Self-suspending proppants for hydraulic fracturing
A technology of hydraulic fracturing and proppant, which is applied in the direction of drilling composition, production fluid, wellbore/well components, etc., and can solve the problem of high cost of the system
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Embodiment 1
[0161] Example 1: Preparation of inner polymer layer
[0162] An inner polymer layer at a concentration of 100 ppm was prepared on a sand sample by adding 200 g of 30 / 70 mesh frac sand to a FlackTek Max 100 long tank. 85 g of tap water and 2 g of a 1% polydiallyldimethylammonium chloride (PDAC) solution were added to the sand. The samples were then manually shaken for about 5 minutes, vacuum filtered, and dried in an oven at 80°C. Sand samples were then removed from the oven and used for subsequent testing.
[0163] The 10 ppm inner polymer layer coating was formulated using the same method as described above, except only 0.2 g of the 1% PDAC solution was used.
[0164] At maximum polymer loading ("Max PDAC"), the inner polymer layer was formulated using the same method as described above, except that 1 g of a 20 wt. % PDAC solution was used. After treatment, the sand was washed with excess tap water, vacuum filtered, and dried in an oven at 80°C. Sand samples were then ...
Embodiment 2
[0165] Example 2: Preparation of inner polymer layer
[0166] An inner polymer layer at a concentration of 100 ppm was prepared on a sand sample by dissolving 0.2 g of LPEI 500 in 10 g of ethanol to form a 2% solution of LPEI 500 in ethanol. In a 250 mL round bottom flask, 0.75 g of 2% LPEI 500 solution was added to 70 g of ethanol. 150 g of 30 / 70 mesh frac sand was then added to the round bottom flask. Solvent was removed using a 65 °C water bath and using a rotary evaporator. Samples were then removed from the flasks and used for subsequent testing.
Embodiment 3
[0167] Example 3: Preparation of Outer Polymer Layer
[0168] An outer polymer layer was applied to sand samples by mixing the sand with liquid Flopam EM533 polymer under different conditions. In one coating method, pure polymer product is added. In another coating method, the polymer product is extended by diluting with hexane. For hexane dilution, in a 40 mL glass vial, add 10 g of polymer to 10 g of hexane and vortex until homogeneous. The polymer was then added to a 30 g sample of 30 / 70 mesh frac sand in a FlackTek Max 100 tank. The samples were placed in a FlackTek DAC 150 SpeedMixer at 2600 rpm for about 25 seconds. The samples were removed from the speed mixer and dried in an oven at 80°C overnight.
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