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Waterborne anticorrosion coating composition and process for providing corrosion-resistant coating on metal surface

A corrosion-resistant coating, metal surface technology, used in anti-corrosion coatings, devices for coating liquids on surfaces, coatings, etc., can solve problems such as insufficient adhesion to corrosion-resistant substrates

Inactive Publication Date: 2015-07-29
THE CHEMOURS CO FC LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, no method for obtaining low-VOC waterborne coatings has been proposed or suggested, and, to date, such systems have remained insufficient with respect to corrosion resistance and adhesion to substrates after exposure to seawater

Method used

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  • Waterborne anticorrosion coating composition and process for providing corrosion-resistant coating on metal surface
  • Waterborne anticorrosion coating composition and process for providing corrosion-resistant coating on metal surface
  • Waterborne anticorrosion coating composition and process for providing corrosion-resistant coating on metal surface

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0163] Blue marine coatings were formulated using Phthalocyanine Blue Millbase (Table 2) and PTFE Millbase (Table 4, Fluoropolymer A) with the formulation (wet add) shown in Table 5 below. A separately prepared white millbase was blended with a blue millbase to match the shade of blue marine paint required by the industry.

[0164] Table 5: Aqua blue monocoat formulation of Example 1

[0165]

[0166] The overall formulation components, including those of the mill base, are shown below (Table 6).

[0167] Table 6: Formulation of Example 1 - Single Coat Blue.

[0168] Example 1

[0169]

[0170] The metal panels were then coated with the coating composition and tested for salt spray corrosion resistance as described above. The blue formulations shown in Table 5 showed good performance on grit blasted CRS panels (untreated) and outperformed comparative commercial coatings (>500 hours) in the ASTM B117 salt spray test. It is then applied to the fastener (zinc phosph...

example 2

[0172] For the blue formulation, reformulation was done in an attempt to improve salt spray performance to achieve 2500 hours of salt spray corrosion resistance (on treated steel). For Blue Marine Coating Example 2, the phenolic resin dispersion was removed and a small molecule melamine crosslinker (hexa-(methoxymethyl)melamine (HM)) was used as the sole crosslinker (Table 8) . Simultaneously, using the blue and white pigments, separate white and blue millbase dispersions were reprepared as a single millbase. The improved blue pigment millbase is shown in Table 7 (and hereinafter referred to as "mixed white / blue millbase").

[0173] Table 7: Mixed White / Blue Mill Base

[0174]

[0175] Table 8: Aqua blue monocoat formulations of Example 2

[0176]

[0177] The overall formulation components, including those of the mill base, are shown below (Table 9).

[0178] Table 9: Formulation for Example 2 - Single Coat Blue.

[0179] Example 2

[0180]

[0181] The m...

example 3

[0192] The initial aqueous red monocoat formulation of Example 3 used a commercially available aqueous fluoropolymer dispersion from FEP that could be blended directly with the red millbase dispersion in Table 12 and other formulation ingredients.

[0193] Table 12: Aqueous red monocoat formulation of Example 3

[0194]

[0195] However, the red marine coating of Example 3 had a lower than target desired gloss and a slightly lower performance COF (target COF, static COF and dynamic COF were all <0.20).

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Abstract

A waterborne coating composition, a process for providing a corrosion-resistant coating on a corrodible metal surface, an anticorrosion film formed by the composition, as well as an anticorrosive article, are disclosed. The coating composition comprises 10-35% by weight of one or more fluoropolymer; 30-65% by weight of one or more phenoxy resin; one or more crosslinking agent; a liquid carrier medium; and 0-40% by weight of an auxiliary binder consisting of one or more of polyethersulfone, polyphenylene sulfide, polyamide, polyimide, polyamideimide, polyether ether ketone, polyetherimide, polyurethane, alkyd resin, polyester, or acrylic polymers.

Description

technical field [0001] The present invention relates to low VOC water-based anti-corrosion coating compositions, methods for providing corrosion-resistant coatings on corrodible metal surfaces, anti-corrosion films formed from said compositions, and anti-corrosion coatings protected by such anti-corrosion films. products. While generally useful for coating offshore equipment, the present invention is of particular note that it provides waterborne fluoropolymer coating compositions for fasteners such as nuts and bolts, wherein the coating provides improved corrosion resistance while maintaining good coating-substrate adhesion and stripping ability (coating-coating peeling), allowing nuts and bolts to unscrew even after exposure to saltwater environments. Advantageously, the aqueous composition can be used as a one-coat marine coating. Background technique [0002] Many infrastructures require anti-corrosion treatment. For example, since some steel structure facilities such...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/00
CPCC08L61/06C09D171/00C09D5/08C08L61/28C08G2650/56Y10T428/31529C09D127/18C08L63/00C08L27/18B05D3/007F16B33/008
Inventor P.L.休斯曼
Owner THE CHEMOURS CO FC LLC