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Catalyst for C8 aromatics isomerization reaction technology and preparation method thereof

A carbon eight aromatic hydrocarbon and catalyst technology, applied in the field of catalyst and its preparation, can solve the problems of high reaction equipment and operation requirements, complex reaction process and catalyst, complex catalyst system flow, etc., and achieves good reaction stability and improved reaction activity. with high selectivity, reactivity and selectivity

Inactive Publication Date: 2012-05-23
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

In this new type of catalytic material called Molecules Sieve (MS), it was discovered that by adding certain substances into an organic compound mixture containing benzenes or naphthols, they could effectively separate different types of chemical components from each other without affecting their properties such as structure or reactiveness. These materials were found effective even when combined together under specific conditions during synthesis processes. They showed improved efficiency over traditional methods like acid treatment alone while maintaining excellent performance on various products produced through these techniques.

Problems solved by technology

Technological Problem addressed in this patents is how efficiently produce para-mtoluenced naphtha (C10+M/ZL) through decomposition of aliphered compounds called phytanes during pyridine formation processes like dimerization and decislation of α-,β-unsaturated carboxylic acids (α,ω)-dimensiloxynanone). Current methods involve expensive metals and zeolite catalysis systems, leading to increased costs associated therewith.

Method used

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  • Catalyst for C8 aromatics isomerization reaction technology and preparation method thereof
  • Catalyst for C8 aromatics isomerization reaction technology and preparation method thereof
  • Catalyst for C8 aromatics isomerization reaction technology and preparation method thereof

Examples

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Embodiment 1

[0032] 1) Take SiO2 2 / Al 2 o 3 50 parts of hydrogen-type ZSM-11 molecular sieve with a molar ratio of 60, impregnated with 8% benzyl silicone oil in petroleum ether solution, volatilized and removed the solvent petroleum ether after impregnation, dried at 120°C and roasted at 530°C to complete ZSM-11 modified by liquid phase silicon deposition method to obtain 3.1wt% SiO 2 / ZSM-11; the above-mentioned molecular sieve is further impregnated with 3.0wt% ammonium molybdate solution, dried at 120°C for 2 hours and then calcined at 480°C for 2 hours to complete the molybdenum oxide loading modification of the molecular sieve and obtain 1.8wt% Mo / 3.1wt%SiO 2 / ZSM-11; 2) Take SiO 2 / Al 2 o 3 40 parts of hydrogen-type Beta molecular sieves with a molar ratio of 24, the molecular sieves were impregnated with 4.0wt% lanthanum nitrate solution, dried at 120°C for 2 hours, and then calcined at 500°C for 2 hours to complete the metal lanthanum oxide loading modification and obtain 2...

Embodiment 2

[0034] 1) Take SiO2 2 / Al 2 o 3 30 parts of hydrogen-type ZSM-5 molecular sieves with a molar ratio of 25, impregnated with 15% petroleum ether solution of methyl silicone oil, volatilized and removed the solvent petroleum ether after impregnation, dried at 120°C and then roasted at 500°C to complete ZSM -5 modified by liquid phase silicon deposition method to obtain 5.7wt% SiO 2 / ZSM-5; the above-mentioned molecular sieve is further impregnated with 1.2wt% palladium nitrate solution, dried at 120°C for 2 hours and then roasted at 550°C for 2 hours to complete the metal palladium oxide-loaded modification of the molecular sieve and obtain 0.58wt% Pd / 6.7wt% SiO 2 / ZSM-5; 2) Take SiO 2 / Al 2 o 3 50 parts of hydrogen-type MCM-22 molecular sieves with a molar ratio of 20, impregnating the molecular sieves with 7.0 wt% magnesium nitrate solution, drying at 120°C for 2 hours, and then roasting at 480°C for 2 hours to complete the metal magnesium oxide loading modification, O...

Embodiment 3

[0036] 1) Take SiO2 2 / Al 2 o 3 10 parts of hydrogen-type EU-1 molecular sieve with a molar ratio of 20, impregnated with 20% petroleum ether solution of methyl silicone oil, volatilized and removed the solvent petroleum ether after impregnation, dried at 120°C and roasted at 490°C to complete EU -1 modified by liquid phase silicon deposition method to obtain 8.2wt% SiO 2 / EU-1; ​​the above-mentioned molecular sieve was further impregnated with 12.5wt% nickel nitrate solution, dried at 120°C for 2 hours and then calcined at 510°C for 2 hours, that is, the metal nickel oxide loading modification of the molecular sieve was completed, and 8.7wt% Ni was obtained / 6.7wt% SiO 2 / EU-1; ​​2) Take SiO 2 / Al 2 o 3 50 parts of hydrogen-type MOR molecular sieves with a molar ratio of 8, the molecular sieves were impregnated with 1.0wt% cerium nitrate solution, dried at 110°C for 2 hours, and then calcined at 490°C for 2 hours to complete the metal cerium oxide loading modification a...

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Abstract

The invention relates to a catalyst for C8 aromatics isomerization reaction technology and a preparation method thereof. The composite reaction catalyst compounded by two different molecular sieve components modified by different methods according to a certain ratio, wherein one component has high-selectivity catalytic action on xylene isomerization and the other component has shape selective catalysis action on ethylbenzene deethylation. Due to the high-selectivity catalytic action of the composite molecular sieve catalyst, high-selectivity catalysis for dealkylation reaction of ethylbenzenein C8 mixed aromatics and the reaction that m-xylene and o-xylene are isomerized into p-xylene can be simultaneously realized. In the reaction technology of isomerization and dealkylation in the C8 mixed aromatics, a fixed bed reactor is adopted, the C8 mixed aromatics are taken as raw materials (an aromatic mixture mainly comprises m-xylene, o-xylene and ethylbenzene) and subjected to reaction at the temperature of between 350 and 460 DEG C and the airspeed of 2.5 to 15h<-1> and under the pressure of 0.5 to 3.0MPa. The reaction catalyst has high reaction activity, selectivity and stability, simplifies the process flow of the reaction and can obviously reduce the energy consumption and production cost.

Description

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Claims

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Application Information

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Owner TONGJI UNIV
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