Biomass heavy-oil hydrocracking catalyst and preparation method thereof

A biomass heavy oil and hydrocracking technology, which is applied in the direction of physical/chemical process catalysts, molecular sieve catalysts, chemical instruments and methods, etc., can solve the problems of high acid value, high oxygen content and high viscosity of biomass oil, and achieve improved The effect of uniformity

Inactive Publication Date: 2013-05-29
LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Biomass oil produced by thermal cracking has the disadvantages of high acid value, high oxyge...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Mix 43 grams of modified Y molecular sieve, 17 grams of SBA-15, and 7 grams of molybdenum trioxide evenly, add 4ml of concentrated nitric acid and appropriate amount of water, stir evenly and place for 2 hours, then dry at 120°C for 12 hours, and grind into powder.

[0023] Mix 20 grams of German-made SB alumina, 5 grams of kaolin, and 3 grams of magnesium oxide evenly, place them in a palladium chloride solution containing 1.0 grams of Pd metal for impregnation, and dry them at 120°C for 12 hours after immersion; then place Immerse in a nickel acetate solution containing 5.0 grams of Ni metal, dry at 120°C for 12 hours after immersion for 12 hours, and finally grind it into powder.

[0024] Mix the solid powder obtained in the above two steps evenly, add 6ml of concentrated nitric acid and appropriate amount of water, add 2 grams of safflower powder, stir and mix evenly, extrude into Φ2mm cylindrical strips on the extruder, and heat up to 120°C at a speed of 2°C / Min Dr...

Embodiment 2

[0026] Mix 30 grams of modified Y molecular sieve, 20 grams of SBA-15, and 5 grams of molybdenum trioxide evenly, add 6ml of concentrated hydrochloric acid and appropriate amount of water, stir evenly and place for 2 hours, then dry at 120°C for 12 hours, and grind into powder.

[0027] Mix 30 grams of German-made SB alumina, 4 grams of kaolin, and 4 grams of magnesium oxide evenly, place them in a rhodium chloride solution containing 0.8 grams of Rh metal for impregnation, and dry at 120°C for 12 hours after immersion; then place It is impregnated in a nickel acetate solution containing 6.0 grams of Ni metal, dried at 120° C. for 12 hours after immersion for 12 hours, and finally ground into powder.

[0028]Mix the solid powder obtained in the above two steps evenly, add 9ml of concentrated hydrochloric acid and appropriate amount of water, add 2 grams of safflower powder, stir and mix evenly, extrude into Φ2mm cylindrical strips on the extruder, and heat up to 120°C at a spee...

Embodiment 3

[0030] Mix 40 grams of modified Y molecular sieve, 15 grams of SBA-15, and 6 grams of tungsten trioxide evenly, add 5ml of concentrated nitric acid and appropriate amount of water, stir evenly and place it for 2 hours, then dry it at 120°C for 12 hours, and grind it into powder.

[0031] Mix 25 grams of German SB alumina, 4 grams of kaolin, and 4 grams of boric acid evenly, and place them in a mixed solution of chloride containing 0.7 grams of Rh metal for impregnation. After soaking for 12 hours, dry at 120°C for 12 hours; Ni metal was impregnated in a nickel acetate solution of 5.0 g, dried at 120°C for 12 hours after impregnated for 12 hours, and finally ground into powder.

[0032] Mix the solid powder obtained in the above two steps evenly, add 9ml of concentrated nitric acid and appropriate amount of water, add 2 grams of scallop powder, stir and mix evenly, extrude into Φ2mm cylindrical strips on the extruder, and heat up to 120°C at a speed of 2°C / Min Dry at constant t...

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PUM

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Abstract

The invention discloses a hydrocracking bifunctional catalyst and a preparation method thereof. A hydrogenation function in the catalyst is achieved by an active center composed of noble metal and non-noble metal, and a cracking function is achieved by an acid site on the surface of a catalyst carrier composed of a modification Y molecular screen, an SBA-15, magnesium oxide or boric acid, aluminium oxide and kaolin through pinching in a mixing manner; and the catalyst is characterized in that the noble metal and the non-noble metal can form a hydrogenation activity centre according to the proportion, surface acid concentration and acid strength are adjustable by controlling each component mixture ratio and a preparation process, the balance problem of the hydrogenation function and the cracking function in a hydrocracking reaction process is effectively solved, activity, selectivity, anti-carbon capability, antitoxic capability, and hydrogen consumption of the catalyst are improved, and the service life of the catalyst is prolonged. The catalyst is used for an overhydrocracking reaction of heavy fraction oil and biomass heavy oil.

Description

technical field [0001] The invention relates to a catalyst for hydrocracking of oxygen-containing ring compounds and a preparation method thereof, in particular to a catalyst for hydrocracking of heavy components of biomass oil and a preparation method thereof. Background technique [0002] The global biomass reserves are abundant, which is a clean renewable resource, but petroleum resources are seriously insufficient. The development and utilization of renewable biomass resources to replace petroleum resources is currently considered to be an effective way to solve the problem of insufficient petroleum resources. The biomass is rapidly heated under complete anoxic conditions to rapidly pyrolyze the biomass, and the pyrolysis gas is rapidly condensed to obtain the primary liquid fuel --- bio-oil (Bio-oil). Biomass oil obtained by pyrolysis is a mixture of water and complex oxygen-containing organic matter, including almost all kinds of oxygen-containing organic matter, and t...

Claims

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Application Information

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IPC IPC(8): B01J29/16C10G3/00
CPCY02P30/20
Inventor 李实军王健康闫亮陈晓明李静
Owner LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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