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A model for determining the diffusivity of dyestuffs in colorants

A diffusion and color paste technology, applied in the direction of measuring devices, analytical materials, instruments, etc., can solve the problems of lack of experimental models or means, and achieve the effects of good reproducibility of results, accurate measurement, and safe and reliable experiments

Active Publication Date: 2016-11-30
ZHANGJIAGANG INST OF IND TECH SOOCHOW UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, at present, there is a lack of theoretical research on the diffusion properties and diffusion models of dyes in printing paste media at home and abroad.
The reason may be that in the actual printing process, the color paste film on the surface of the fabric is relatively thin, and the transfer, adsorption, and diffusion of the dye during the printing process are mostly completed in the next step under high temperature or high pressure conditions, and there is a lack of relevant and effective experimental models or means

Method used

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  • A model for determining the diffusivity of dyestuffs in colorants
  • A model for determining the diffusivity of dyestuffs in colorants
  • A model for determining the diffusivity of dyestuffs in colorants

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Weigh 6g of sodium alginate paste, and slowly add 94ml of deionized water under stirring conditions to prepare a puree with a solid content of 6% for later use. Then take the above density as 1.73g·ml -1 , a volume of 7.5ml of the original slurry, and add the dissolved acid lake blue A dye 0.03g, stir evenly, the obtained dye concentration is 4g L -1 The color paste is spare.

[0036] See attached figure 1, take 1.3g of sodium alginate puree and put it in a transparent cylindrical container 1 whose specifications are r=0.0068m, l=0.05m, then let it stand for 2 hours, and fully remove the residual air bubbles in the puree, so that the cylindrical container 1 The upper surface of the middle raw pulp is smooth. Take 0.2 g of the above-mentioned color paste, apply it evenly to the upper end surface of the original paste in the cylindrical container 1, and then place the cylindrical container 1 containing the color paste and the original paste in the constant temperature ...

Embodiment 2

[0044] According to the method in Example 1, the diffusion performance of Acid Lagoon A in sodium alginate slurry at 95°C was measured. The diffusion time is 7.2×10 3 s, other experimental conditions and steps are the same as in Example 1.

[0045] Under the above conditions, the experimental measurement of the diffusion rate of Acid Lagoon A in sodium alginate slurry at 95°C is 5.57×10 -8 mol / (m 2 s).

Embodiment 3

[0047] Weigh 6g of sodium alginate paste, slowly add 94ml of deionized water under stirring conditions to obtain a blank slurry with a solid content of 6%, then take 99g of the blank slurry, add 1g of glycerin, and stir evenly to obtain a glycerol concentration of 1.41 ×10 -7 mol L -1 The puree is set aside. Then take 13g of the above-mentioned puree, add 0.03g of acid lake blue A dye, and stir evenly to obtain a dye concentration of 5.79×10 -3 mol L -1 , The concentration of glycerol in the auxiliary agent is 1.41×10 -7 mol L -1 The color paste is spare.

[0048] According to the method in Example 1, it is determined that Acid Lagoon A is 1.41×10 at 90° C. and the concentration of auxiliary glycerin. -7 mol L -1 Diffusion properties of sodium alginate slurries. Other experimental conditions and steps are the same as in Example 1.

[0049] The experimental results show that Acid Lagoon A has a concentration of 1.41×10 glycerol at 90°C. -7 mol L -1 , the diffusion ti...

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Abstract

The invention provides a model for measuring the diffusivity of dyes in color paste, which comprises a constant temperature metal bath device (4). The top of the constant temperature metal bath device (4) is provided with a heat preservation cover (2). The constant temperature metal bath device (4) is equipped with at least one cylindrical container (1) with an open top, the container (1) is made of transparent material, and the bottom of the container (1) is equipped with a Hole (3), is provided with plug at the pulp hole (3). Its purpose is to provide a method with simple operation steps, no need for high temperature and high pressure, safe and reliable experiment, high stability of test data, good reproducibility of results, and accurate determination of dye diffusion rate in color paste; at the same time, it has high sensitivity and is suitable for certain A specific dye has good selectivity and can be used to determine the diffusion properties of dyes other than disperse dyes in colorants.

Description

technical field [0001] The invention relates to a model for measuring the diffusivity of dyes in color paste, which belongs to the technical field of textile dyeing and finishing. Background technique [0002] According to domestic and foreign literature reports, in the basic theory of modern dyeing of textiles, the adsorption of dyes on the surface of solid fibers and the diffusion of dyes in the inner phase of fibers have achieved quite mature research results. The adsorption of dyes on fiber macromolecules can be divided into physical adsorption and chemical adsorption. Physical adsorption is mainly related to intermolecular Van der Waals force, hydrogen bond, hydrophobic interaction, etc., while chemical adsorption is mainly realized by ionic bond, coordinate bond, covalent bond, etc. The force is related to the nature of the chemical bond (dyeing and printing process). Adsorption and Diffusion [M]. Beijing: Textile Industry Press, 1985.144-149). Among them, three typi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N13/00
Inventor 龙家杰陈锋
Owner ZHANGJIAGANG INST OF IND TECH SOOCHOW UNIV