Hydrogenation method for producing biological grease by motor fuel

A technology for bio-oil and motor fuel, which is applied in the preparation of bio-fuel, bio-material, and liquid hydrocarbon mixture, etc., can solve the problems of short operation period, influence of hydrogenation catalyst operation period, poor catalyst stability, etc., so as to improve the stability of operation. Effect

Active Publication Date: 2012-05-23
CHINA PETROLEUM & CHEM CORP +1
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AI Technical Summary

Problems solved by technology

[0005] EP1741767 and EP1741768 disclose a method for producing diesel fractions from animal and vegetable oils, mainly animal and vegetable oils first undergo hydrogenation, and then pass through an isomerization catalyst bed to obtain low-condensation diesel components, but due to the hydrogenation Water is generated during the process, which has a very adverse effect on the isomerization catalyst, and the device cannot run stably for a long period of time
[0006] In the bio-oil hydrogenation process including the above method, one of the main problems encountered is that the stability of the catalyst is poor, the operation cycle is short, and the catalyst needs to be frequently shut down to replace the catalyst
Especially when bio-oil is used as raw material alone or the mixing ratio of bio-oil is high, the operation cycle of the hydrogenation catalyst will be significantly affected, which cannot meet the requirements of industrial applications

Method used

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  • Hydrogenation method for producing biological grease by motor fuel
  • Hydrogenation method for producing biological grease by motor fuel
  • Hydrogenation method for producing biological grease by motor fuel

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Embodiment Construction

[0023] The method of the present invention is specifically as follows: using one or several mixed oils in the biogrease as the raw material oil, under the hydroprocessing operating conditions, the raw material oil and hydrogen pass through the hydroprocessing reaction zone containing at least two hydrogenation catalysts , the obtained hydrotreated oil is recycled in the gas separated by the high-pressure separator (referred to as high fraction), and can also be discharged from the system, and the obtained liquid is fractionated to obtain the following products: one or more of gas, naphtha, and diesel oil One, if the properties of diesel products are further improved or the operation period is extended, a part of diesel and unconverted oil is also considered to be recycled back to the reaction system. The bio-oil used in the examples is a commercially available product, and solid impurities are filtered out before use.

[0024] Further illustrate the specific situation of the p...

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Abstract

The invention relates to a hydrogenation method for producing biological grease by motor fuel. The method is characterized in that the biological grease is taken as a raw oil, under the hydrogenation condition, the raw oil and hydrogen are mixed and passed through a hydrogenation reaction zone, oil is generated by hydrogenation and separated to obtain hydrogen-rich gas for circularly using, the separated liquid is directly produced to the motor fuel. Compared with the prior art, the hydrogenation method for producing the biological grease by motor fuel is capable of effectively improving the storage stability by taking animal and plant grease as the fuel oil, simultaneously ensuring the long-time stable operation of a hydrogenation apparatus.

Description

technical field [0001] The invention belongs to a production method of renewable energy, and relates to a hydrogenation method, in particular to a hydrogenation method for directly producing motor fuel by using biological oil as raw material oil. Background technique [0002] At present, the energy on a global scale mainly comes from fossil energy, among which petroleum is the most important source of motor fuel. Petroleum is a non-renewable energy source. Not only are the resources increasingly depleted, but also the quality and inferiority are intensifying. The continuous development of the world economy and increasingly stringent environmental protection regulations require the production of a large amount of light and clean fuels, which require the existing refining technology to be improved and improved. While improving, new oil substitutes are added to produce products that meet the requirements at the lowest cost. [0003] As a renewable resource, bio-oil has been wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G3/00
CPCY02E50/13Y02E50/10Y02P30/20
Inventor 刘涛曾榕辉李宝忠张学辉白振民方向晨王仲义
Owner CHINA PETROLEUM & CHEM CORP
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