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In-situ particle strengthening heat resisting aluminium base composite material

A particle-reinforced, composite material technology, applied in the field of aluminum-based materials, can solve the problems of inability to meet the requirements of high temperature strength, low content of reinforced particles, etc., and achieve the effects of good interface bonding, good high temperature stability, and good heat resistance.

Inactive Publication Date: 2007-07-18
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The fraction of reinforcing particles in this material is 3-5%, the content of reinforcing particles is low, and the tensile strength at 315°C is 200-220MPa, which cannot meet the high-temperature strength requirements of some special service environments.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] Preparation ingredients weight percent composition 1% Mg, 1% Cu, 0.5% Ni, 0.5% Fe, 0.05% Zr, 5% TiB 2 , and the rest are heat-resistant aluminum matrix composites of Al.

[0013] Add industrial pure aluminum into the crucible to melt the aluminum ingot, and KFB 4 、KTiF 6 Mix evenly, then add the mixed salt into the melt, and carry out mechanical stirring to make the mixed salt react with the melt. After the reaction, take out the by-products of the reaction, and add industrial pure Mg, Al-Cu, Al-Ni, Al - Fe, Al-Zr master alloy, degassed and refined, poured into cast billet, then extruded cast billet into a bar of a certain size, and then subjected to solution aging treatment.

[0014] TiB in composite 2 The size of the particles is 50-300nm, and the particles are dispersed in the matrix. TiB 2 The interface with the substrate is clean, there is no interface reaction, and the combination is good. Mechanical properties of materials at 300°C: σ b =258MPa, σ 0.2 =215...

Embodiment 2

[0016] Preparation ingredients weight percent composition 2% Mg, 2.5% Cu, 1.5% Ni, 1.5% Fe, 0.3% Zr, 20% TiB 2 , and the rest are heat-resistant aluminum matrix composites of Al.

[0017] Add industrial pure aluminum into the crucible to melt the aluminum ingot, and KFB 4 、KTiF 6 Mix evenly, then add the mixed salt into the melt, and carry out mechanical stirring to make the mixed salt react with the melt. After the reaction, take out the by-products of the reaction, and add industrial pure Mg, Al-Cu, Al-Ni, Al - Fe, Al-Zr master alloy, degassed and refined, poured into cast billet, then extruded cast billet into a bar of a certain size, and then subjected to solution aging treatment.

[0018] TiB in composite 2 The size of the particles is 50-300nm, and the particles are dispersed in the matrix. TiB 2 The interface with the substrate is clean, there is no interface reaction, and the combination is good. Mechanical properties of materials at 300°C: σ b =265MPa, σ 0.2 =2...

Embodiment 3

[0020] Preparation ingredients weight percent composition 3% Mg, 5% Cu, 3% Ni, 3% Fe, 0.5% Zr, 40% TiB 2 , and the rest are heat-resistant aluminum matrix composites of Al.

[0021] Add industrial pure aluminum into the crucible to melt the aluminum ingot, and KFB 4 、KTiF 6 Mix evenly, then add the mixed salt into the melt, and carry out mechanical stirring to make the mixed salt react with the melt. After the reaction, take out the by-products of the reaction, and add industrial pure Mg, Al-Cu, Al-Ni, Al - Fe, Al-Zr master alloy, degassed and refined, poured into cast billet, then extruded cast billet into a bar of a certain size, and then subjected to solution aging treatment.

[0022] TiB in composite 2 The size of the particles is 50-250nm, and the particles are dispersed in the matrix. TiB 2 The interface with the substrate is clean, there is no interface reaction, and the combination is good. Mechanical properties of materials at 300°C: σ b =289MPa, σ 0.2 =267MPa,...

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Abstract

The present invention is one kind of in-situ grain reinforced aluminum base composite material, and belongs to the field of material technology. The in-situ grain reinforced aluminum base composite material consists of Mg 1-3 wt%, Cu 1-5 wt%, Ni 0.5-3 wt%, Fe 0.5-3 wt%, Zr 0.05-0.5 wt%, reinforcing TiB2 grain 5-40 wt%, and Al for the rest. The reinforcing TiB2 grains in the size of 20-300 nm are distributed homogeneously in the base material with clear interface and no interface reaction. The in-situ grain reinforced aluminum base composite material has tensile strength at 300 deg.c higher than 250 MPa, excellent high-temperature performance and wide application in aeronautics, astronautics, heat energy and other fields.

Description

technical field [0001] The invention relates to an aluminum-based material in the technical field of composite materials, in particular to an in-situ particle-reinforced heat-resistant aluminum-based composite material. Background technique [0002] Aluminum matrix composites have high specific strength, high specific modulus, good heat resistance and wear resistance, and are widely used in aerospace, national defense, industry and other fields. The preparation methods of aluminum matrix composites include stirring casting, vacuum pressure impregnation, mechanical alloying, powder metallurgy and other processes. Due to the poor wettability between reinforcing particles and matrix in the aluminum matrix, the interface reaction is difficult to control, and the distribution of reinforcing particles is uneven, which affects the performance of aluminum matrix composites. At the same time, the preparation process of using external particles is complicated and the cost is high, wh...

Claims

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Application Information

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IPC IPC(8): C22C21/00
Inventor 陈东王浩伟孙焕焕李险峰马乃恒
Owner SHANGHAI JIAO TONG UNIV