A kind of leather retanning and dyeing process

A leather and process technology, applied in the field of leather retanning and dyeing process, can solve the problems of difficult treatment of dye-containing sewage, poor leather dyeing effect, no obvious distinction, etc., saving manpower and drum equipment, saving costs, reducing The effect of energy consumption and chemical cost

Active Publication Date: 2015-11-18
XINGYE LEATHER TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The traditional leather retanning and dyeing process is: rinsing→retanning→neutralization→filling, dyeing→fatliquoring→chromatography. The dyeing process is carried out in the middle of the retanning and dyeing process. In this way, the dye-containing waste liquid must be discharged from the middle of the dyeing process, and even some processes need to add dyes for pre-dyeing during rinsing. The wastewater discharged from this process contains dyes from the beginning to the end, which increases the difficulty of treatment. The leather retanning and dyeing process requires more than 20 tons of water, and at least discharges more than 12 tons of wastewater containing dyes, which has brought serious environmental problems
At the same time, the traditional leather retanning and dyeing process steps are relatively complicated. Dyeing is often carried out in the same bath with multiple processes such as filling, fatliquoring, retanning and even neutralization. There is no obvious distinction between the processes. There is a competitive relationship in the combination of leather, which affects the dyeing effect, and requires more chemicals and manpower
[0003] Therefore, the above-mentioned traditional leather retanning and dyeing process is used to process leather, and a large amount of dye-containing sewage produced is difficult to treat and pollutes the environment. The effect of leather dyeing is poor, the accuracy is low, and the color fullness is poor.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A leather retanning and dyeing process, comprising the following steps:

[0018] (1) Drum operation is adopted, the mechanical action mode is uniform rotation, and the rotation speed is 8r / min, and the rinsing, retanning, neutralization, filling, and fatliquoring processes are carried out according to conventional methods, and no dyes are used in these processes;

[0019] (2) Add 150 parts by weight of water at a temperature of 40°C to the drum where the leather treated in (1) is located, adjust the pH to 3.6, add 2.5 parts by weight of brown dye leather brown NGR (manufacturer: Qingdao Dyestuff Factory), add Leveling agent INVADERMAL (adduct of fatty acid and fatty amine and ethylene oxide, manufacturer: Swiss CIBA-GEIGY company) 0.2 parts by weight, react for 60 minutes, add 1.0 parts by weight of formic acid, react for 20 minutes, add chrome retanning agent BITANCHROM26 / 33 (manufacturer: Tiger Industries Co., Ltd.) 0.6 parts by weight, react for 50 minutes; add 0.6 ...

Embodiment 2

[0021] A leather retanning and dyeing process, comprising the following steps:

[0022] 1) Drum operation is adopted, the mechanical action mode is uniform rotation, and the rotation speed is 7r / min, and the rinsing, retanning, neutralization, filling, and fatliquoring processes are carried out according to the conventional method, and no dye is used in these processes;

[0023] 2) Add 160 parts by weight of water at a temperature of 42°C to the drum where the leather treated in (1) is located, adjust the pH to 3.9, add 2 parts by weight of black dye BLACKT (manufacturer: Starr), and add leveling agent INVADERMAL (adduct of fatty acid and fatty amine and ethylene oxide, manufacturer: CIBA-GEIGY, Switzerland) 0.2 parts by weight, react for 40 minutes, add 1.2 parts by weight of formic acid, react for 15 minutes, add chromium powder CHROMOSALBF (manufacturer, LANXESS Chemical) 0.5 parts by weight, react for 50 minutes, and finally add 0.5 parts by weight of cationic fatliquoring...

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PUM

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Abstract

The invention relates to the field of leather processing and provides a leather retanning and dyeing process through which the dyeing accuracy and color fullness can be obviously improved, the manual labor is effectively saved, the energy consumption and material cost are reduced, the environmental pollution is reduced and the dyeing wastewater treatment difficulty is reduced. The leather retanning and dyeing process sequentially comprises the process steps: bleaching, retanning, neutralizing, filling, stuffing and dyeing, wherein the pH in the dyeing process is controlled to be 3.5-4.5, and the dye amount is 1.5-2.5 percent.

Description

technical field [0001] The invention relates to the field of leather processing, in particular to a leather retanning and dyeing process. Background technique [0002] The traditional leather retanning and dyeing process is: rinsing→retanning→neutralization→filling, dyeing→fatliquoring→chromatography. The dyeing process is carried out in the middle of the retanning and dyeing process. In this way, the dye-containing waste liquid must be discharged from the middle of the dyeing process, and even some processes need to add dyes for pre-dyeing during rinsing. The wastewater discharged from this process contains dyes from the beginning to the end, which increases the difficulty of treatment. The leather retanning and dyeing process requires more than 20 tons of water, and at least discharges more than 12 tons of wastewater containing dyes, which brings serious environmental problems. At the same time, the traditional leather retanning and dyeing process steps are relatively com...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P3/32D06P1/00D06P1/607D06P1/653D06P1/44
Inventor 吴华春蔡建设施跃娄永峰
Owner XINGYE LEATHER TECH CO LTD
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