Polyvinyl alcohol anion-exchange membrane and preparation method thereof

An anion exchange membrane and polyvinyl alcohol technology, applied in the chemical field, can solve problems such as secondary pollutants, unenvironmental protection of raw materials and preparation process, secondary pollution of solid waste, etc., and achieve the effect of increasing adsorption capacity
CN103252175AActive Publication Date: 2013-08-21江苏省盐海化工有限公司

Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
江苏省盐海化工有限公司
Publication Date
2013-08-21

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Abstract

The invention provides a polyvinyl alcohol anion-exchange membrane and a preparation method thereof. The polyvinyl alcohol anion-exchange membrane is prepared from quaternary polyvinyl alcohol, polydimethyldiallylammonium chloride, tetraethoxysilane and a cross-linking agent, wherein the weight ratio of the quaternary polyvinyl alcohol to the polydimethyldiallylammonium chloride is 1: (0.1 to 0.6). The polyvinyl alcohol anion-exchange membrane prepared by the preparation method provided by the invention is good in selective adsorption and high in adsorption capacity for chromium ions, free from secondary pollution after adsorption, as well as environment-friendly in raw materials and preparation process.
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Description

technical field

[0001] The invention belongs to the field of chemistry, and in particular relates to a polyvinyl alcohol anion exchange membrane. Background technique

[0002] Cr(Ⅵ) belongs to the first class of pollutants, its toxicity is 100 times that of Cr(Ⅲ), it has great harm to the human body, and long-term intake may cause cancer. Chromium will not degrade by itself under natural conditions, and has a persistent danger to the environment. Chromium mainly comes from processes such as electroplating, tanning, printing and dyeing, and chromium salt production. The state has strict restrictions on the wastewater discharge of the above-mentioned enterprises, and the Cr (Ⅵ) discharge standard must be lower than 0.5mg / L.

[0003] Cr(Ⅵ) is one of the common toxic heavy metals, especially in electroplating wastewater and leather wastewater. At present, the methods for removing Cr reported in the literature mainly include chemical adsorption, membrane interception, electroly...

Claims

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