2615 results about "Polysiloxene" patented technology

The invention discloses an aerogel fire extinguishing agent for fire fighting, a fire extinguishing device and a releasing method.The aerogel fire extinguishing agent for fire fighting is prepared from, by mass, 8-12 parts of silicon dioxide aerogel powder, 40-45 parts of perfluorohexanone, 1.5-2 parts of zinc molybdate, 0.8-1.2 parts of nano cerium oxide, 2-3 parts of hyperbranched polysiloxane and 0.2-0.3 part of 18-crown-6 ether. Solid-phase silicon dioxide aerogel powder is matched with liquid-phase perfluorohexanone, zinc molybdate, nano cerium oxide, hyperbranched polysiloxane, 18-crown-6 ether and the like are compounded to serve as auxiliaries, efficient fire extinguishing can be conducted on precise electrical elements, residues are few, loss of instruments and equipment is small, and the fire extinguishing agent is suitable for being applied to the electrical field.

The invention relates to the technical field of cable materials, and provides a flexible EVA cable sheath material and a preparation method thereof. The cable sheath material is prepared from the following raw materials in parts by weight: 25 to 50 parts of ethylene-vinyl acetate copolymer EVA, 15 to 30 parts of ultra-low density polyethylene, 2 to 10 parts of grafted EVA, 2 to 10 parts of flame retardant, 2 to 10 parts of polydopamine modified montmorillonite-boron nitride fiber composite material, 0.5 to 3 parts of flexibilizer, 0.2 to 1 part of silicone and 0.2 to 1 part of organopolysiloxane. A grafting monomer for grafting EVA comprises maleic anhydride and / or an acrylate compound; the polydopamine modified montmorillonite-boron nitride fiber composite material is prepared from montmorillonite, boron nitride fibers, hydroxylated lignin, dopamine hydrochloride and polyethyleneimine through a reaction. Various functional raw materials are compounded, and the obtained cable sheath has good flexibility, flame retardance, thermal deformation resistance, aging resistance and mechanical performance.

The invention belongs to the technical field of coatings, and relates to a polysiloxane epoxy hybrid environment-friendly coating and a preparation method thereof. The coating belongs to an environment-friendly solvent type coating with low VOC content, modified epoxy resin is adopted as a base, auxiliaries such as a film-forming agent and a dispersing agent are added, and benzophenone and tertiary amine composite photoinitiator is supplemented, so that the prepared coating has good corrosion resistance, high temperature resistance and the like, and the coating can quickly form a film at normal temperature and under the UV illumination condition, shortens the curing period, and is suitable for large-scale popularization and application. The emission of VOC (volatile organic compounds) is reduced.

The invention provides a compressible high-thermal-conductivity graphene thermal interface material and a preparation method thereof. The preparation method comprises the following steps: preparing a graphene oxide film with low structural unit thickness by adopting a centrifugal spin-coating film casting method, performing limited thermal expansion delamination, compounding with polysiloxane, and performing directional lamination to obtain a highly-oriented graphene / organic silicon composite material. And applying shear stress after pressurizing and densifying along the normal direction of the graphene sheet layer, so that the graphene structure unit forms a continuous buckling structure which is high in density and easy to compress. The densification process promotes the interaction among delamination structure units, broadens a phonon transmission channel, inhibits phonon-boundary scattering, enhances the comprehensive heat-conducting property, plays a role in promoting stress transmission among graphene, and ensures the formation of a continuous buckling structure under shear stress. A continuous buckling structure and a relatively low structure unit thickness (llt in the graphene structure unit; and the compression modulus of the densified vertical graphene array is jointly reduced by means of high density, high thermal conductivity and high compressibility of an existing thermal interface material, and the method can be applied to the fields of new energy automobiles, high-power chips, aerospace electronic equipment and the like, and the problem that high density, high thermal conductivity and high compressibility of the existing thermal interface material are difficult to consider at the same time is solved.

The invention relates to an automobile paint surface protective film agent and a preparation method thereof, and belongs to the technical field of automobile beauty. The automobile paint surface protective film agent is prepared from the following raw materials: amino functional polysiloxane, fluorine modified acrylic resin, epoxy modified organic silicon emulsion, functional filler, a surfactant, hydrophobic modified silicone oil, a brightening agent, a penetrating agent, a cosolvent and deionized water, and the raw materials are blended to prepare the automobile paint surface protective film agent. The functional filler is prepared by firstly carrying out surface modification on a polymer and then carrying out click chemistry on dodecanethiol on hydroxylated nano silicon dioxide, and the polymer is prepared by carrying out nucleophilic addition on poly (ethylene glycol) methacrylate Mn360, poly (ethylene glycol) methacrylate Mn500 and isophorone diisocyanate. The automobile paint surface protective film agent is high in film forming speed, a formed film layer has the characteristic of multiple effects, and meanwhile, the wear resistance is also very good.

The invention relates to the technical field of PC transparent flame-retardant toughening modification, in particular to phenolic hydroxyl-terminated modified polysiloxane with a side chain containing phenyl and sulfonate groups and a preparation method of copolymerized PC. The modified polysiloxane is prepared by the following steps: performing ring opening polymerization on phenol-containing double end sockets and cyclotetrasiloxane to obtain modified polysiloxane containing double bonds and phenyl functional groups, and grafting sulfonate through a thiol-ene click chemical reaction. Diphenyl carbonate, bisphenol A and the modified polysiloxane are used as raw materials, a polysiloxane-PC block copolymer is formed through copolymerization, efficient flame retardance and high transparency are achieved, and meanwhile extremely high low-temperature impact strength is achieved.

The invention provides a sidewalk antiskid terrace material and a construction process thereof, and belongs to the technical field of terrace material manufacturing. The sidewalk antiskid terrace material is prepared from the following components: epoxy resin, polysiloxane elastic resin, fluorocarbon resin, modified covalent organic framework nanosheets, boron nitride nanotubes, nano silicon nitride particles, nano silicon dioxide, nano zinc oxide, a modified flame retardant, attapulgite, a curing agent, an accelerant, a flatting agent, a coupling agent and a dispersing agent. According to the sidewalk antiskid terrace material, various high-performance resins are compounded with the nano filler to form a coating with a compact and uniform structure, so that the mechanical strength and wear resistance of the terrace are remarkably improved. In addition, due to the application of the modified flame retardant, the floor has a good flame-retardant effect, and the safety is improved. The whole formula and the construction process are scientific and reasonable, strong adhesion of the coating is ensured, construction is simple and convenient, curing is sufficient, and the coating is suitable for long-term use of outdoor sidewalks and has attractive appearance and practicability.

The invention discloses a sulfydryl silicon resin, a UV light-cured organic silicon optical adhesive as well as a preparation method and application thereof. The optical adhesive comprises sulfydryl silicon resin, vinyl polysiloxane and a photoinitiator, the molar ratio of sulfydryl in the sulfydryl silicon resin to vinyl in the vinyl polysiloxane is (1.2-1.5): 1; the molar ratio of vinyl in the vinyl polysiloxane to the photoinitiator is 1: (0.3-1.8). The optical adhesive disclosed by the invention can be subjected to rapid photocuring based on a click reaction of sulfydryl-vinyl, the preparation method of the optical adhesive does not need a solvent, and compared with conventional OCA, the optical adhesive has a certain filling advantage in the aspect of a full-lamination process, also has relatively high binding power, relatively low stress relaxation rate and excellent creep recovery rate, and can be used for preparing the optical adhesive. Therefore, the optical adhesive is especially suitable for flexible display application scenes represented by folding screens.

The invention relates to the technical field of glazes, and discloses a high-performance ceramic glaze for bacteriostatic domestic porcelain and a preparation method thereof. The high-performance ceramic glaze of the antibacterial domestic porcelain is prepared from the following raw materials in parts by weight: 5 to 15 parts of albite, 20 to 30 parts of potassium feldspar, 10 to 30 parts of kaolin, 13 to 26 parts of quartz, 0.3 to 7 parts of talc, 5 to 10 parts of limestone, 2 to 5 parts of ludwigite, 0.5 to 1 part of rare earth, 2 to 5 parts of honeysuckle-loaded CuS, 1 to 3 parts of modified polysiloxane, 0.1 to 0.5 part of sodium tripolyphosphate and 0.1 to 0.3 part of carboxymethyl cellulose. The high-performance ceramic glaze for the antibacterial domestic porcelain prepared by the invention has relatively good long-acting antibacterial performance and high strength.

The invention discloses a large-current-carrying-capacity flexible power cable, which belongs to the technical field of cable preparation, is used for solving the technical problem that the flame retardant property and the mechanical property of the power cable need to be further improved in the prior art, and specifically comprises a cable core, a wrapping layer, an insulating layer and a sheath layer which are sequentially arranged from inside to outside. The preparation method comprises the following steps: preparing alkoxy silane containing a benzocyclobutene group, preparing flame-retardant particles by using a sol-gel method, preparing modified polyurethane by using modified polysiloxane and 2, 5-furandimethanol as soft segments, naphthalene diisocyanate as a hard segment and trimethylolpropane as a chain extender, and preparing the flame-retardant flame-retardant polyurethane. The linear low-density polyethylene, the MAH-g-PE, the modified polyurethane, the flame-retardant particles and the auxiliary additive are melted and extruded outside the wire core to form the insulating layer, so that the power cable is obtained, the flame-retardant property of the power cable is effectively improved, and the mechanical property and the current-carrying stability of the power cable are also improved.

The invention discloses silencing and mildew-proof organic silica gel as well as a preparation method and application thereof, and belongs to the technical field of organic silicon binding material polymers. Comprising the following components in parts by weight: 35-45 parts of nano calcium carbonate, 32-40 parts of hydroxyl-terminated polysiloxane, 5-9 parts of silencing powder, 0.5-2.5 parts of glass fiber powder, 5-9 parts of a hyperbranched polymer, 2-5 parts of a hydrophobic surface modifier, 1.5-3 parts of color paste, 1-2 parts of a water-based coupling agent, 1-2 parts of a cross-linking agent, 0.5-2.5 parts of a mildew preventive, 0.4-2 parts of a composite titanide and 0.4-0.7 part of nano silver powder. According to the invention, the nano silver powder and the mildew preventive are compounded, and an inorganic sterilization system is combined, so that broad-spectrum environment-friendly bacteriostasis is realized, and high-humidity long-acting protection is met; the powder is subjected to hydrophobic treatment, moisture is blocked, and high adhesion is kept; silencing powder serves as a core, a sound absorption network is cooperatively formed, the noise reduction capacity is improved, and the device is suitable for multiple scenes.

The invention relates to the technical field of optical materials, and discloses organic silicon micropowder as well as a preparation method and application thereof. The organic silicon micro powder is composed of a plurality of polysiloxane microspheres, the surface relative smoothness of each polysiloxane microsphere is R, 1.02 < = R < = 1.30, R = Rq / Ra, Rq is the root mean square surface roughness of the polysiloxane microspheres, and Ra is the average surface roughness of the polysiloxane microspheres; the relative size uniformity of the organic silicon micro-powder is RSU, RSU = 1-phi / d2 > = 0.992, phi is the variance of the diameter of the organic silicon micro-powder, and d is the average diameter of the organic silicon micro-powder. The organic silicon micropowder has the advantages of higher light utilization rate, higher light transmittance and good light scattering and diffusion uniformity; after the material is applied to a light diffusion material, the light control fineness is high, the light transmittance and diffusivity are good, and the light transmittance and brightness are higher; and the flatness of the coating formed when the coating is used as a raw material for forming the coating is good.

The invention discloses an aircraft fairing and a fairing body composite material integrated forming process, and relates to the technical field of aviation equipment manufacturing. The forming process comprises the following steps: 1) preparing a prepreg; (2) sectional forming; 3) a curing process; (4) demolding and trimming; 5) an assembly process; the whole of the front section, the middle section and the tail section of the fairing is of a long-size U-shaped streamline structure. According to the invention, through molecular collaborative design of fluorination modification-polysiloxane toughening-cyanate ester interpenetration, the key contradiction of a high-performance fairing material is systematically solved; ultrahigh strength and toughness are realized at the same time by utilizing in-situ nano microphase separation; a dense graphite carbon layer is generated through catalysis, so that efficient halogen-free flame retardance is achieved; by means of the partition design of molecular fluorination and surface metallization, the high wave transmission and lightning protection functions are ingeniously unified. And finally, a new generation of aircraft fairing composite material with force bearing, wave transmission, heat resistance, impact resistance and environmental stability is successfully prepared.

The invention discloses two-component addition type low-density liquid foaming silicone rubber and a preparation method thereof, and belongs to the technical field of silicone rubber preparation. Comprising a component A and a component B, the component A is prepared from the following components in parts by weight: 50 to 70 parts of vinyl terminated polysiloxane, 10 to 20 parts of vinyl hydroxyl silicone oil, 0.5 to 2 parts of platinum catalyst, 15 to 25 parts of HGM (at) PN-rGO / APP and 3 to 8 parts of methyl vinyl MQ resin; the component B is prepared from the following components in parts by weight: 50 to 60 parts of vinyl-terminated polysiloxane, 8 to 15 parts of hydrogen-terminated hydrogen-containing silicone oil, 10 to 20 parts of methyl-terminated hydrogen-containing silicone oil, 5 to 10 parts of hydroxyl-terminated silicone oil, 0.002 to 0.01 part of an inhibitor, 10 to 20 parts of fumed silica and 1 to 3 parts of a tackifier. The synergistic components in the HGM-coated PN-rGO / APP can greatly improve the flame retardant property of the silicone rubber, improve the compression strength and reduce the heat release rate at the same time.

The invention discloses a preparation process of open-cell organic silicon foam, and aims to solve the problems of non-uniform pore structure, low aperture ratio and difficulty in performance balance in the prior art. The process comprises the following steps: optimizing parameters through bubble nucleation, pore connectivity and a mechanical property model; preparing a composite raw material containing polysiloxane, a fluorine-containing monomer, nano silicon dioxide and hollow microspheres; dynamic pressure circulation and ultrasonic-assisted pre-foaming are adopted; performing staged gradient foaming and curing; and carrying out vacuum post-treatment and plasma surface modification. According to the invention, accurate regulation and control of multi-scale pores are realized, air permeability, mechanical properties and hydrophilicity are significantly improved, heat insulation and high temperature resistance are accidentally improved, process efficiency is improved, by-product emission is reduced, and the method is suitable for the fields of aerospace, filtration and biomedicine.

The invention discloses a high-flexibility drag chain cable and a preparation method thereof, belongs to the technical field of cable processing, and is used for solving the technical problem that the flame retardance and wear resistance of a drag chain cable in the prior art need to be further improved, and the high-flexibility drag chain cable specifically comprises a battery cell, a wrapping layer and a sheath layer which are sequentially arranged from inside to outside, and the sheath layer wraps the wrapping layer. The preparation method comprises the following steps: preparing a modified flame retardant from modified polysiloxane and a phosphorus-based substance through amine-aldehyde condensation, introducing the modified flame retardant into a polyurethane chain segment through a block reaction, carrying out a chain extension reaction to obtain modified polyurethane with a three-dimensional network structure, carrying out melt extrusion on the modified polyurethane, a filler and an auxiliary additive, and coating a wrapping layer with the obtained product. According to the drag chain cable, the flame retardant property and wear resistance of the drag chain cable are improved, and the distortion resistance of the drag chain cable is also improved.

The invention relates to the technical field of membrane separation materials, in particular to a mixed matrix membrane and a preparation method and application thereof. The mixed matrix membrane comprises: (1) a polymer functional membrane; (2) a base film for supporting the polymer functional film; a polymer in the polymer functional film comprises a polymer with a structure as shown in a formula (a), in the formula (a), R0 is an alkylene chain, R1 is a polysiloxane group, R2 is alkyl or hydrogen, and m is equal to 1-20. According to the present invention, the functional membrane prepared from the polymer having the structure (a) is used, and the structure of the polysiloxane is designed and optimized, such that the mixed matrix membrane has excellent organic solvent tolerance and organic solvent pervaporation separation property, and the interfacial compatibility between the polymer and the porous filler can be improved.

The invention relates to an insulating material, in particular to a voltage-breakdown-resistant high-insulation EPDM material and application thereof, and the voltage-breakdown-resistant high-insulation EPDM material comprises the following components: modified silicone rubber, 4, 4 '-thiobis (6-tert-butyl o-cresol), a composite filler, a cross-linking agent, 4-isopropoxybenzoic acid and an EPDM matrix; according to the voltage-breakdown-resistant high-insulation EPDM material disclosed by the invention, the comprehensive performance of the material is greatly improved and the application field of the EPDM material is widened through the matching of all the components and the specific dosage ratio of the components. The modified silicone rubber is introduced, the modified silicone rubber is obtained by modifying vinyl-containing perfluoropolyether-b-polysiloxane, in the vinyl-containing perfluoropolyether-b-polysiloxane, a perfluoropolyether chain segment has extremely low surface energy and good chemical stability, and a polysiloxane chain segment endows the vinyl-containing perfluoropolyether-b-polysiloxane with excellent flexibility and electrical insulating property.

The invention relates to the technical field of organic silicon materials, and discloses high-thermal-conductivity low-dielectric organic silica gel and a preparation method and application thereof.The high-thermal-conductivity low-dielectric organic silica gel is prepared from a component A and a component B. The component A is prepared from, by weight, 35-45 parts of vinyl polysiloxane, 40-50 parts of vinyl silicone resin, 5-20 parts of modified boron nitride, 0.75-1.25 parts of a flatting agent, 1.5-2.5 parts of a defoaming agent and 0.05-0.15 part of a platinum catalyst; and the component B comprises the following components in parts by weight: 15-20 parts of vinyl polysiloxane, 60-85 parts of hydrogen-containing silicone oil and 0.05-0.15 part of an inhibitor. According to the scheme, a continuous and effective 3D heat conduction network is constructed through modified boron nitride, the heat conduction performance of the organic silica gel is improved, meanwhile, covalent interaction is formed between the modified boron nitride and other matrixes, interface bonding is high, the dipole polarization effect at an interface is reduced, the dielectric constant is reduced, and the organic silica gel is quite suitable for the field of electronic packaging.

This invention discloses a PETG co-extruded composite sheet and its preparation method. The method involves adding extruder and APET masterbatch to an extruder, then layering and combining the extruder melt and APET masterbatch melt to form a composite melt with an upper and lower layer of extruder and a middle layer of APET masterbatch. This is then shaped by roller pressing to obtain the PETG co-extruded composite sheet. During the blending process of modified polyester and modified filler, the epoxy group structure in the modified polyester molecule can react with the secondary amine in the modified filler, resulting in mild cross-linking and increasing the strength of the polyester material. The modified polyester molecular chain contains polysiloxane segments, and also has polysiloxane segments branched onto its side links. When impacted, the flexible polysiloxane segments absorb and dissipate a large amount of energy through violent movement, rotation, and entanglement. Furthermore, the nano-reinforcing points formed by the cage-like silsesquioxane structure within the molecule contribute to the excellent scratch resistance of the prepared composite sheet.

The invention relates to the technical field of foaming materials, and particularly discloses a silicone rubber foaming material and a preparation method thereof. The silicone rubber foaming material is prepared from the following raw materials in parts by weight: 1-60 parts of hydroxyl silicone oil, 10-60 parts of vinyl silicone oil, 1-15 parts of hydrogen-containing silicone oil, 1-5 parts of methyl silicone oil, 0.5-1 part of an inhibitor, 0.25-0.5 part of a platinum catalyst, 5-15 parts of modified polysiloxane and 10-30 parts of white carbon black. The invention also provides a preparation method of the composition. Compared with the prior art, the silicone rubber foaming material prepared by the invention does not contain halogen and other harmful substances, does not cause secondary pollution in a combustion process, and can realize efficient balance of mechanical properties and flame retardant properties.

The invention discloses a radiation refrigeration coating as well as a preparation method and application thereof, and relates to the technical field of material preparation. The preparation method comprises the following steps: sintering hexagonal boron nitride, and removing boron oxide to obtain modified boron nitride powder; the preparation method comprises the following steps: reacting supramolecular polysiloxane with methoxypolyethylene glycol to obtain hyperbranched polysiloxane; the modified boron nitride powder and hyperbranched polysiloxane are subjected to hydrolysis on boron nitride under the alkaline condition, and silane modified boron nitride is obtained; the silane modified boron nitride is added into a polyurethane coating matrix to form the radiation refrigeration coating. The silicon-oxygen modified group is introduced to the surface of the boron nitride, so that the interaction between the boron nitride and the coating group is greatly improved, and the stability of the coating is improved; the coating can be cured under different environmental conditions, and construction on power equipment is facilitated; the formed radiation refrigeration coating is high in sunlight reflectivity, high in mid-infrared emissivity and high in heat dissipation capacity for power equipment.

The invention relates to the technical field of epoxy resin, in particular to self-repairing epoxy resin and a preparation method thereof. The self-repairing epoxy resin is prepared from the following raw materials in parts by mass: 80 to 120 parts of bisphenol A type epoxy resin, 20 to 40 parts of bisphenol F type epoxy resin, 5 to 15 parts of 1, 6-hexanediol diglycidyl ether, 1 to 3 parts of 3, 5-dimethylphenylboronic acid, 1 to 5 parts of furyl maleimide, 10 to 20 parts of dodecanedioic acid, 5 to 15 parts of butanetetracarboxylic acid, 1 to 3 parts of catalyst, 10 to 15 parts of nano silicon dioxide, 1 to 2 parts of boron nitride nanosheet and 1 to 2 parts of hyperbranched polyamidoamine. The curing agent is prepared from the following components in parts by weight: 20-30 parts of epoxy resin, 1-2 parts of sulfydryl-terminated polysiloxane, 20-30 parts of amine curing agent, 5-15 parts of reinforcing filler and 0.5 According to the invention, the balance among self-repairing capability, mechanical property and heat resistance is successfully realized; in the microcrack propagation process, fracture and recombination mechanisms of dynamic covalent bonds effectively prevent further propagation of cracks.

The invention discloses a high-temperature-stripping-resistant epoxy structural adhesive as well as a preparation method and application thereof, and belongs to the technical field of high-performance composite materials. The epoxy structural adhesive comprises bisphenol A type epoxy resin, novolac epoxy resin, polysiloxane-polyurethane modified epoxy resin, core-shell modified epoxy resin, PEEK ultrafine powder and other components, and through mutual cooperation of all the components, the problems that in a high-temperature service environment, the adhesive layer modulus of traditional adhesive is rapidly attenuated, and a bonding interface is prone to failure are solved; the epoxy structural adhesive provided by the invention has both rapid curing and heat resistance, is stable in interface bonding, has the highest modulus of 1.28 GPa at 80 DEG C, the highest peel strength of 7.8 N / mm at 80 DEG C, and a damage mode of cohesion or high-proportion mixed damage, and is especially suitable for structural bonding requirements of harsh scenes such as peripheral structures of automobile engines, high-temperature areas of electronic equipment and the like.

The invention belongs to the technical field of acrylic plates, and particularly relates to a continuous casting high-hardness acrylic plate and a preparation method thereof.The preparation method comprises the steps that siloxane modified methacrylic acid, methyl methacrylate and n-butyl methacrylate are mixed, an azo initiator is added into the mixture, and then stirring and mixing are conducted to obtain pre-polymerized slurry; the preparation method comprises the following steps: mixing hydroxyl-terminated ether polysiloxane, isophorone diisocyanate and a catalyst dibutyltin dilaurate, reacting to obtain a macromolecular prepolymer, and then adding an end-capping reagent and a photoinitiator into the macromolecular prepolymer to obtain coating slurry; and injecting the pre-polymerized slurry between two annular steel belts which operate synchronously, coating the two annular steel belts with the coating slurry, and carrying out ultraviolet curing to obtain the high-hardness acrylic plate. Through ultraviolet curing, a high-hardness layer is formed outside the acrylic plate, polyurethane is modified by hydroxyl-terminated ether polysiloxane, the rigidity of a soft chain segment is improved by a polysiloxane chain segment, and the hardness of polyurethane is improved.

A photoelectric composite cable for an underwater buoy, and a preparation process therefor. A polyurethane, a self-repairing polyurethane prepolymer, and a composite nano zinc oxide are selected as an outer sheath base material. A modified polysiloxane having a B-O six-membered ring dynamic cross-linked network and a long-chain alkane group and an amino is introduced into the self-repairing polyurethane prepolymer; 5,5'-methylenedisalicylaldehyde and isophorone diisocyanate are together subjected to stepwise polymerization with the modified polysiloxane, and the 5,5'-methylenedisalicylaldehyde is cross-linked with diphenylmethane diisocyanate to obtain a self-repairing polyurethane prepolymer; and nano zinc oxide is subjected to a modification treatment, wherein dodecyltrimethoxysilane and 3-glycidoxypropyltrimethoxysilane are used for dual modification, such that super-hydrophobic nano zinc oxide having good thermal stability and high dispersity is prepared in a toluene system.

The invention discloses a preparation method for improving the cycle performance of a lithium negative electrode material, and relates to the technical field of lithium negative electrode materials. Lithium powder, Ti3C2Tx and polysiloxane are mixed and calcined to prepare the modified lithium metal material, Ti3C2Tx has a layered structure and provides a stable conductive frame, and the formation of the frame can provide electronic conductivity and effectively inhibit local current density in the charge-discharge process, so that deposition of lithium is limited in the structure, the defects of lithium dendrites are overcome, and the performance of the lithium metal material is improved. The functional group on the surface of the Ti3C2Tx has high binding energy with lithium metal, volume change of the pole piece in the long-time charging and discharging process can be reduced, due to introduction of polysiloxane, the surface energy of Li ion diffusion can be reduced through the Si-O functional group of polysiloxane, Li < + > is evenly distributed, the risk of SEI film breakage is reduced, and therefore the cycle performance of the battery end is improved.

The invention discloses a high-strength, low-temperature-resistant and aging-resistant polymer rubber material and a preparation method thereof in the technical field of rubber materials. The high-strength, low-temperature-resistant and aging-resistant polymer rubber material comprises the following components in parts by weight: 100-120 parts of a rubber matrix, 44-62.5 parts of an interface auxiliary agent, 8-15 parts of a vulcanization system, 4-5 parts of a protection system and 8-12 parts of a toughening agent. According to the invention, a multi-component synergistic system is constructed by the multifunctional reinforcer, amino-terminated polysiloxane, amino-terminated polybutadiene and epoxidized soybean oil, and meanwhile, a carbon black / Si-69 interface assistant and a protection / vulcanization system are optimized, so that the synergistic improvement of mechanical properties, low temperature resistance and aging resistance is achieved; the technical problems that traditional rubber is single, excellent in performance and unbalanced in comprehensive performance are solved.

The invention discloses a high-temperature-resistant high-stripping organic silicon pressure-sensitive adhesive and a preparation method thereof, and relates to a pressure-sensitive adhesive and a preparation method thereof. The invention aims to solve the problems of insufficient temperature resistance, low peel strength and poor binding force with a base material of the existing organic silicon pressure-sensitive adhesive. According to the invention, phenyl siloxane rubber, hydroxyl-terminated polysiloxane and methyl vinyl MQ silicon resin are used as basic raw materials, and polysilazane is used as a heat-resistant modifier to carry out heat-resistant modification on the chemical structure of the pressure-sensitive adhesive; a trifunctional allyl silane monomer is added in the film preparation process, so that the crosslinking density of the system is improved, and the heat resistance of the pressure-sensitive adhesive is further improved; the bonding force between the pressure-sensitive adhesive and a polyimide substrate is improved by adding the peroxysilane coupling agent, and the use of a primer in the coating process is omitted; by adding the hydroxyl MQ silicon resin and the phosphate adhesion promoter, the bonding strength of the pressure-sensitive adhesive is improved, and the high-temperature-resistant and high-stripping organic silicon pressure-sensitive adhesive is prepared. According to the invention, the high-temperature-resistant and high-stripping organic silicon pressure-sensitive adhesive can be obtained.

The invention relates to the technical field of protective films, in particular to a high-light-transmittance label protective film and a preparation method thereof.A multi-layer protective film formed by compounding a release film layer, an adhesive layer, a PET film and a protective layer is constructed; composite vinyl ester resin constructed by taking epoxy resin and acrylic acid as raw materials is subjected to toughening modification, and then a linear reactive diluent is compounded to construct a high-toughness protective layer which is resistant to high temperature and aging and can be photo-cured; long-chain alkane modified nano silicon dioxide is introduced into the protective coating, nano silicon dioxide is aminated by 3-aminopropyltriethoxysilane, and then 17-carbon monoisocyanate prepared by taking acetone, stearic acid, triphenylphosphine, sodium azide and N-chlorosuccinimide as raw materials is grafted to form the long-chain alkane modified nano silicon dioxide. Vinyl butadiene styrene rubber, composite vinyl ester resin, tackifying resin, a softening agent and a photoinitiator are mixed to prepare the adhesive layer.