The invention provides a self-cleaning water-resistant paint which is composed of a modified acrylate emulsion, water, a mineral filler, a nano photocatalyst and a chemical additive, wherein the mineral filler comprises cellular quartz powder, calcined kaolin and pyrauxite; the photocatalyst comprises doped nano titanium oxide powder, doped nano zinc oxide powder, nano zinc titanate powder, nano bismuth titanate powder and graphene; and the chemical additive comprises a thickener, a waterproofing agent, a dispersing agent, a plasticizer, a defoaming agent, a preservative and a film formation assistant. Thus, the paint has the advantages of high binding force, favorable water resistance and favorable self-cleaning capacity.