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Photocatalyst composite structure and preparation method thereof

A photocatalyst and structure technology, applied in the production of hydrogen and other directions, can solve the problem of limited improvement of photocatalytic performance, and achieve the effects of improving photocatalytic degradation efficiency, separation efficiency and large specific surface area.

Inactive Publication Date: 2015-07-29
EAST CHINA UNIV OF SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology describes an improved catalyst system called this compound's specialized structures made up from tiny particles or small tubular segments attached together at their ends. These smaller parts create larger areas where certain molecules like oxygen have enough space available for them to attach themselves onto these surfaces. By combining different types of materials into one material, it provides more effective ways to remove harmful contaminant species such as pesticides, bacteria, dirt, grease, etc., while also allowing other components within the matrix to absorb sunlight effectively without losing effectiveness over longer periods due to reduced activity levels caused by long exposure times. Overall, this innovative design enhance the performance and durability of various industrial processes involving decomposition reactions.

Problems solved by technology

Technologies for creating efficient catalyst systems containing both oxygen atoms and carboxyl radicals for decompositring harmful chemical species from contaminants include combining different types of photosensitive materials together to enhance their activity towards decomposition of harmful molecules without reducing their effectiveness over time. Additionally, modifying the crystal size distribution of various components within each type helps increase the effective area of exposed surfaces and increases the amount of active sites per unit volume. These modifications help achieve better optically excited charge transfer processes between the charges and reduced dark current scatterings during photochemistry.

Method used

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  • Photocatalyst composite structure and preparation method thereof
  • Photocatalyst composite structure and preparation method thereof

Examples

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Effect test

Embodiment 1

[0031] g-C 3 N 4 trunk

[0032] Take 5g of melamine in 100ml of deionized water, ultrasonically disperse, add a certain amount of dilute H 2 SO 4 (volume ratio H 2 SO 4 :H 2 O=1:1), stirred for 2 hours, filtered and washed with deionized water, and dried at 80°C for 12 hours. Then take 3g of the dried sample at the bottom of the porcelain ark, put it into a tube furnace, and bake it at 600°C for 4h under the protection of argon to obtain g-C 3 N 4 .

[0033] g-C 3 N 4 impregnated with metal ions

[0034] Mix 100ml of nickel nitrate aqueous solution with different concentrations and 2g g-C 3 N 4 Ultrasonic mixing, wherein the concentration of nickel nitrate aqueous solution is between 0.005M and 0.02M, after stirring for about 2 hours, centrifuge to separate the solid and liquid, and dry the solid at 60°C to obtain g-C loaded with nickel ions 3 N 4 .

[0035] g-C 3 N 4 On in situ grown CNTs branched structure

[0036] g-C loaded with nickel nitrate 3 N 4 Sp...

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Abstract

The present invention provides a photocatalyst composite structure and a preparation method thereof. The photocatalyst composite structure has backbone-branch structural feature; the graphite type carbon nitride (g-C3N4) is the backbone, and carbon nanotubes(CNTs) grown in situ on the backbone chemical through vapor deposition (CVD) are the branches; and the nano photocatalyst coats on the entire backbone-branch complex structure surface. The invention has the advantages that the photocatalyst composite structure can degrade organic contaminants and realize photocatalytic water decomposition for hydrogen production under ultraviolet and visible light; in addition, the backbone-branch composite structure has large specific surface area, and can fully contact with organic pollutants and electrolyte solution to improve the photocatalytic efficiency.

Description

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Claims

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Application Information

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Owner EAST CHINA UNIV OF SCI & TECH
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