; the iron-based silicon phosphorus composite negative
electrode material is prepared by a one-step or multi-step mechanical ball milling method. In the iron-based silicon phosphorus composite negative
electrode material, the introduction of the iron elementary substance induces the
microstructure to be disordered and reduces the
lithium ion diffusion energy barrier, and meanwhile, the iron elementary substance and the
lithium phosphide formed in situ respectively provide abundant
electron and
ion transmission paths and cooperatively buffer the huge
volume deformation of the silicon negative electrode in the lithiation / delithiation process; furthermore, the electrochemical reversibility, the
cycling stability and the rate capability of the material in the
lithium storage process are effectively improved.