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Double-chelate liquid fertilizer and preparation method thereof

A technology of liquid fertilizers and chelated fertilizers, applied in fertilizer mixtures, fertilization devices, applications, etc., can solve the problems of unstable chelated products, different sources of amino acids, and different molecular weights, so as to ensure direct absorption and utilization and improve nutrients Content, the effect of ensuring stability

Active Publication Date: 2015-06-10
LUXI CHEM GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to these problems in the chelating process of different chelating agents, humic acid exists as a chelating agent: (1) crops with different molecular weights are not easy to absorb; (2) poor chelating ability, chelated compounds are unstable; (3) Not applicable to international organic agriculture
Amino acid is used as a chelating agent in the chelation of trace elements: (1) easy to decompose under visible light, easy to flatulence; (2) different sources of amino acids; the effect is quite different; (3) poor chelating ability, chelated compounds are unstable; (4) Only sugar alcohols are used as chelating agents, sugar alcohols are small molecules, similar to amino acid chelation, and chelated products are unstable; (5) domestic sources of relevant trace elements are all inorganic salts (sulphate, nitric acid) salt, chloride)

Method used

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  • Double-chelate liquid fertilizer and preparation method thereof
  • Double-chelate liquid fertilizer and preparation method thereof
  • Double-chelate liquid fertilizer and preparation method thereof

Examples

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Effect test

Embodiment 1

[0045] Such as figure 1 Shown flow chart, a kind of preparation method of double chelating liquid zinc fertilizer, comprises the following steps:

[0046] (1) Take by weighing mannitol chelating agent 20g, organic polymer chelating agent EDTA 19g, be dissolved in 300ml aqueous solution;

[0047] (2) Add 2.28g of KOH to adjust the pH value to 6, promote the dissolution of the chelating agent, stir and dissolve for 5 minutes, and add medium and trace elements after the chelating agent is slightly dissolved;

[0048] (3) Weigh 1.79g of zinc sulfate monohydrate and 12.2g of zinc oxide, stir and dissolve, react at a constant temperature of 80°C, and the reaction time is 1 hour, and the solution is clear; due to containing a small amount of zinc sulfate, Zn 2+ Ion and sugar alcohol chelating agent, organic polymer chelating agent -COOH, -OH chelation substitution reaction, constantly replacing H + , so that the solution environment remains acidic (the pH of the original solution i...

Embodiment 2

[0051] A preparation method of double chelated liquid iron fertilizer, comprising the following steps:

[0052] (1) Weighing sorbose alcohol Chelating agent 20g, organic polymer chelating agent IDHA 37.3g, dissolved in 300ml aqueous solution;

[0053] (2) Add KOH4.48g, adjust the pH value to 5, promote the dissolution of the chelating agent, stir and dissolve for 5min, and add medium and trace elements after the chelating agent dissolves slightly;

[0054] (3) Weigh 1.52g ferrous sulfate, 26.9g ferrous oxide, stir and dissolve, react at a constant temperature of 80°C, the reaction time is 1 hour, and the solution is clear; due to containing ferrous sulfate, ferrous sulfate is soluble in water, Fe 2+ Ion and sugar alcohol chelating agent, organic polymer chelating agent -COOH, -OH chelation substitution reaction, constantly replacing H + , so that the solution environment remains acidic (the pH of the original solution is 1), on the one hand the dissolution of ferrous oxide ...

Embodiment 3

[0057] A preparation method of double chelated zinc-copper liquid compound fertilizer, comprising the following steps:

[0058] (1) Take by weighing mannitol chelating agent 40g, organic polymer chelating agent DTPA 74.6g, be dissolved in 600ml aqueous solution;

[0059] (2) Add KOH9.12g, adjust the pH value to 4, promote the dissolution of the chelating agent, stir for 5min, and add medium and trace elements after the chelating agent dissolves slightly;

[0060] (3) Weigh 25g of copper sulfate, 8.1g of zinc oxide, stir and dissolve, react at a constant temperature of 80°C, the reaction time is 1 hour, and the solution is clear; due to containing copper sulfate, copper sulfate is soluble in water, Cu 2+ Ion and sugar alcohol chelating agent, organic polymer chelating agent -COOH, -OH chelation substitution reaction, constantly replacing H + , so that the solution environment remains acidic (the pH of the original solution is 0.5), on the one hand, it promotes the dissolution ...

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Abstract

The invention discloses a double-chelate liquid fertilizer. The double-chelate liquid fertilizer comprises a sugar alcohol chelating agent, an organic polymer chelating agent, medium trace element salt, medium trace element oxide, KOH and water. The preparation method comprises the following steps of: weighing the sugar alcohol chelating agent, and the organic polymer chelating agent according to a proportion, and dissolving into water; adding KOH to prompt the dissolving of the chelating agents, and dissolving for 5-10min; weighing the medium trace element salt and the medium trace element oxide according to the proportion, dissolving into the solution, and stirring; reacting at a constant temperature until the solution is clear, so as to obtain the double-chelate liquid fertilizer. With the sugar alcohol and organic polymer as the chelating agents, compared with double chelating employing single sugar alcohols or amino acids, the direct absorbing and using of crops are guaranteed, the organic polymer chelate is stable, the sugar alcohol chelate is absorbed fast, the organic polymer chelate can be released slowly, and by the cooperation of both, the purpose of synergistic interaction of rapid and medium effect release of medium trace elements can be achieved.

Description

technical field [0001] The invention relates to a double chelating liquid fertilizer, in particular to a liquid fertilizer with trace elements in a chelated state produced by using double chelating technology. Background technique [0002] With the continuous improvement of crop yield and multiple cropping index, people have the "bad habit" of unbalanced fertilization for a long time, and macronutrients such as nitrogen, phosphorus, and potassium are supplemented excessively, while the medium and micronutrient nutrients taken away by crops are not systematically replenished. Supplement, resulting in the lack of medium and micronutrient crops, the soil area is increasing, and the problem is becoming more and more serious. The average percentage of available zinc content in soils in northeast, north and northwest regions below the critical value (0.5mg / kg) was 71.1%; the average percentage of available manganese content in northern soils below the critical value (4.0mg / kg) was...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00
Inventor 杜光补吕新春张伟
Owner LUXI CHEM GRP
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