Nanosubstrate with conductive zone and method for its selective preparation
a technology of conductive zone and nanosubstrate, which is applied in the direction of nanoinformatics, polycrystalline material growth, transportation and packaging, etc., can solve the problems of inability to find the method for manufacturing nanostructures and other problems to da
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[0054] The method is exemplified hereinbelow with reference to selective growth of metal tips onto semiconductor nanorods and tetrapods.
[0055] In a method for selective growth of contacts made of gold, AuCl3 was dissolved in toluene by use of dodecyldimethylamonium bromide (DDAB) and dodecylamine, and the resulting solution was added to a toluene solution comprising of colloidal grown nanorods or tetrapods. The method is exemplified for the prototypical CdSe nanocrystal system that is highly developed synthetically and widely studied for its size and shape dependent properties.
[0056] CdSe rods and tetrapods of different dimensions (see below), were prepared by high temperature pyrolisys of suitable precursors, in a coordinating solvent containing a mixture of trioctylphosphineoxide (TOPO), and of phosphonic acids [9]. In a typical Au growth reaction, a gold solution was prepared containing 12 mg AuCl3 (0.04 mmol), 40 mg of DDAB (0.08 mmol) and 70 mg (0.37 mmol) of dodecylamine in ...
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