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Process and device for processing and preparing hydrocarbon by utilizing liquefied gas

A liquefied gas and process technology, which is applied in the fields of hydrocarbon cracking to produce hydrocarbons, production of liquid hydrocarbon mixtures, and organic chemistry, etc., can solve the problems of uncoordinated device operation, low price, and low propylene content in the gas separation feed gas.

Active Publication Date: 2014-03-26
SHANDONG ORIENT HONGYE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] This method has high requirements on equipment and heat energy, especially when separating isobutane in the de-isobutanizer tower, 200 layers of trays are needed, the height of the whole tower reaches 160 meters, and the temperature at the top of the tower is not lower than 50°C. The thermal conditions are harsh, the energy consumption is high, accounting for 50% of the total energy consumption, the operation of the device is uncoordinated, and the quality of the isobutane product cannot meet the requirements; at the same time, the content of propylene in the raw gas produced is low, only 15%, resulting in the downstream gas Unstable operation of sub-device
At the same time, the aromatic hydrocarbon impurity content after the aromatization reaction is high, the market competitiveness of the product is weak, and the price is low

Method used

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  • Process and device for processing and preparing hydrocarbon by utilizing liquefied gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0069] A process for producing hydrocarbons by utilizing liquefied gas, including the following steps:

[0070] (1) Cracking reaction process:

[0071] The C4 raw material in the cracking raw material tank is transported to the device area by the raw material pump, and exchanges heat with the pyrolysis reaction product through the first heat exchanger and the second heat exchanger. After the heat exchange, the C4 raw material enters the heating furnace to further raise the temperature To 500°C, the heated gas enters from the top of the cracking reactor to carry out the cracking reaction;

[0072] From the bottom of the cracking reactor, the cracking reaction product passes through the second heat exchanger, the first heat exchanger, the hot water heat exchanger, and the cracking product cooler (reaction condenser) for heat exchange and cooling until the temperature drops to 40 After ℃, it enters the gas-liquid separation tank for separation (the cracking reaction product cond...

Embodiment 2

[0096] Such as figure 1 As shown, a device for realizing the process of utilizing liquefied gas to process hydrocarbons as described in Example 1 includes a cracking reaction system, an absorption stabilization system, an aromatization reaction system, a gas separation raw material gas concentration system, and an aromatics purification system.

[0097] The cracking reaction system includes: raw material pump 1, first heat exchanger 2, second heat exchanger 3, heating furnace 4, cracking reactor 5, reaction product cooler 6, hot water heat exchanger 7, gas Liquid separation tank 8, reaction liquid pump 9, rich gas compressor 10, air compressor outlet air cooler 11, air compressor outlet cooler 12, air compressor outlet liquid separation tank 13;

[0098] The outlet of raw material pump 1 is connected to the bottom nozzle of the shell side of the first heat exchanger 2, the top nozzle of the shell side of the first heat exchanger 2 is connected to the bottom nozzle of the shell...

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Abstract

The invention discloses a process and a device for processing and preparing hydrocarbon by utilizing liquefied gas. The process comprises the processes of cracking reaction, absorption and stabilization, aromatization reaction, gas separation raw material gas stripping concentration and aromatic hydrocarbon purification. The device comprises a cracking reaction system, an absorption and stabilization system, an aromatization reaction system, a gas separation raw material gas stripping concentration system and an aromatic hydrocarbon purification system. The process and the device have the advantages that the energy consumption is low, and after the process is adopted, a deisobutanizer stops running, 90 kilograms of standard coals consumed by a carton-4 raw material per ton are treated, and 48.5 percent of energy is saved; gas separation raw material gas propylene is high in content and is improved from 15 percent to 50 percent in mass fraction; the requirements on equipment and heat energy are low and are easily realized; and the device is simple in process, is easy in operation and control and stable in running.

Description

technical field [0001] The invention relates to a liquefied gas deep processing technology, in particular to a technology and a device for processing hydrocarbons by utilizing liquefied gas, and belongs to the field of processing hydrocarbons by liquefied gas. Background technique [0002] There are many methods for the processing and separation of liquefied gas used in chemical production. At present, there is mainly one kind commonly used in the industry: first pretreatment of raw materials, the C2C3 components in the liquefied petroleum gas are extracted from the top of the depropanizer, and the mixed C4 components at the bottom of the tower enter the deisobutanizer , the isobutane is separated from the top of the deisobutanization tower, and the components with carbon four or more at the bottom of the tower enter the cracking reaction system for cracking reaction, and the obtained low-carbon hydrocarbons including propylene enter the absorption stabilization system; Abs...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C11/06C07C4/04C07C7/11C07C7/05C07C15/00C07C2/00C10G50/00
CPCY02P20/52
Inventor 王峰忠高丰宝张志田牟怀堂刘路路
Owner SHANDONG ORIENT HONGYE CHEM
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