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Hydro-upgrading method for diesel distillate

A technology for hydrogenation, upgrading and fractionation, which is applied in refining to remove heteroatoms, etc., can solve the problems of complex process, limited improvement of cetane number, and difficult operation, and achieves simple device process, large production flexibility, Easy-to-operate effects

Active Publication Date: 2012-09-12
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] The purpose of the present invention is to overcome the disadvantages of the conventional hydro-upgrading method of diesel oil fractions, such as complex process flow, difficult operation or limited cetane number increase range, to provide a simple process, low operation difficulty and cetane Hydrogenation upgrading method of diesel fraction with large value increase

Method used

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  • Hydro-upgrading method for diesel distillate
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  • Hydro-upgrading method for diesel distillate

Examples

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Embodiment approach

[0040] According to a preferred embodiment of the present invention, the method for hydro-upgrading the diesel fraction can be figure 1 The method shown is carried out. Such as figure 1 As shown, the diesel fraction 1 with a total aromatic content of not less than 35% by weight passes through the feed oil pump 3, and is counted as 11 after being preheated, mixed with hydrogen-rich gas 20, 22, and enters the first reactor 5, and sequentially with the first hydrorefining catalyst The second hydrorefining catalyst is contacted with the hydro-upgrading catalyst to carry out deep desulfurization, denitrification, dearomatization and cetane number improvement reactions to obtain the contacted product 12, the total aromatic content of the contacted product is low 于35wt%. The diesel fraction 2 with a total aromatic content of less than 35% by weight passes through the feed oil pump 4, and is counted as 13 after preheating, mixed with the contact product 12, that is, the effluent 12 of...

Embodiment 1

[0045] This example is used to illustrate the method for hydro-upgrading diesel fraction provided by the present invention.

[0046] The feedstock oil C, which accounts for 54.5% by weight of the total feed, is in contact with hydrogen-rich gas (hydrogen content of 80% by volume), enters the first reactor after being preheated by the heating furnace, and is sequentially connected with the first hydrorefining catalyst H (the first In a reactor, 20% by volume of the second hydrorefining catalyst J), the second hydrorefining catalyst J, and the hydrorefining catalyst M are contacted, and the volume ratio of the second hydrorefining catalyst J to the hydrorefining catalyst M is 4:1. Feedstock oil A, which accounts for 15.5% by weight of the total feed, and feedstock oil B, which accounts for 30% by weight of the total feed, are mixed and preheated in a heating furnace, and then mixed with the effluent from the first reactor to enter the second reactor, followed by The first hydroref...

Embodiment 2

[0048] This example is used to illustrate the method for hydro-upgrading diesel fraction provided by the present invention.

[0049] The feedstock oil C, which accounts for 75% by weight of the total feed, is in contact with hydrogen-rich gas (hydrogen content of 60% by volume), enters the first reactor after being preheated by the heating furnace, and is sequentially connected with the first hydrorefining catalyst I (the first In a reactor, 10% by volume of the second hydrorefining catalyst J), the second hydrorefining catalyst K, and the hydrorefining catalyst N are contacted, and the volume ratio of the second hydrorefining catalyst K to the hydrorefining catalyst N is 2:1. 25% by weight of the total feed amount, the feedstock oil B and hydrogen-rich gas are mixed and preheated by a heating furnace, and then mixed with the effluent from the first reactor to enter the second reactor, and in turn with the first hydrorefining catalyst I (the first 15% by volume of the second hyd...

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Abstract

The invention discloses a hydro-upgrading method for diesel distillates, wherein, the method comprises the steps of: in the presence of a hydrorefining catalyst and a hydro-upgrading catalyst, facilitating the diesel distillates with the total aromatics content not less than 35 weight % to contact a hydrogen-rich gas in a first reactor, so that the products after the contact has the total aromatics content not less than 35 weight%; afterwards in the presence of the hydrorefining catalyst and in a second reactor, facilitating the obtained products to contact a mixture of the diesel distillateswith the total aromatics content less than 35 weight%. The hydro-upgrading method for the diesel distillates provided by the invention improves the quality of the diesel products to a large extent while maintaining high diesel yield, namely, the diesel yield is 93-99 weight%.

Description

Technical field [0001] The invention relates to a method for hydro-upgrading diesel oil fractions. Background technique [0002] As the requirements for environmental protection are getting higher and higher, the requirements of various countries on the quality of diesel products are becoming stricter. For automotive diesel, the most changed indicators in the new specifications are sulfur content and cetane number. In China's upcoming emission standards equivalent to Euro IV, diesel cetane number is required to be no less than 51, and sulfur content no more than 50 micrograms / g. [0003] On the other hand, as international crude oil prices continue to rise, domestic refineries use crude oil to reduce procurement costs, and the crude oil used by domestic refineries is getting worse, and the properties of its secondary processing oils such as catalytic diesel and coking diesel are getting worse. It is mainly manifested by high content of aromatics, low cetane number, high content o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G45/02
Inventor 蒋东红张毓莹胡志海王子文辛靖聂红
Owner CHINA PETROLEUM & CHEM CORP