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Method for adjusting pH of liquid and ph adjustor

A technology for regulating devices and regulating methods, which is applied in chemical instruments and methods, water treatment parameter control, water/sludge/sewage treatment, etc., and can solve problems such as easy corrosion of devices and high salt concentration

Inactive Publication Date: 2008-06-04
TANAH PROCESS LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, in the conventional method using a diaphragm, the salt concentration of the pH-adjusted solution becomes high, and the device is easily corroded.

Method used

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  • Method for adjusting pH of liquid and ph adjustor
  • Method for adjusting pH of liquid and ph adjustor
  • Method for adjusting pH of liquid and ph adjustor

Examples

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preparation example Construction

[0057] In the production method of the present invention, the aqueous liquid used in the above step (ii) may be the aqueous solution (A) of the step (i). In this case, the step (ii) is performed in a state where the ion-adsorbing electrodes (E1) and (E2) are immersed in the aqueous solution (A) of the step (i).

[0058] The aqueous liquid treated in step (ii) is a liquid containing water, for example, a liquid in which water accounts for 50% by mass or more (for example, 80% by mass or more or 90% by mass or more). A typical example of an aqueous liquid is water or an aqueous solution.

[0059] In the production method of the present invention, the aqueous liquid in the step (ii) may be different from the aqueous solution (A) treated in the step (i). An example of this situation is given below.

[0060] (1st case)

[0061] In the first example, in the step (i), the conductive substance (C1) adsorbs at least one anion (L) contained in the ion (L) - ).

[0062] Next, in ste...

Embodiment 1

[0141] First, as shown in FIG. 9A , an activated carbon cloth of about 5 cm×6 cm was prepared, and a current collector 91 b coated with Pt on Ti was attached to the activated carbon cloth 91 a to manufacture an activated carbon electrode (ion-adsorbing electrode) 91 . In addition, the activated carbon electrode 92 was produced by the same method. In addition, Ti electrodes were coated with Pt to form counter electrodes 93 and 94 .

[0142] Next, as shown in FIG. 9B , activated carbon electrodes 91 and 92 were disposed between counter electrode 93 and counter electrode 94 , and placed in a box-shaped container with an inner volume of 100 ml. 80 ml of an aqueous NaCl solution having a concentration of 0.01 mol / liter was added to the container.

[0143] Next, a current of 100 mA (0.1A x 180 seconds = 18C) was passed between the activated carbon electrodes for 3 minutes to adsorb chlorine ions to the anode and sodium ions to the cathode in the same manner as in FIG. 1A . Then, w...

Embodiment 2

[0145] The same electrode and NaCl aqueous solution as in Example 1 were prepared, and they were arranged in the same manner as in Example 1. Next, a current of 100 mA (0.1A×180 seconds=18C) was passed between the activated carbon electrodes for 3 minutes to adsorb chlorine ions on the anode and adsorb sodium ions on the cathode. Then, without changing the solution, a current of 60 mA was applied for 20 seconds using the activated carbon electrode having adsorbed sodium ions as the anode and the counter electrode as the cathode, thereby preparing an alkaline aqueous solution. The resulting aqueous solution had a pH of 9.77.

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Abstract

In an aqueous solution (20) containing a hydrogen ion and at least one ion (L) other than a hydroxyl ion, voltage is applied across an ion adsorption electrode (11) containing an electrically conductive material (C1), which can adsorb an ion, and an ion adsorption electrode (12) containing an electrically conductive material (C2), which can adsorb an ion, so that the ion adsorption electrode (11)is an anode, whereby an anion contained in an aqueous solution (20) is adsorbed on the electrically conductive material (C1) and a cation contained in the aqueous solution (20) is adsorbed on the electrically conductive material (C2). Next, in a water-containing liquid (30), voltage is applied across any one of the ion adsorption electrode (11) or the ion adsorption electrode (12) and a counter electrode (13) or (14) to change pH of the liquid (30).

Description

technical field [0001] The invention relates to a liquid pH adjustment method and a pH adjustment device. Background technique [0002] In the past, various methods of adjusting the pH of liquids have been proposed. For example, a method of producing acidic water and alkaline water by disposing two electrodes sandwiching an ion-permeable membrane and electrolyzing salt water has been proposed (JP-A-7-299457). [0003] Also, devices capable of adjusting pH without using a diaphragm have been proposed (JP-A-4-284889 and JP-A-8-19781). In these devices, a plurality of flat electrodes are arranged at narrow intervals, and water flows between them in a laminar manner. The laminar flow of alkaline water and the laminar flow of acidic water are formed by electrolysis of the water flowing between the electrodes, and these are taken out separately to obtain alkaline water and acidic water. [0004] In these conventional devices, the oxygen gas and hydrogen ion generation reaction ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/46
CPCC02F2001/46133C02F1/4618C02F2209/06C02F2209/005C02F1/283
Inventor 棚桥正和棚桥正治
Owner TANAH PROCESS LTD