Al2O3-SiC-C iron runner casting material and preparation method thereof

An iron ditch castable, al2o3-sic-c technology, which is applied in the field of iron ditch castables, can solve the problems that the oxidation resistance is not well solved, the thermal shock resistance is not ideal, and the high temperature flexural strength is reduced. Achieve good economic effect, good slag corrosion resistance and oxidation resistance, and the effect of strong thermal shock stability

Inactive Publication Date: 2014-07-16
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

For example, the patented technology of "a new type of main iron ditch castable" (CN201110044222.X) discloses the use of modified nano-carbon powder to replace asphalt, improve its oxidation resistance and carbon residue rate, and also improve the anti-burst performance during baking. However, the thermal shock resistance is not ideal; "a type greater than 2500m 3 "Blast Furnace Main Trough Castable" (CN201210281186.3) patented technology, which discloses the addition of zinc-aluminum spinel powder, nano-sized zirconium silicate, and zirconia hollow spheres, and uses silica sol suspension as a nano-bonding agent to improve the pouring efficiency. The thermal shock stability of the material, but the cost has also increased a lot accordingly, and the anti-oxidation has not been well solved; Graphite partially replaces spherical pitch to improve its oxidation resistance and reduce environmental pollution, but the high temperature flexural strength is correspondingly reduced

Method used

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  • Al2O3-SiC-C iron runner casting material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] a kind of Al 2 o 3 - SiC-C iron ditch castable and preparation method thereof. First, 50-55wt% of fused brown corundum particles, 8-10wt% of fused brown corundum fine powder, 3-7wt% of silicon carbide particles, 6-8wt% of silicon carbide fine powder, 3-5wt% of α -Al 2 o 3 Micropowder, 2-4wt% spherical asphalt, 2-4wt% silica micropowder, 2-4wt% calcium aluminate cement, 2-4wt% metal antioxidant and 0.1-0.2wt% dispersant as raw materials, Add 0.1-0.5wt% catalyst of the raw materials, dry mix evenly, and obtain Al 2 o 3 -SiC-C iron channel castable.

[0026] In this embodiment: the metal antioxidant is metal aluminum; the catalyst is Fe powder with a particle size of 0.02-1 μm.

Embodiment 2

[0028] a kind of Al 2 o 3 - SiC-C iron ditch castable and preparation method thereof. Except following raw material and catalyzer, all the other are with embodiment 1:

[0029] In this embodiment: the metal antioxidant is metal silicon; the catalyst is Ni powder with a particle size of 0.02-1 μm.

Embodiment 3

[0031] a kind of Al 2 o 3 - SiC-C iron ditch castable and preparation method thereof. Except following raw material and catalyzer, all the other are with embodiment 1:

[0032] In this embodiment: the metal antioxidant is a mixture of metal aluminum and metal silicon; the catalyst is FeNi alloy powder with a particle size of 0.02-1 μm.

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Abstract

The invention specifically relates to an Al2O3-SiC-C iron trench castable and a preparation method thereof. The technical solution is: first, 50-60wt% of fused brown corundum particles, 8-12wt% of fused brown corundum fine powder, 3-10wt% of silicon carbide particles, 6-11wt% of silicon carbide fine powder, 3 ~7wt% α-Al2O3 micropowder, 2~4wt% spherical pitch, 2~4wt% silica micropowder, 2~4wt% calcium aluminate cement, 2~4wt% metal antioxidant and 0.1~0.3wt% % dispersant as the raw material, plus 0.1-3wt% catalyst of the raw material, and dry-mix evenly to obtain the Al2O3-SiC-C iron channel castable. The preparation cost of the present invention is relatively low, and the prepared Al2O3-SiC-C iron ditch castable has the advantages of low water addition, large flow value, good high-temperature service performance and strong thermal shock stability, so that the blast furnace iron channel has a large amount of iron and refractory materials Less consumption.

Description

technical field [0001] The invention belongs to the technical field of iron ditch castables. Concretely involving an Al 2 o 3 - SiC-C iron ditch castable and preparation method thereof. Background technique [0002] In recent years, with the development of blast furnace smelting technology, the smelting intensity has been continuously increased. In 2011, the national blast furnace pig iron has reached 628 million tons, and the consumption of refractory materials in blast furnace iron trough is relatively large. al 2 o 3 -SiC-C castable has the characteristics of high strength, erosion resistance, thermal shock resistance and long service life. At the same time, the high thermal conductivity, low expansion rate and slag non-wetting of carbon and silicon carbide all endow this material system with good performance. Physical and chemical properties, so it is widely used in blast furnace tapping trough system. At present, the volume of the blast furnace continues to increa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/66
Inventor 李享成李亚雄朱伯铨
Owner WUHAN UNIV OF SCI & TECH
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