Cold-resisting halogen-free inflaming retarding ABS (Acrylonitrile Butadiene Styrene) and preparation method thereof
An ABS material and cold-resistant technology, which is applied in the field of cold-resistant halogen-free flame-retardant ABS and its preparation, can solve the problems of high corrosion, large smoke generation, and non-environmental protection, and achieve high impact strength and excellent flame-retardant performance.
Inactive Publication Date: 2014-04-30
GUANGDONG JUSHI CHEM CO LTD
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Problems solved by technology
Patent 102604314A discloses a halogen flame-retardant ABS material, which has good cold resistance, but uses a bromine-containing flame retardant, which produces a large amount of smoke, and the HX gas released during combustion is highly corrosive and not environmentally friendly.
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preparation example Construction
[0031] A preparation method of cold-resistant halogen-free flame-retardant ABS material, comprising the following steps:
[0032] 1) Mix all kinds of raw materials evenly;
[0033] 2) Melt and extrude the uniformly mixed raw materials, water cool and pelletize.
[0034] The temperature of melt extrusion is 180-200°C.
Embodiment 1
[0037] The formula composition of the present embodiment is as follows:
[0038] The formula of table 1 embodiment 1
[0039]
Embodiment 2
[0041] The formula composition of the present embodiment is as follows:
[0042] The formula of table 2 embodiment 2
[0043]
[0044]
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The invention discloses a cold-resisting halogen-free inflaming retarding ABS (Acrylonitrile Butadiene Styrene) material. The cold-resisting halogen-free inflaming retarding ABS material is composed of the following raw materials in parts by mass: 65-85 parts of ABS, 15-25 parts of a halogen-free flame retardant, 0-10 parts of a cold-resisting toughening agent, 0.5-2 parts of a lubricant and 0.5-2 parts of other auxiliary agents, wherein the halogen-free flame retardant is a complex of melamine salt, hypophosphite and a flame retardant synergist; the melamine salt is at least one of melamine cyanurate, melamine phosphate, melamine polyphosphate and melamine pyrophosphate. A preparation method of the cold-resisting halogen-free inflaming retarding ABS material comprises the following steps: (1) uniformly mixing all the raw materials; and (2) fusing and extruding the uniformly-mixed raw materials, cooling by water and dicing to obtain the product. The ABS material prepared by the invention has high impact strength and low-temperature impact strength, has excellent inflaming retarding performance and is free of halogen.
Description
technical field [0001] The invention relates to a cold-resistant halogen-free flame-retardant ABS and a preparation method thereof. Background technique [0002] ABS is the abbreviation of acrylonitrile-butadiene-styrene terpolymer. Due to its excellent physical properties, the market demand is huge. With the continuous improvement of people's living standards and the increasing emphasis on safety, flame-retardant ABS came into being and is widely used in various fields. [0003] Flame-retardant ABS usually adopts the method of adding halogen compounds to achieve flame retardancy. Halogen-based flame retardants have a good balance of cost and performance and a wide range of applications. However, due to environmental protection considerations, the use of halogen-containing flame-retardant materials is increasing globally. Cautiously, the introduction of various regulations has made the trend of halogen-free materials. [0004] However, the usual halogen-free flame-retardan...
Claims
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IPC IPC(8): C08L55/02C08L77/00C08L101/00C08L83/04C08K13/02C08K5/3492C08K3/22C08K3/32C08K3/34C08K5/134C08K5/20B29C47/92B29C48/92
CPCB29C48/919B29C48/04B29C48/92B29C2948/92704B29C2948/92876B29C2948/92895
Inventor 张翼翔沈寒知杨杰
Owner GUANGDONG JUSHI CHEM CO LTD
