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35results about How to "Slightly corroded" patented technology

Electrolytic manganese dioxide, and method for its production and its application

ActiveUS20120141361A1Excellent in middle rate discharge characteristicSlightly corrodedElectrolysis componentsCell electrodesHigh rateElectrolysis
An object of the present invention is to provide electrolytic manganese dioxide to be used as a cathode active material for an alkali-manganese dry cell, which has a high alkali potential and is provided with a high reactivity and packing efficiency as a cathode for the cell, and which is excellent in the middle rate discharge characteristic, and electrolytic manganese dioxide excellent in the high rate discharge characteristic and the middle rate discharge characteristic, which will not cause corrosion of metal materials, and a method for its production.In the present invention, electrolytic manganese dioxide having an alkali potential of at least 280 mV and less than 310 mV, and FWHM of at least 2.2° and at most 2.9°, is used. It is preferred that of the electrolytic manganese dioxide, the (110) / (021) peak intensity ratio in the X-ray diffraction peaks is at least 0.50 and at most 0.80, and the (110) interplanar spacing is at least 4.00 Å and at most 4.06 Å. Further, electrolytic manganese dioxide wherein the JIS-pH (JIS K1467) is at least 1.5 and less than 2.6, the sodium content is at least 0.02 wt % and less than 0.10 wt %, the sulfate group content is less than 1.30 wt %, the median diameter is at least 30 μm and at most 50 μm, and the BET specific surface area is at least 20 m2 / g and at most 50 m2 / g, is preferred.
Owner:TOSOH CORP

Electrolytic manganese dioxide, and method for its production and its application

An object of the present invention is to provide electrolytic manganese dioxide to be used as a cathode active material for an alkali-manganese dry cell, which has a high alkali potential and is provided with a high reactivity and packing efficiency as a cathode for the cell, and which is excellent in the middle rate discharge characteristic, and electrolytic manganese dioxide excellent in the high rate discharge characteristic and the middle rate discharge characteristic, which will not cause corrosion of metal materials, and a method for its production.In the present invention, electrolytic manganese dioxide having an alkali potential of at least 280 mV and less than 310 mV, and FWHM of at least 2.2° and at most 2.9°, is used. It is preferred that of the electrolytic manganese dioxide, the (110) / (021) peak intensity ratio in the X-ray diffraction peaks is at least 0.50 and at most 0.80, and the (110) interplanar spacing is at least 4.00 Å and at most 4.06 Å. Further, electrolytic manganese dioxide wherein the JIS-pH (JIS K1467) is at least 1.5 and less than 2.6, the sodium content is at least 0.02 wt % and less than 0.10 wt %, the sulfate group content is less than 1.30 wt %, the median diameter is at least 30 μm and at most 50 μm, and the BET specific surface area is at least 20 m2 / g and at most 50 m2 / g, is preferred.
Owner:TOSOH CORP

Method for preparing sulfurized isobutylene by combining hydrogen sulfide tail gas in sulfur-phosphoric acid production

The invention discloses a method for preparing sulfurized isobutylene by combining hydrogen sulfide tail gas in sulfur-phosphoric acid production . The method comprises the following steps: purifying the hydrogen sulfide tail gas; introducing hydrogen sulfide gas into a reaction container added with concentrated ammonia water and sulfur sulfur is completely dissolved to serve as mother liquor, and wherein the molar ratio of ammonia to sulfur to hydrogen sulfide is 1: (0.8-1.2): (0.15-0.30); injecting isobutene into the mother liquor at the temperature of 120-140 DEG C, and carrying out reaction for 1-5 hours at the temperature of 120-190 DEG C, wherein the molar ratio of isobutene to hydrogen sulfide is 1: 0.3 to 1: 0.48; after the reaction is finished, cooling to not higher than 30 DEG C, separating liquid, taking an oil phase part, and washing with water; and carrying out high vacuum falling film heating distillation separation on the washed oil phase part, and collecting a fraction at 120-140 DEG C to obtain the product. According to the technical scheme, safe recovery of hydrogen sulfide is achieved, much less wastewater is generated, the process conversion rate and the comprehensive yield are high, the production efficiency is high, the product character and performance are high, and the technological process is simple.
Owner:XINXIANG RICHFUL LUBE ADDITIVE CO LTD
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