This invention discloses a ternary composite extraction
system for iron-containing brine with a
high magnesium-to-
lithium ratio and its application. The ternary composite extraction
system includes: a main extractant, a co-extractant, a phase behavior modifier, and a
diluent; wherein the main extractant includes diphenyl octyl
phosphate, the co-extractant includes di(2-ethylhexyl)
phosphoric acid, and the phase behavior modifier includes
diethyl succinate. This invention proposes a ternary composite extraction
system containing DPOP, P2O4, and DES, and establishes a differentiated extraction-back-extraction pathway for complex iron-containing systems. It enables effective
lithium recovery through water back-extraction and controls the distribution behavior of iron in the system, thereby simplifying the process and improving the stability of the organic
phase cycle.