Liquid crystal display
A liquid crystal display and polyimide technology, applied in static indicators, instruments, nonlinear optics, etc., to achieve the effects of reducing optical hysteresis, improving dimensional stability, and high heat resistance
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Embodiment 1
[0043] Embodiment 1: the synthesis of 6FDA-DACH (PI-FD)
[0044]
[0045] At room temperature, use a three-necked flask and pass through nitrogen, dissolve 2.32g of DACH diamine into 41g of DMAc, and then add 5g of 6FDA bis-anhydride until 6FDA is completely dissolved, and continue stirring for 3 hours , forming a viscous polyamic acid solution. Then use a doctor blade to form a film on the glass substrate, and then heat it to 100°C, 200°C and 300°C for 1 hour and bake for imidization reaction to form a highly transparent and colorless polyimide film material.
Embodiment 2
[0046] Embodiment 2: Synthesis of 6FDA-m-TB-HG-co-6FDA-IPDA (PI-FTI)
[0047]
[0048] At room temperature, using a three-necked flask with nitrogen, 1.64 g of m-TB-HG (2,2'-Dimethyl-4,4'-diamino biphenyl, 2,2'-dimethyl-4,4' -Diaminobiphenyl) and 0.56g of IPDA (Isophorone diamine, isophorone diamine) diamine are dissolved in 41g of DMAc, and then 5g of 6FDA bis-acid anhydride is added after m-TB-HG and IPDA are completely dissolved , until the 6FDA was completely dissolved, and continued to stir for 3 hours to form a viscous polyamic acid solution. Then use a doctor blade to form a film on the glass substrate, and then heat it to 100°C, 200°C and 300°C for 1 hour and bake for imidization reaction to form a highly transparent and colorless polyimide film material.
Embodiment 3
[0049] Example 3: Synthesis of 6FDA-m-TB-HG-co-6FDA-DACH (PI-FTD)
[0050]
[0051] At room temperature, use a three-necked flask and pass through nitrogen, dissolve 1.63g of m-TB-HG and 0.70g of DACH diamine into 42g of DMAc, and then dissolve 5g of m-TB-HG and DACH Add 6FDA bis-acid anhydride until 6FDA is completely dissolved, then continue stirring for 3 hours to form a viscous polyamic acid solution. Then use a doctor blade to form a film on the glass substrate, and then heat it to 100°C, 200°C and 300°C for 1 hour and bake for imidization reaction to form a highly transparent and colorless polyimide film material.
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