The invention discloses a green deplating solution for a photovoltaic
welding strip and a valuable
metal separation and
recovery method. The deplating solution is an
aqueous solution, and solutes comprise a main
oxidizing agent, a green acidic auxiliary agent, a complexing cosolvent and a
copper special
corrosion inhibitor; the main oxidant is selected from
sodium persulfate,
ammonium persulfate and
ferric nitrate; the green acidic auxiliary agent is selected from
sulfamic acid,
methanesulfonic acid,
tartaric acid and
citric acid; the complexing cosolvent is selected from
sodium chloride,
ammonium chloride and
thiourea; and the
corrosion inhibitor is selected from
benzotriazole, methyl
benzotriazole and 2-mercapto
benzimidazole. The waste
welding strip is subjected to an immersion reaction at the temperature of 20-60 DEG C,
tin, lead and / or silver enter the solution in the form of
complex ions, and a
copper substrate is kept bright and clean; and after
solid-liquid separation, gradient
recovery of silver extraction by replacement, lead separation by
temperature difference crystallization and
tin precipitation by
hydrolysis can be adopted, or total replacement
recovery by adding excessive
zinc-based displacer can be adopted. The separation and
recovery method is rapid in deplating, free of white films, low in
copper loss and suitable for silver-containing and silver-free solder strips.