Compounds for Electronic Devices
A compound and atom technology, applied in the field of compounds of formula, can solve problems such as limiting organic electroluminescence devices
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[0226] A) Synthesis Example
[0227] Unless otherwise specified, the following syntheses were carried out in dry solvents under a protective gas atmosphere. The compounds of the present invention can be prepared by means of synthetic methods known to those of ordinary skill in the art.
[0228] Starting materials that can be used are, for example, 3-(bromophenyl)-1-phenyl-2-propen-1-one (Chemistry & Biodiversity, 2005, 2(12), 1656-1664), 2-(3-bromophenyl )-4,6-diphenylpyrimidine, 4-(3-bromophenyl)-4,6-diphenylpyrimidine (WO2005 / 085387) and 9,10-dihydro-9,9'-dimethyl Acridine (Chem. Ber. 1980, 113(1), 358-384).
[0229] I) Synthesis of intermediate 1a and analogous compounds 2a-9a
[0230] step 1:
[0231]
[0232] 149 g (687 mmol) of methyl 2-bromobenzoate and 100 g (784 mmol) of 4-chloroaniline were dissolved in 1500 ml of toluene and degassed by introducing an inert gas. Then 271 g (825 mmol) of degassed Cs were added 2 CO 3 , 15.4g (69mmol) Pd(OAc) 2 and 13.9 g (...
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