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Method for producing ferrous metasilicate by using smelting waste slag of nickel, copper and cobalt

A technology of ferrous silicate and cobalt slag, which is applied in the field of copper and cobalt smelting waste to produce ferrous silicate and nickel, can solve the problems of lack of viability and sustainable development ability, pollution, no practical value, etc. Effects of mobility and chemical activity

Inactive Publication Date: 2009-09-30
牛庆君
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nickel, copper, and cobalt smelting waste slags are piled up after cooling, occupying a large amount of land and causing serious pollution to the environment
[0004] At present, my country has accumulated about 10 million tons of nickel, copper, and cobalt smelting waste slag, and it is still increasing at a rate of about 1.8 million tons per year, resulting in a great waste of resources and serious environmental pollution.
[0005] Ni, Cu, Fe, Co, S, CaO, MgO, SiO are contained in nickel, copper, and cobalt smelting waste slag 2 etc., using the nickel, copper, cobalt smelting waste slag to simply recover iron metal, there are mature technical processes at home and abroad for reference, but so far, when these technical processes are dealing with nickel, copper, cobalt smelting waste The common characteristics of these technologies are excessive energy consumption, serious secondary pollution, high comprehensive production costs, poor economic and environmental benefits, and no viability and sustainable development capabilities. Therefore, these methods are not practical value, but has not been practically promoted and used so far

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Embodiment one: a kind of method that produces ferrous silicate with nickel, copper, cobalt smelting waste slag, this processing method comprises the following steps: nickel, copper, cobalt slag are heated to molten state, heat preservation makes nickel, copper, cobalt slag Keep the molten state, wherein the nickel, copper, and cobalt slag in the molten state refer to the temperature at 1150-1300°C, and at the same time, oxygen is introduced into the nickel, copper, and cobalt slag to react to form a solid residue. The amount of oxygen introduced is Nickel, copper, cobalt slag 0.4-1 cubic meter per ton, the time of introducing oxygen is 5-10 minutes, until this solid residue is no longer generated, at this time the hot slag is divided into three layers, namely the solid scum in the upper layer, the middle part Liquid ferrous silicate, the bottom slag of the lower layer, and then remove the solid scum of the upper layer, remove the bottom slag of the lower layer, that is,...

Embodiment 2

[0024] Embodiment two: a kind of method that produces ferrous silicate with nickel, copper, cobalt smelting waste slag, this processing method comprises the following steps: nickel, copper, cobalt slag are heated to molten state, heat preservation makes nickel, copper, cobalt slag Keep the molten state, wherein the molten nickel, copper, and cobalt slag refer to the temperature at 1150-1300°C, and at the same time, air is introduced into the nickel, copper, and cobalt slag to react to form solid residues, and the amount of air introduced is 2-5 cubic meters of nickel, copper, and cobalt slag per ton, and the time for introducing air is 5-10 minutes until the solid residue is no longer generated. Liquid ferrous silicate, the bottom slag of the lower layer, and then remove the solid scum of the upper layer, remove the bottom slag of the lower layer, that is, the heavy metal layer of nickel, copper, and cobalt slag in molten state, and the lower layer accounts for 4-6% of the tota...

Embodiment 3

[0025] Embodiment three: a kind of method that produces ferrous silicate with nickel, copper, cobalt smelting waste slag, this processing method comprises the following steps: nickel, copper, cobalt slag are heated to molten state, heat preservation makes nickel, copper, cobalt slag Keep the molten state, wherein the molten nickel, copper, and cobalt slag refer to the temperature at 1150-1300°C, measure the content of potassium ions and sodium ions in nickel, copper, and cobalt slag, when the weight percentage of potassium ions is greater than 0.05% , when the weight percentage of sodium ions is greater than 0.05%, pass into nickel, copper, cobalt slag so that the chlorine gas that reacts to generate solid residue, the amount of passing through chlorine gas is 0.1-0.25 cubic meters per ton of nickel, copper, cobalt slag The feeding time of chlorine gas is 5-10 minutes; until the solid residue is no longer generated, the thermal slag is divided into three layers, namely the uppe...

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PUM

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Abstract

The present invention relates to a comprehensive utilization technology for smelting waste slag of nickel, copper and cobalt, especially a method for producing ferrous metasilicate by purifying the smelting waste slag of nickel, copper and cobalt with a high temperature thermal solution status. The method includes the steps of a. heating the nickel, copper and cobalt slag to a molten state or fetching the nickel, copper and cobalt slag of the molten state directly; b. holding the nickel, copper and cobalt slag with the molten state by heat insulation, at the same time infusing oxygen or air into the nickel, copper and cobalt slag to react to generate solid residue; c. removing the solid residue; the method of the invention is energy-saving and environment protection, has low cost, and it is capable of producing ferrous metasilicate products by purifying the nickel, copper and cobalt smelting waste slag with a thermal solution status.

Description

technical field [0001] The invention relates to a comprehensive utilization technology of nickel, copper and cobalt smelting waste slag, in particular to a method of purifying and removing impurities from nickel, copper and cobalt smelting waste slag in a high-temperature hydrothermal state to produce ferrous silicate products A method for producing ferrous silicate by using nickel, copper and cobalt smelting waste slag. Background technique [0002] Nickel, copper, and cobalt are all non-ferrous metals, which are widely used in the national economy, especially in steel, aerospace, electromechanical, electric power, telecommunications, inorganic chemicals, and new material industries. The pyro-process nickel, copper and cobalt smelting industry is an important branch of the non-ferrous metallurgy industry and an important non-ferrous metal raw material industry. SiO in charge during nickel, copper and cobalt smelting 2 , CaO, MgO, Al 2 o 3 , Fe 3 o 4 The mixture enters...

Claims

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Application Information

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IPC IPC(8): C01B33/20
Inventor 牛庆君
Owner 牛庆君
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