Electrode, photoelectric conversion element, electronic apparatus and architectural structure
A photoelectric conversion element and electrode technology, which is applied in the field of electronic equipment and building structures, can solve the problems of expensive, platinum dissolution, and degradation of power generation characteristics, and achieve excellent conversion efficiency and durability
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Embodiment 1-1)
[0172] [Preparation of Carbon Counter Electrode]
[0173]First, carbon black (manufactured by Mitsubishi Chemical Corporation, product name: #2600), vapor grown carbon fiber (VGCF) (manufactured by Showa Denko KK), and polyvinylidene fluoride (PVdF) (manufactured by Kureha Chemical Co., Ltd. Manufacture, Product Name: #7300) mixed thoroughly into a powder state. At this time, adjust the mixing ratio of each material so that the mass ratio (B / A) of carbon black (A) to vapor-grown carbon fiber (B) is 25 / 75, and polyvinylidene fluoride (N) is relatively The ratio ((N / M)×100) of the total amount (M) of all materials of the electrode was 2% by mass. In this case, all materials constituting the carbon counter electrode were carbon black, vapor-grown carbon fibers, and polyvinylidene fluoride. Subsequently, a carbon paste can be prepared by adding N-methylpyrrolidone to the mixed powder and stirring the resulting mixture with a paint shaker.
[0174] Next, the prepared carbon past...
Embodiment 2-1 to 2-8)
[0190] The preparation of the dye-sensitized solar cell was the same as in Example 1-1, but the mass ratio (B / A) of carbon black (A) to vapor-grown carbon fiber (B) was changed to the value shown in Table 2.
[0191]
Embodiment 3-1 to 3-6)
[0193] The preparation of the dye-sensitized solar cell is the same as in Example 1-1, but the ratio of polyvinylidene fluoride (N) to the total amount (M) of all materials constituting the carbon counter electrode ((N / M)×100) The values shown in Table 3 were changed, and the mass ratio (B / A) of carbon black (A) to vapor-grown carbon fibers (B) was fixed at 25 / 75.
[0194]
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