Binder for jet printing inks, jet printing inks containing same, and printed matter
An inkjet printing and adhesive technology, applied in printing, ink, application and other directions, can solve the problems of fading, deterioration and damage of printed images, and achieve the effect of good storage stability, high-definition and bright printed images
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[0127] Hereinafter, the present invention will be described more specifically using examples and comparative examples.
Synthetic example 1
[0128] [Synthesis Example 1] Preparation of Organic Solvent Solution (a1-1) of Hydrophilic Group-Containing Polyurethane
[0129] 376 parts by mass of polyoxytetramethylene glycol (PTMG-2000 manufactured by Mitsubishi Chemical Co., Ltd.) with a number average molecular weight of 2000 was added to a reaction vessel equipped with a stirrer, a thermometer, a dropping funnel, a condenser tube, and a nitrogen inlet. 93 parts by mass of isophorone diisocyanate (IPDI) was heated up to 100° C. and reacted at the same temperature for 1 hour.
[0130] Next, the temperature was lowered to 80° C., 31 parts by mass of dimethylolpropionic acid (DMPA) and 269 parts by mass of methyl ethyl ketone (MEK) were put into the above-mentioned reaction vessel, and then reacted at 80° C. for 5 hours, and then, 231 parts by mass of isopropanol (IPA) was dropped into the above-mentioned reaction vessel and diluted to obtain an organic solvent solution (a1-1) of 50 mass % of non-volatile components of po...
Synthetic example 2
[0131] [Synthesis Example 2] Preparation of Organic Solvent Solution (a1-2) of Hydrophilic Group-Containing Polyurethane
[0132] Add polycarbonate polyol with a number average molecular weight of 2000 having a 1,6-hexanediol skeleton (manufactured by Ube Industries, Ltd.) UH-200) 376 parts by mass and 93 parts by mass of isophorone diisocyanate were heated up to 100° C. and reacted at the same temperature for 1 hour.
[0133] Next, the temperature was lowered to 80° C., and 31 parts by mass of dimethylolpropionic acid (DMPA) and 269 parts by mass of methyl ethyl ketone (MEK) were charged into the reaction vessel, followed by further reaction at 80° C. for 5 hours.
[0134] Next, 231 parts by mass of isopropyl alcohol (IPA) was poured into the above-mentioned reaction vessel for dilution to obtain an organic solvent having a weight-average molecular weight of 36,000 and a hydrophilic group-containing polyurethane with a non-volatile content of 50% by mass. Solution (a1-2).
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