PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT
Patent Information
- Authority / Receiving Office
- US ¡ United States
- Patent Type
- Applications(United States)
- Current Assignee / Owner
- 3M INNOVATIVE PROPERTIES CO
- Publication Date
- 2008-10-30
- Estimated Expiration
- Not applicable ¡ inactive patent
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Abstract
Description
[0001] The present invention relates to a process of reducing the amount of fluorinated emulsifier in fluoropolymer dispersions using anion exchange resins in the presence of one or more pH-dependent surfactants. The invention also relates to fluoropolymer dispersions containing the pH-dependent surfactants but containing no or only low amounts of fluorinated emulsifiers, and to uses of these dispersions.BACKGROUND
[0002] Fluoropolymers, i.e. polymers having a fluorinated backbone, have been long known and used in a various applications because of their desirable properties such as heat resistance, chemical resistance, weatherability, UV-stability etc. Various fluoropolymers are for example described in âModern Fluoropolymersâ, edited by John Scheirs (ed), Wiley Science 1997. The fluoropolymers may have a partially fluorinated backbone, generally at least 40% by weight fluorinated, or a fully fluorinated backbone. Particular examples of fluoropolymers include polytetrafluoroethylene (P...