Zr-based amorphous alloy and a preparing method thereof

a technology of amorphous alloys and preparing methods, which is applied in the field of zr-based amorphous alloys and a preparing method thereof, can solve the problems of difficult to manufacture large-scale amorphous alloys, limiting the application of amorphous metallic alloys, and reducing the internal cooling speed of products

Inactive Publication Date: 2009-06-04
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, some characteristics of the amorphous metallic alloys limit their applications.
For example, it is difficult to manufacture large size amorphous alloys.
But as product size increases, the internal cooling speed within the product is declining.
Thus, the internal amorphous degree is low in the long range and it is difficult to form large size amorphous structures.
Also, it is difficult to effectively improve the plasticity characteristics of the amorphous materials.
So when the stress reaches a certain degree, the amorphous alloy material may break suddenly, which may lead to accidents.
Thus, the applications of the amorphous alloy materials as structural materials are limited.
Zhao et al. however does not address the issues of large size amorphous alloy manufacturing and the plasticity of the amorphous alloy materials.

Method used

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  • Zr-based amorphous alloy and a preparing method thereof
  • Zr-based amorphous alloy and a preparing method thereof

Examples

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Effect test

example 1

[0022]A preparation method of a Zr-based amorphous alloy is illustrated in this example.

[0023]Raw materials Zr, Ti, Sn, Cu, Ni, Fe, Be (about 25 grams) were added to an electric arc melting equipment (Shen Yang Scientific Instrument Manufacturing Company Limited). The ratios of the raw materials were as follows: (Zr0.74Ti0.25Sn0.01)55.34(Cu0.56Ni0.44)20.65Fe1.96Be22.05. The equipment was vacuumized to about 5 Pa. The raw material was melted at about 2,000° C. under Ar protection for about 6 minutes. The molten master alloy was mixed sufficiently, and then cooled into an ingot. The ingot was re-melted at about 1,500° C. using electric arc melting, and then cooled in a copper mold casting process with a cooling speed of about 102 k / s to obtain the Zr-based amorphous alloy sample C1.

example 2

[0024]Another preparation method of a Zr-based amorphous alloy is illustrated in this example.

[0025]Raw materials Zr, Ti, Sn, Cu, Ni, Fe, Be (about 200 kg) were added to an induction melting equipment (Zhongbei Technology). The ratios of the raw materials were as follows: (Zr0.74Ti0.25Sn0.01)55.34(Cu0.56Ni0.44)20.65Fe1.96Be22.05. The equipment was vacuumized to about 5 Pa. The raw materials were melted at about 1,800° C. under Ar protection for about 10 minutes. The molten master alloy was mixed sufficiently, and then cooled into an ingot. The ingot was re-melted at about 1,200° C. using resistance heating, and then cooled in a die-casting process with a cooling speed of about 104 k / s to obtain the Zr-based amorphous alloy sample C2.

example 3

[0026]Yet another preparation method of a Zr-based amorphous alloy is illustrated in this example.

[0027]Raw materials Zr, Ti, Sn, Cu, Ni, Fe, Be (about 20 g) were added to a quartz tube (Zhongbei Technology). The ratios of the raw materials were as follows: (Zr0.80Ti0.17Sn0.03)40Y5Nb5(Cu0.64Ni0.36)25Fe5Be20. The tube was vacuumized to about 200 Pa. The raw materials were melted at about 2,000° C. by induction heating under Ar protection for about 5 minutes. The molten master alloy was mixed sufficiently, and then cooled into an ingot. The ingot was re-melted at about 1,500° C. by induction heating, and then cooled in a water quenching process with a cooling speed of about 103 k / s to obtain the Zr-based amorphous alloy sample C3.

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Abstract

In one aspect, a Zr-based amorphous alloy comprises Zr, Ti, Cu, Ni, Fe, Be, and Sn. In another aspect, a Zr-based amorphous alloy comprises about 30-75 atomic percent of (ZrxTiySnz), about 10-35 atomic percent of (CumNin), about 0.1-15 atomic percent of Fe, and about 0.1-35 atomic percent of Be. Reference numerals x, y and z are atomic fractions, and x+y+z equals to 1, wherein x is about 0.6-0.85, and z is in the range of about 0.01x-0.1x. Reference numerals m and n are atomic fractions, and m+n equals to 1, and wherein m is about 0.5-0.65. In yet another aspect, a method for preparing a Zr-based amorphous alloy comprises melting a raw material comprising Zr, Ti, Cu, Ni, Fe, Be, and Sn to form an alloy mixture; and molding the alloy mixture to form the amorphous alloy.

Description

[0001]The present application claims priority to Chinese Patent Application No. 200710187786.2, filed Nov. 30, 2007, the entirety of which is hereby incorporated by reference.FIELD OF THE DISCLOSURE[0002]The present disclosure relates to a Zr-based amorphous alloy and a preparing method thereof.BACKGROUND OF THE DISCLOSURE[0003]Amorphous metallic alloys are disordered in the long range but ordered in the short range. They have desirable physical and chemical properties, such as high strength, high hardness, high wearing resistance, high corrosion resistance, relatively wide elastic range, high electric resistance, good superconductivity, and low magnetic loss. Amorphous metallic alloys have huge potential when used as structural materials. They are widely used in many fields such as mechanics, IT electronics, the military industry and so on.[0004]However, some characteristics of the amorphous metallic alloys limit their applications. For example, it is difficult to manufacture large...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C22F1/16C22C45/10
CPCC22C1/002C22C45/10C22C16/00C22C1/11
Inventor LU, KUNJIANG, LINLINZHANG, FALIANGGONG, QING
Owner BYD CO LTD
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