Quick synthesizing method of triazinyl covalent bond organic framework material with nano pores and application thereof

An organic framework and nano-hole technology, applied in the field of nano-hole triazine-based covalent bond organic framework materials, can solve the problems of high production cost, low production efficiency, large production energy consumption and the like
CN102190797AInactive Publication Date: 2011-09-21ANHUI UNIVERSITY
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Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
ANHUI UNIVERSITY
Publication Date
2011-09-21
Estimated Expiration
Not applicable · inactive patent

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Abstract

The invention relates to a quick synthesizing method of a triazinyl organic framework material with nano pores, a triazinyl organic oligomer and a triazinyl organic compound and application thereof. In the presence of a Lewis acid as well as in the presence that an inorganic salt fusing assistant exists or does no exist in at least one single nitrile-based and / or multi-nitrile-based organic compound and under the condition of microwave radiation, the covalent bond organic framework material with a triazinyl structure and nano pores, the triazinyl organic oligomer or the triazinyl organic compound is generated, wherein pores or channels which are positioned in at least one direction in space and have size of over 0.3nm are arranged inside the obtained triazinyl covalent bond organic framework solid. The method provided by the invention has the advantages of short required synthesis time, high production efficiency and low production energy consumption; and the products have wide application range.
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Description

technical field

[0001] The invention belongs to a nano-hole triazine-based covalent bond organic framework material, a triazine-based organic oligomer, and a rapid synthesis method of a triazine-based organic compound and an application thereof. Background technique

[0002] Nanoporous covalent organic framework materials are a new class of porous materials, which are different from metal organic framework materials, another new type of porous materials that have been developed rapidly in recent years. Covalent organic frameworks are formed by covalent bonds, including H, C, O, B and other elements. Compared with other porous materials, covalent organic framework materials have the characteristics of lower density, higher specific surface area, and better thermal stability (thermal stability can reach 500°C).

[0003] There have been some literature reports on the synthesis and application of nanoporous covalent organic framework materials, such as Mastalerz M. et al. in An...

Claims

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