Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Cerium-based composite oxide catalyst for catalyzing and purifying nitric oxide

A composite oxide and nitrogen oxide technology, applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, catalyst activation/preparation, etc., can solve the problem of narrow operating temperature window and sensitive reaction space velocity. , poor low temperature activity, etc., to achieve the effect of improving service life, reducing harm, and good resistance to high temperature sintering

Active Publication Date: 2014-03-26
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
View PDF2 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to solve the problem of narrow operating temperature window, poor low-temperature activity, and N 2 Due to the shortcomings of low selectivity and sensitivity to reaction space velocity, the present invention provides a novel cerium-based composite oxide catalyst and its preparation method for the first time, which can be used as mobile sources represented by diesel vehicle exhaust and flue gas from coal-fired power plants. The representative stationary source NO x Catalytic purification

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Cerium-based composite oxide catalyst for catalyzing and purifying nitric oxide
  • Cerium-based composite oxide catalyst for catalyzing and purifying nitric oxide

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-4

[0016] Dissolve ammonium tungstate in oxalic acid solution (mass ratio of ammonium tungstate to oxalic acid is 1:1), and add cerium nitrate solution to the solution to prepare a solution with a Ce / W molar ratio of 0.5 and mix evenly. Add excess urea to the mixture, and continuously stir at 90°C for 12 hours, then perform suction filtration and washing, put the filter cake in an oven and dry it overnight at 100°C, and finally calcinate it in the air at 500°C in a muffle furnace for 5 hours. A powdered catalyst was obtained. The prepared catalyst was pressed into tablets, crushed, sieved, and 40-60 meshes were taken for later use, which was called catalyst A. Catalysts B and C were prepared respectively by changing the Ce / W molar ratio to 1.0 and 2.0 while other conditions remained unchanged. Catalyst D was prepared by calcining catalyst B in air at 800°C for 1 h.

Embodiment 5

[0018] With the cerium-tungsten composite oxide catalyst A, B, C and D that embodiment 1-4 makes, carry out NH on self-made miniature fixed-bed reactor 3 Selective Catalytic Reduction of NO x The investigation of reactivity. The consumption of catalyst is 0.12ml, and the composition of reaction gas mixture is: [NO]=[NH 3 ]=500ppm, [O 2 ] = 5%, N 2 As balance gas, the total gas flow rate is 500ml / min, and the space velocity is 250,000h -1 , The reaction temperature is 150-450°C. NO and NH 3 and by-product N 2 O, NO 2 All were measured using an infrared gas cell. The reaction results are shown in Table 1.

[0019] Catalyst B at 250,000h -1 Under the condition of space velocity, more than 80% NO can be achieved in the temperature range of 200-450°C x conversion rate, and at N 2 The selectivity is greater than 97%. Catalyst D calcined at 800°C can still be used at 250,000h -1 Under space velocity conditions, over 80% NO can be achieved within the temperature range of...

Embodiment 6

[0021] Using catalyst B, the effect of reaction space velocity on catalyst activity was investigated in a self-made miniature fixed-bed reactor. The consumption amount of catalyst is respectively 0.3ml, 0.12ml, 0.06ml, and the composition of reaction gas mixture is: [NO]=[NH 3 ]=500ppm, [O 2 ] = 5%, N 2 As balance gas, the total gas flow rate is 500ml / min, and the corresponding space velocity is 100,000h -1 、250,000h -1 , 500,000h -1 , Reaction temperature 150 ~ 450 ℃. NO and NH 3 and by-product N 2 O, NO 2 All were measured using an infrared gas cell. The reaction results are shown in Table 2.

[0022] Catalyst B at a space velocity of 100,000h -1 Under certain conditions, more than 98% of NO can be achieved in the temperature range of 200-450°C x conversion rate, and N 2 The generation selectivity is greater than 98%, showing a very wide operating temperature window; even at 500,000h -1 Under the condition of high space velocity, Catalyst B can still achieve mor...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

Disclosed is a Ce-based composite oxide catalyst for selective catalytic reducing nitrogen oxides with ammonia, which comprises Ce oxide and at least one oxide of transition metal except Ce. The Ce-based composite oxide catalyst is prepared by a simple method which uses non-toxic and harmless raw materials, and it has the following advantages: high catalytic activity, and excellent selectivity for generating nitrogen etc. The catalyst can be applied in catalytic cleaning plant for nitrogen oxides from mobile and stationary sources.

Description

technical field [0001] The invention is applied to the technical field of environmental catalysis, and relates to a cerium-based composite oxide catalyst used for catalytic purification of nitrogen oxides from mobile sources represented by diesel vehicle exhaust and stationary sources represented by flue gas from coal-fired power plants. Background technique [0002] Nitrogen oxides (NO x , mainly referring to NO and NO 2 ) will cause major environmental problems such as photochemical smog, acid rain, greenhouse effect and ozone layer depletion, and at the same time have biological respiratory toxicity, which can cause great harm to the ecological environment and human health. Therefore, how to effectively remove NO x It has become a hot issue in the field of environmental protection today. [0003] With the increasing shortage of oil resources, CO 2 The pressure to reduce emissions is increasing, and more and more attention has been paid to diesel vehicles with good fue...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/30B01J23/888B01D53/94B01D53/86B01D53/56
CPCB01D2255/40B01J23/8885B01D53/9418B01J23/002B01D2255/20776B01D2251/2062B01J23/881B01J23/28Y02T10/24B01J37/031B01J23/30B01J35/04B01D2255/20769B01J23/888B01D2255/20738B01J23/83B01D53/565B01D2255/2065B01J37/038B01D2251/202B01J23/10B01J37/0009B01J2523/00Y02A50/20Y02T10/12B01J35/56B01J2523/3712B01J2523/68B01J2523/69B01J2523/842
Inventor 贺泓单文坡刘福东石晓燕张长斌王少莘
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com