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Degradable and/or Deformable Diverters and Seals

a diverter and seal technology, applied in the direction of sealing/packing, transportation and packaging, wellbore/well accessories, etc., can solve the problems of ball being unable to hold pressure, problems in proper fluid flow in the well or other later well operations, etc., to achieve high cross-linking unit density, increase pack permeability, and high tensile strength

Inactive Publication Date: 2021-06-24
TERVES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent describes a degradable ball or seal that can be used in oil and gas operations to restore circulation, divert fluid, seal perforations, and limit entry holes for workover or other operations. The degradable ball has a unique structure made of a thermoplastic elastomer or metallic composite that can be designed to have variable stiffness. This helps to ensure the ball can perform its duties effectively while reducing or preventing mud or fluid loss, diverting flow during fracturing, and temporarily sealing perforations. The degradable ball can also be filled with voids or pores to aid in its degradation. Overall, this invention provides an efficient and effective solution for oil and gas operations.

Problems solved by technology

The commercially available degradable perforation balls and diverter systems are not acceptable because of their limited temperature range which can result in the balls softening and transforming to a different shape, thereby resulting in the ball being unable to hold pressure, the formation of byproducts which effect formation permeability (e.g., cannot be removed completely), or contain organic or other functional byproducts.
Also, the remainders of these prior perforation balls may be forced into the flair path and may not degrade completely, thereby causing problems in proper fluid flow in the well or other later well operations.

Method used

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  • Degradable and/or Deformable Diverters and Seals
  • Degradable and/or Deformable Diverters and Seals
  • Degradable and/or Deformable Diverters and Seals

Examples

Experimental program
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Effect test

example 1

[0201]An elastomeric dissolvable composite ball formed of about 50 vol. % soda lime glass microballoons having a particle size of 30 μm and a density of 0.23 g / cc was bonded together with 20 vol. % powdered nitrile-butadiene rubber (NBR) particles and 30 vol. % polyvinyl alcohol. The elastomeric dissolvable composite ball had a size of ⅞ in. diameter and an overall density of 0.95 g / cc. The elastomeric dissolvable composite ball was tested to hold 1500 psi for two hours and, as illustrated in Table 1, loses 50% weight over a period of 72 hours in tap water at 51.7° C., and which left particles in the range of 30-100 μm.

example 2

[0202]An elastomeric dissolvable composite ball formed of about 60 vol. % soda lime glass microballoons having a particle size of 30 micron and a density of 0.23 g / cc was bonded together with 20 vol. % powdered NBR particles and 20 vol. % polyvinyl alcohol. The elastomeric dissolvable composite ball had a size of ⅞ in. diameter and an overall density of 0.80 g / cc. The elastomeric composite ball was tested to hold 1500 psi for four hours and, as illustrated in Table 1, loses 50% weight over a period of 96 hours in tap water at 51.7° C., and which left particles in the range of 30-100 μm.

TABLE 1Initial 3 hrs.6 hrs.24 hrs.48 hrs.72 hrs. ExampleWt. (g)(g)(g)(g)(g)(g)15.5835.7905.3404.9564.7092.97025.7125.9866.1505.5414.6162.907

example 3

[0203]An elastomeric dissolvable composite ball formed of about 60 vol. % soda lime glass microballoons having a particle size of 20 μm and a density of 0.46 g / cc was bonded together with 20 vol. % powdered NBR particles and 20 vol. % polyvinyl alcohol. The elastomeric dissolvable composite ball had a size of ⅞ in. diameter and an overall density of 1.05 g / cc. This elastomeric composite ball was tested to hold 1500 psi for 0.5 hours, as illustrated in FIG. 8, and loses 50% weight over a period of 24 hours in tap water at 51.7° C., and which left particles in the range of 50-70 μm. The partially degraded ball is illustrated in FIG. 9.

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Abstract

A variable stiffness engineered degradable ball or seal having a degradable phase and a stiffener material. The variable stiffness engineered degradable ball or seal can optionally be in the form of a degradable diverter ball or sealing element which can be made neutrally buoyant.

Description

[0001]The present disclosure claims priority on U.S. Provisional Application No. 62 / 967,864 filed Jan. 30, 2020, which are all incorporated herein by reference.[0002]The present disclosure is related to U.S. patent application Ser. No. 16 / 654,099 filed Oct. 16, 2019, which in turn claims priority on U.S. Provisional Application No. 62 / 747,358 filed Oct. 18, 2018, which are all incorporated herein by reference.[0003]The present disclosure claims priority on U.S. patent application Ser. No. 15 / 728,813 filed Oct. 10, 2017, which in turn is a divisional of U.S. patent application Ser. No. 15 / 294,957 filed Oct. 17, 2016 (now U.S. Pat. No. 10,625,336 issued Apr. 21, 2020), which is a divisional of U.S. patent application Ser. No. 14 / 627,236 filed Feb. 20, 2015, (now U.S. Pat. No. 9,757,796 issued Sep. 17, 2018), which in turn claims priority on U.S. Provisional Application No. 61 / 942,879 filed Feb. 21, 2014, which are all incorporated herein by reference.[0004]The present disclosure claim...

Claims

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Application Information

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IPC IPC(8): B22D23/06B22D19/14B22D21/00B22D21/04B22D25/06B22D27/00B22D27/08C22C23/00C22C23/02C22C47/08C22C49/04C22C49/14B22D27/02B22D27/11B22F1/00C22C1/03B22F1/062
CPCB22D23/06C22C49/02B22D21/007B22D21/04B22D25/06B22D27/00B22D27/08C22C23/00C22C23/02C22C47/08C22C49/04C22C49/14B22D27/02B22D27/11B22F1/004C22C1/03B22D19/14E21B33/13E21B2200/08C22C47/14B33Y10/00B33Y80/00B33Y70/00B22F3/225B22F3/20B22F10/00B22F3/02B22F3/14Y02P10/25B22F1/062B22F2304/05B22F2999/00B22F2301/35
Inventor SHERMAN, ANDREWFARKAS, NICHOLASMEESALA, RAGHU
Owner TERVES