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Tin soldering alloy and tin soldering conjugant using the same

A joint body and solder technology, applied in the field of solder alloys and solder joint bodies using the solder alloys

Inactive Publication Date: 2010-12-01
HITACHI METALS LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The object of the present invention is to overcome the defects of existing solder alloys and provide a new type of solder alloy. The characteristics of the Sn-Ag-Al based solder alloy of the bonding material, and the ability to suppress the change of the solder alloy over time, is very suitable for practical use

Method used

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  • Tin soldering alloy and tin soldering conjugant using the same
  • Tin soldering alloy and tin soldering conjugant using the same
  • Tin soldering alloy and tin soldering conjugant using the same

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0062] Sn, Ag, Al, Sb, Y, and Ge were weighed so as to have the composition shown in Table 1, then melted, and the alloy melts obtained in pairs were poured into a mold to produce a solder alloy, and the following evaluation tests were performed.

[0063] (Evaluation Test 1)

[0064] A borosilicate glass plate (product name TEMPAX) cut into 30 mm square and 3 mm thick was placed on a hot plate heated to 350° C. as a material to be joined, and preheated. Thereafter, using a soldering iron tip to which ultrasonic vibration was applied (ultrasonic welding device SUNBUNDER USM-III manufactured by Kuroda Technology Co., Ltd.), the solder alloy was coated on one surface of the glass plate so that the thickness of the solder alloy became 100 μm, and the Allow to cool slowly. Next, the sample cooled to room temperature was cut with a cutter so that the solder surface of the sample had a grid-like 5×5 grid of 5 mm square, and a peel test piece was produced.

[0065] In order to confi...

example 2

[0083] Weigh Ag, Al, Sb, Y, Ge and Sn, so that it becomes Ag=8.5%, Al=0.35%, Sb=2.0%, Y=0.075%, Ge=0.03%, remaining Partly having a composition of Sn (Al / Sb=0.18), the solder alloy of the present invention was produced by melting in an Ar gas atmosphere, and pouring the resulting alloy melt into a mold. Similarly, in the comparative example, no Sb was added, and a solder alloy in which Ag=8.5%, Al=0.35%, Y=0.075%, Ge=0.03%, and the remainder was Sn was produced in the same manner. The following evaluation tests were performed on the prepared solder alloys.

[0084] (Evaluation Test 1)

[0085] First, a borosilicate glass plate (product name TEMPAX) cut into a 50 mm square and 3 mm thick was placed on a hot plate heated to 350° C. as a material to be joined, and heated in advance. Thereafter, using a soldering iron tip (ultrasonic welding device SUNBUNDER USM-III manufactured by Kuroda Technology Co., Ltd.) to which ultrasonic vibrations were applied, the solder alloy of the ...

example 3

[0098] After weighing Ag, Al, Sb, and Sn so that it becomes Ag=3.5%, Al=0.10%, Sb=1.5% and the remainder being Sn (Al / Sb=0.07), the Melting was carried out in an Ar gas atmosphere, and then the resulting alloy melt was poured into a mold to produce the solder alloy of the present invention. The following evaluation tests were performed on the prepared solder alloys.

[0099] (Evaluation Test 1)

[0100] An alumina plate (manufactured by Nikkato Co., Ltd., product name: SSA-S) cut into 25 mm square and 2.5 mm thick was set on a hot plate heated to 270° C. as a material to be joined, and heated in advance. Thereafter, using a soldering iron tip to which ultrasonic vibrations were applied (ultrasonic welding device SUNBUNDER USM-III manufactured by Kuroda Technology Co., Ltd.), the solder alloy of the present invention was coated on one surface of an alumina plate so that the thickness thereof became 130 μm. Cool slowly in the atmosphere. The surface of the solder applied afte...

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Abstract

The present invention relates to a novel tin soldering alloy and a tin soldering conjugant using the same, wherein the tin soldering alloy is capable of keeping the characteristics of Sn-Ag-Al series tin soldering alloy of jointing oxide of glass and ceramic and the like, hard grafting material of Mo and the like with difference wettability, and capable of restraining the characteristics from varying along the time. The tin soldering alloy contains (by weight percentage): 0.9%-10.0% of Ag, 0.01%-0.50% of Al, and 0.04%-3.00% of Sb, a rate of Al and Sb is equal to or less than 0.25 but not equal to 0, the balance is Sn and unavoidable impurities. Furthermore, the tin soldering alloy also contains one or two of no more than 1.0% of Y and no more than 1.0% of Ge.

Description

technical field [0001] The present invention relates to a solder alloy and a solder joint body using the solder alloy, and in particular to a member suitable for joining oxides such as glass or ceramics or having an oxidized surface such as aluminum (Al) or the like Solder alloys such as Mo having poor wettability, and solder joints using the same. Background technique [0002] Among the conventional techniques for bonding oxides such as glass, the mainstream method used for bonding and sealing at around 380° C. is to use lead solder or lead glass frit. However, it becomes impossible to use lead due to environmental problems, so that alternative techniques must be established. Therefore, the inventors of the present invention proposed a solder alloy containing Sn as a main component and adding Ag and Al as a solder alloy for oxide bonding used for bonding of glass or the like (WO2007 / 7840 A). Furthermore, the inventors of the present invention proposed a solder alloy in wh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C13/00
Inventor 森胁隆行千绵伸彦
Owner HITACHI METALS LTD