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Active radiation hardenable resin composition, and spacer and/or color filter protective layer for display element using the same

A technology of active energy rays and curable resins, which is applied in the direction of optical filters, optical elements, nonlinear optics, etc., can solve the problems of poor elastic recovery rate, etc., and achieve the effects of excellent toughness, excellent developability, and high radiation sensitivity

Active Publication Date: 2014-06-18
NIPPON KAYAKU CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The polymer component, which is the main component of the composition, is excellent in developability and flexibility, but has the problem of poor elastic recovery required as a photo-spacer

Method used

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  • Active radiation hardenable resin composition, and spacer and/or color filter protective layer for display element using the same
  • Active radiation hardenable resin composition, and spacer and/or color filter protective layer for display element using the same
  • Active radiation hardenable resin composition, and spacer and/or color filter protective layer for display element using the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-1～1-40

[0154] Examples 1-1 to 1-40: Preparation of reactive polycarboxylic acid compound (A)

[0155] NC-3000H (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 288 g / eq) and NC-2000 (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 230 g) were added as epoxy resin (a) in the amount described in Table 1 / eq), XD-1000 (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 254g / eq), EOCN-103S (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 200g / eq), EPPN-201 (Nippon Kayaku Co., Ltd. Manufactured by the company, epoxy equivalent 190g / eq), NER-1302 (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 280g / eq), NER-7403 (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 292g / eq), EPPN -502H (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 170g / eq), add acrylic acid (abbreviated as AA, Mw=72) as compound (b) in the amount described in Table 1, add in the amount described in Table 1 Dimethylol propionic acid (DMPA for short, Mw=134) ...

Synthetic example 1

[0179] 7 parts by mass of 2,2'-azobis(2,4-dimethylvaleronitrile) and 200 parts by mass of diethylene glycol methyl ethyl ether were charged into a flask equipped with a condenser tube and a stirrer. Next, 5 parts by mass of styrene, 16 parts by mass of methacrylic acid, 34 parts by mass of tetrahydrodicyclopentadienyl methacrylate, 40 parts by mass of glycidyl methacrylate, α-methylstyrene two 3 parts by mass of the polymer were replaced with nitrogen, and then 5 parts by mass of 1,3-butadiene was added, and stirring was started slowly. The temperature of the solution was raised to 70°C, and the temperature was maintained for 5 hours to obtain a polymer solution containing the copolymer [G-1]. The solid content concentration of the obtained polymer solution was 33.1%, and the weight average molecular weight of the polymer was 10,000.

[0180]

[0181] H-1: Fluorine-containing surfactant (Neos Co., Ltd., Futhergent FTX-218)

[0182] H-2: Silicone surfactant (Toray Dow Corni...

Embodiment 2-1

[0187] (B-1 ) 100 parts by mass, 10 parts by mass of (C-3) as a photopolymerization initiator (C), and adding PGMEA and DEGDM as an organic solvent to achieve the desired solid content concentration, mixed as a surfactant (H) ( H-1) 0.3 parts by mass were filtered through a membrane filter with a pore diameter of 0.2 μm to prepare the composition (S-1). In addition, the numerical value of the organic solvent in Table 2 is the mass ratio of PGMEA and DEGDM.

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PUM

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Abstract

The invention relates to active radiation hardenable resin composition, and a spacer and / or a color filter protective layer for a display element using the same. The objective of the invention lies in providing the spacer and the color filter protective layer for the display element, wherein the spacer or the protective layer is good in heat resistant transparency, flatness, flexibility, and tenacity. The active radiation hardenable resin composition for spacer or the protective layer contains a reactive polybasic carboxylic acid compound (A), a reactive compound (B) different from the reactive polybasic carboxylic acid compound (A), a photopolymerization initiator (C), and an organic solvent (D). The reactive polybasic carboxylic acid compound (A) enables the reaction products of epoxy resin with a compound (b) and a compound (c) to further react with polybasic anhydride (d) to obtain the reactive polybasic carboxylic acid compound (A), wherein one molecule of the reactive polybasic carboxylic acid compound (A) at least contains two or more epoxy groups, one molecule of the compound (b) contains one or more polymerizable olefinic unsaturated groups and one or more carboxy groups, and one molecule of the compound (c) at least contains two or more hydroxide radicals and one or more carboxy groups.

Description

technical field [0001] The present invention relates to an active energy ray-curable resin composition, a spacer for a display element, and / or a color filter protective film. Background technique [0002] As a material for a display device, a resin composition containing a binder polymer, a photopolymerizable monomer, a photopolymerization initiator, and the like has been used. In recent years, as materials for display devices (LCD, EL, PDP, FED (SED), rear projection displays, electronic paper or digital cameras, etc., especially display elements, display element peripheral materials), such as color liquid crystal display Devices (LCDs) are rapidly gaining popularity. Generally speaking, the structure of a color liquid crystal display device is: a color filter is opposed to an electrode substrate such as a TFT substrate and a gap of about 1 to about 10 μm is provided, a liquid crystal compound is filled in the gap, and the surrounding area is sealed. The material is seale...

Claims

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Application Information

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IPC IPC(8): G03F7/027G02F1/1339G02B1/10
CPCC08F2/46C08F220/06C08F220/18C08F220/32C08F222/04C08F222/1006C08G59/14C08F220/281C08F220/325C08F220/343G02B5/20G02F1/0107
Inventor 小木聪小渊香津美堀口尚文山本和义
Owner NIPPON KAYAKU CO LTD
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