Photo-curing ink-jet nano conductive printing ink, and preparation and use method thereof
A nano-conductive and light-curing technology, applied in ink, printed circuit manufacturing, application, etc., can solve the problems of high temperature resistance of substrate materials, high curing temperature of thermosetting resin, slow curing speed of thermosetting resin, etc., to achieve Effects of shortening sintering time, lowering sintering temperature, and improving resolution
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Embodiment 1
[0042] First dissolve 5g nano silver powder (brand HDY, average particle size 43nm) in 12g ethanol and disperse ultrasonically for 20 minutes to a homogeneous solution, then add acrylic low viscosity resin EB81 under the condition of yellow light (filter out light with a wavelength less than 420nm) (100mPas, 25°C) 2g, butyl acrylate 1g, neopentyl glycol diacrylate 1g, trimethylolpropane triacrylate 0.45g, 1-hydroxycyclohexyl benzophenone 0.3g, dibenzoyl peroxide 0.1g, BYK0200.05g, BYK3730.05g, and p-hydroxyanisole 0.05g were stirred uniformly and then ultrasonically dispersed for 15 minutes to prepare a light-curable inkjet nano conductive ink with a viscosity (20°C) of 10mPa·s.
[0043] Use an inkjet printer to spray the prepared light-curable inkjet nano conductive ink on the surface of the glass substrate, expose it to a high-pressure mercury lamp (main wavelength of 365nm) for 2 minutes, and then sinter it on a controlled temperature hot stage at 180°C 10min, get the experime...
Embodiment 2
[0045] First, dissolve 5.5g nano silver powder (brand HDY, average particle size 43nm) in 15g ethyl acetate and disperse ultrasonically for 20 minutes to a homogeneous solution, and then add acrylates under the condition of yellow light (filtering out light with a wavelength less than 420nm) Viscosity resin viajet100 (100mPas, 25°C) 1.5g, N-vinylpyrrolidone 1g, neopentyl glycol diacrylate 1g, 6 ethoxytrimethylolpropane triacrylate 0.4g, 2-methyl 1-( 4-Methylmercaptophenyl)-2-morpholine 1-acetone 0.3g, dibenzoyl peroxide 0.15g, BYK0550.05g, BYK3730.05g, p-hydroxyanisole 0.05g, stir well and then ultrasonically disperse for 20 minutes Afterwards, a light-curable inkjet nano conductive ink was prepared with a viscosity (20°C) of 8 mPa·s.
[0046] Use an inkjet printer to spray the prepared light-curable inkjet nano conductive ink on the surface of the glass substrate, expose it to a high-pressure mercury lamp (main wavelength of 365nm) for 2 minutes, and then sinter it on a controll...
Embodiment 3
[0048] First, dissolve 6g nano silver powder (brand HDY, average particle size 43nm) in 20g ethyl acetate and disperse ultrasonically for 20 minutes to a homogeneous solution, and then add acrylate low viscosity under the condition of yellow light (filter out light with wavelength less than 420nm) Resin viajet100 (100mPas, 25°C) 1g, isooctyl acrylate 1g, ethoxy neopentyl glycol diacrylate 1g, 6 ethoxy trimethylolpropane triacrylate 0.4g, 2-hydroxy-2-methyl 0.3g of phenyl-1-phenylacetone, 0.15g of azobisisobutyronitrile, BYK0550.05g, Glide1000.05g, and p-hydroxyanisole 0.05g, stir uniformly, and ultrasonically disperse for 20 minutes to prepare photocurable inkjet nano Conductive ink, viscosity (20°C) is 6mPa·s.
[0049] Spray the prepared light-curable inkjet nano conductive ink on the surface of the polyester base with an inkjet printer, expose it to a high-pressure mercury lamp (main wavelength of 365nm) for 100s, and then place it on a controlled temperature hot stage at 150℃ ...
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